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In this paper, WAXD was used to investigate a series of liquid crystalline and non liquid crystalline sequential copolyester, which was synthesized from 1,10 decanediol, 2,2 bis(4 hydroxyphenyl) propane and the mesogenic monomer 2 methyl 1,4 phenylene bis(4 chloroformyl) benzoate.

应用广角X射线衍射对2，2－双（4羟基苯基）丙烷，1，10癸二醇与2－甲基－1，4－苯撑双（4氯甲酰）苯甲酸酯的一系列共聚酯进行了研究。

Two alternative copolymers of thieno[3,4b]pyrazine and triphenylamine or phenylene, P and P, were synthesized by Wittig-Horner polycondensation.

用Wittig-Horner聚合法合成了两种新的含D-π-A结构的共聚物P和P，这两个聚合物有明显的溶剂变色效应。

Multi block copolymer poly p phenylene vinylene co poly(ethylene oxide(PPVEO200 and PPVEO600) was synthesized by Wittig reaction.

通过经典的Wittig反应，成功合成了聚对苯亚乙烯和2种分子量聚氧化乙烯的多嵌段共聚物(PPVEO200和PPVEO600)。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

We designed and synthesized a new type of chiral phosphine ligand 32 with rigidity skeleton.

另外，还构建了一种结构新颖，具有刚性骨架的手性双膦配体32。

A series of novel dicationic symmetrical and asymmetrical ionic liquids based on tributylalkyl phosphonium and alkylimidazolium were synthesized.

合成了一系列含有三丁基烷基膦盐和烷基咪唑盐的对称的和不对称的双离子液体。

Taking toluene, chlorosulfonic acid and phosphoryl chloride as raw materials, p-toluenesulfonyl was synthesized.

以甲苯、氯磺酸、三氯氧磷为原料，氯化铵为催化剂合成对甲苯磺酰氯。

Therefore, N-phosphoamino acids could be used as models in the study of reactions of the phosphoryl group in the life process.First of all, a series of model N-phosphpoamino acids were synthesized. And their ester exchange reaction on the phosphorous center was studied by ~(31)P NMR, HPLC, ESI-MS and ESI-MS/MS.

首先，本论文从氨基酸角度研究磷化学，合成了一系列模型化合物N-磷酰化氨基酸，利用~(31)P NMR技术研究了磷上酯交换反应，发现α-氨基酸对于磷原子存在着手性选择现象，并且这种手性选择的差异随α-氨基酸种类的不同也有所区别。

In order to find active pesticide leading compounds, thinking about that triazolothiadiazoles had various biological activities, this paper designed and synthesized 11 novel title compounds from 3-substituted-4-amino-5-mercapto-1,2,4-triazoles with heterocyclic carboxylic acid via cyclization in the presence of phosphoryl chloride by the princple of combination of active strucural moieties. The structures of the title compounds were characterized by melting point, IR, 1HNMR and elemental analysis.

为了寻找高活性农药先导化合物，考虑到三唑并噻二唑衍生物具有广泛的生物活性，本文利用活性亚结构拼接原理，将活性基团分别引入1，2，4-均三唑并[3，4-b]-1，3，4-噻二唑杂环的3位和6位，合成了未见文献报道的3，6-二取代均三唑并[3，4-b]-1，3，4-噻二唑类化合物11个，并用IR、1HNMR及元素分析测试技术对其进行了结构表征。

The TiO2 synthesized by normal and reverse micelles as templated were applied for phot ocatalytic of Rhodamine B and organic toxic small molecule 2.4-dichlorophenol under ultraviolet irradiation. Oxidation species and photodegradation products in the photoreaction process were detected for studying their photocatalyst properties. The results showed that: the R-TiO2 had a better photocatalysis property under UV irradiation when photodegradation of RhB and DCP compared to the N-TiO2. After 160min, the mineralized rate of RhB can be 95%. And the oxidative species was mainly referred to OH radical.

利用正相和反相胶束介质模板制备的纳米TiO2为光催化剂，在紫外光照射下，对染料罗丹明B和有机有毒无色小分子2，4-二氯苯酚进行光催化降解，研究了其光催化性能，并对光催化过程中氧化物种及降解产物进行了跟踪测定，结果表明，反相胶束模板体系制备的纳米TiO2与正相胶束介质制备的纳米TiO2比较，在紫外照射下对RhB及DCP的降解有较好的光催化性能，对RhB在160min尤催化矿化率可达95%，光催化反应主要的氧化物种涉及在基自由基。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失