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In order to get the information of interaction between metal complex and DNA and select metal complexes which can cleave DNA effectively, twenty seven transition metal complexes containing O/N coordinate atoms have been synthesized in this thesis. We report the synthesis, crystal structure and properties of the complexes. One of the complexes is the first μ〓-oxalato tetranuclear Cu complex, in which there is ferromagnetic interaction between the copper atoms bridged by oxalate ions. Two trinuclear copper complexes containing partial cubane Cu〓O〓 cores have been synthesized and discussed the magnetic properties.

为了解金属配合物与DNA的相互作用及筛选能有效切割DNA的金属配合物，为无机药物合成及应用提供基础信息，本文利用十个含N、O原子的多齿配体设计合成了二十七个未见文献报道的过渡金属配合物，并解析了它们的晶体结构：其中包括首例μ〓-草酸根的四核铜配合物；合成了两个具有μ〓-OH〓三核缺角立方烷结构的Cu配合物；以HCBP衍生物为配体合成了七个过渡金属配合物；以SCN〓、N〓，C〓O〓等为桥联配体，以dmpyen为端基配体合成了十一个配合物。

Diethylthiophosphoryl chloride was synthesized by reacting phosphorus thiochloride with anhydrous alcohol in the presence of NaOH, and then a novel phosphorus-nitrogen- and sulfur-containing flame retardant, 1, 4-di(O,O-diethyl thiophosphoryl imine) benzene, was synthesized via the reaction of diethylthiophosphoryl chloride with p-phenylenediamine.

以三氯硫磷与无水乙醇在NaOH存在下合成了二乙基硫代磷酰氯，然后再与对苯二胺反应合成了新型的含磷、氮、硫的膨胀型阻燃剂：1，4-二（O，O-二乙基硫代磷酰亚胺基）苯。

Mono dodecyl phosphate is synthesized using trichloro phosphate and di dodecyl phosphate is synthesized using phosphorous pentoxide. The structures are confirmed by IR and contents are analyzed by GC and HPLC. Mixed esters with different mass ratios of mono and di esters are prepared.

分别以三氯氧磷为磷酸化剂，合成并提纯了正十二烷基磷酸单酯，以五氧化二磷为磷酸化剂，合成并提纯正十二烷基磷酸双酯，其结构通过质谱得到了确证，产品组成采用气相色谱和高效液相色谱得到了确定。

Two novel tridentate polypyridyl mixed-ligand cobalt [Co (H2Bzimpy)(superscript 3+)] and ruthenium complexes were synthesized and characterized via elemental analysis and (superscript 1)H NMR. The crystal structure of complex B was determined. The interactions between the complexes and calf thymus DNA were investigated with absorption and fluorescence spectroscopys. Photoactivated cleavage of pBR322DNA by the synthesized complexes were studied.

合成了两种新型三齿多吡啶钴[Co(H2Bzimpy)](上标 3+)和钌混配配合物，用元素分析和1HNMR等对其结构进行了表征，测定了配合物B的晶体结构用电子吸收光谱和荧光光谱等方法研究了配合物与小牛胸腺DNA的相互作用以及配合物对pBR322DNA的断裂作用。

This thesis consists of two parts. In Chapter 1, we synthesized novel polyimides containing 1,2,4-triazole and triphenylamine groups. In Chapter 2, we synthesized polys in which main chain contains triazole group and side chain was carbazole group or triphenylamine group.

本实验共分两部分：第一章以合成含1，2，4-三氮唑和三苯胺结构的聚醯亚胺；第二章以合成三氮唑为主链，侧链分别含有咔唑与三苯胺之聚醚醯亚胺，并探讨其热性质、光学性质及应用。

In this thesis, on the one hand, two new tripodal ligands and twenty-three of their lanthanide complexes were synthesized, and their fluorescence properties were investigated, on the other hand, nine new copper and silver complexes with six kinds of tripodal ligands were synthesized and their crystal and molecular structures were determined by X-ray diffraction analysis.

本论文一方面合成了两个新三脚架配体的23个稀土配合物，并对它们的发光性能进行了探讨；另一方面得到了涉及六种三脚架配体的9个铜、银配合物，并测定了它们的晶体结构。

In this dissertation, several novel halogen-free fire-retardant epoxy-based copper clad laminates were developed. Two kinds of phosphrous-containing epoxy resins were synthesized by different method. A novel nitrogen-containing curing agent 2,4, 6-tri (phenol-methylene -amide)-trizone was synthesized for preparing high-performance epoxy polymers, and the synthesis kinetics, cure kinetics and mechanism of MFP cured with DGEBA have been investigated by Differential Scanning Calorimeter and in situ Infrared.

本论文以开发新型无卤阻燃环氧树脂基覆铜板为目标，合成了两类结构不同的含磷环氧树脂以及一种新型的含氮固化剂2，4，6-三-均三嗪，考察了它们合成过程中的影响因素，用DSC和原位红外光谱法探讨了MFP固化环氧树脂的固化反应机理。

An expansion monomer 3, 9-dihydroxymethyl-di (6-methyl-5 -hydroxyl)-2- heptanone-1, 5, 7, 11tetraoxaspiro [5, 5] undecane was synthesized and its volume change during polymerization is about +3.04%. Its prepolymer was also synthesized by toluene 2, 4-diisocyanide with it.

由三经甲基丙烷合成了螺环原碳酸酯单体3'、9'－二羟甲基－3'，9'-二乙基－1，5，7，11－-四氧杂螺环[5、5]十一烷单体（体积膨胀率＋3.04%）以及它的预聚物，并用其来改性环氧树脂B-63。

The synthesized uniphase C with TiC: WC=5: 5 has been synthesized successfully for the first time under the condition determined by this study.

根据研究所确定的条件第一次成功地合成了TiC：WC=5：5的单相C粉末，其粒径为0.6-2μm。

The uniphase C with W/≤0.3 can be synthesized without being preheated. When W/ is higher than 0.3, the sample expansion increases with the increase of W content, the reaction between W and C is incomplete, the combustion products consist of W〓C, WC, TiC, C, and unreacted W. Preheating mixtures can accelerate the completion of the reaction among Ti, W, and C. The uniphase C with W/=0.4 can be synthesized by SHS at preheat temperature of 600℃. There are two kinds of powders with size of 2-4μm and size less than 1μm in the combustion products.

通过燃烧前沿激冷淬熄试验及产物形貌特征（燃烧块断面组织和产物多晶聚合体颗粒）分析，创新性地提出了两种体系的自蔓延高温反应机制。1熔化—溶解—析出机制：当燃烧温度较高时，燃烧前沿Ti粉熔化，W和C溶解于熔融Ti里，而后C从熔融里析出。2扩散—固溶机制：当燃烧温度不足以使燃烧前沿Ti粉熔化时，通过C的扩散先形成TiC层，其后C沿着热应力导致的TiC层裂纹继续扩散，与固态Ti核反应生成TiC；同时，C扩散至W颗粒，形成W〓C，而后通过C的继续扩散W〓C转变成WC；与此同时，WC固溶至TiC里，形成C固溶体。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失