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Organotin compounds have attracted considerable attention by the chemists and their co-workers due to their wide applications for example as pesticidal, bactericidal and antitumour agents in many fields such as industry, agriculture and medicine. It possesses important scientific meaning to synthesize new organotin compounds and study their structures and properties.

有机锡配合物具有优异的催化、杀菌和抗癌等性能而在工业、农业和医药等领域得到广泛的应用,因而受到化学工作者的重视,因此,合成新的有机锡配合物并研究其性质具有重要的科学意义。

Escherichia coli and many other microoganism synthesize aromatic amino acids through the condensation reaction between phospho enolpyruvate and erythro.

ppsA和tktA是芳香族氨基酸生物合成中心途径的两个关键酶基因,在大肠杆菌中,ppsA基因编码磷酸烯醇式丙酮酸合成酶A ,该酶催化丙酮酸合成磷酸烯醇式丙酮酸;tktA基因编码转酮酶A ,该酶在磷酸戊糖途径中生成 4 磷酸赤藓糖起主要作用。

The target of this project is to design and synthesize novel metal phosphonate compounds with porous structures and to study their chemical and physical properties.

金属有机膦酸化合物作为潜在的离子交换材料、选择性催化剂和传感器等而引起了人们极大的兴趣,本项目的目标是设计合成新的有机膦酸多孔化合物,并进一步研究其化学和物理性质。

A novel preparation method to synthesize DEDB by using aluminium phosphotungstate catalyst was developed.

蒋维开发了一种用磷钨酸铝催化合成二甘醇二苯甲酸酯的新方法。

Tetrahydroisowuinolin derivatives and phthalide derivatives were designed and synthesized on the basis of a PDE4 inhibitor pharmacophore model set up through computer simulation. Some tetrahydroisowuinolin derivatives synthesized were evaluated on their activity against PDE4 for study on the structure-activity relationship.(7-cyclopentyloxy)-6-methoxy-3,4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155) and Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (170) showed good activity against PDE4, which were chosen as the lead compounds to design and synthesize another analogs in order to develop selective PDE4 inhibitors with better activity.

分别设计合成了以四氢异喹啉和氨基苯酞为骨架的两类小分子杂环化合物,并对部分四氢异喹啉衍生物测试了其相关的生物活性,初步确定了其构效关系,发现了两个对PDE4有较好抑制活性的先导化合物(7-cyclopentyloxy)-6-methoxy-3,4-dihydroisoquinolin-2(1H)-yl(4-hydroxy-3-methoxyphenyl)methanone (155)和Methyl 7--6-methoxy-2-(4-methoxy- benzoyl)-1-phenyl-1,2,3,4-tetrahydroisoquinoline-3-carboxylate (170)。

Two times hydrolyzation of Fe~(3+) and Cr~(3+) was firstly pointed out in the process of pillar preparation with hydrothermal method. In order to improve the thermal stability, Fe/Cr-Si-pillaring agent solution was synthesized by hydrolyzing Fe~(3+) and Cr~(3+) solution on the surface of silica sol, and Fe/Cr-Si-pillared montmorillonite (Fe/Cr-Si-PILM) was prepared with conventional method and hydrothermal method. Because the technical innovation of preparation is the best way to improve the PILM properties, two novel methods (Microwave method and Ultrasonication method) have been studied to synthesize Fe/Cr-PILM.In order to expand PILMs new application in the field of coal conversion, catalytic activity of Fe/Cr-Si-PILM catalyst in LongKou lignite and ShenHua coal residue liquefaction was discussed and characterized in the last part of this paper.

研究证明:蒙脱石的预处理是可行的,我们以预处理后的Ca-M为原料,研究并优化了PILM的水热法制备工艺,提出了金属离子的二次水解法;为了提高PILM的热稳定性,我们自制了硅溶胶,合成了Fe/Cr-Si三元复合柱化剂,并制备了Fe/Cr-Si-PILM;在PILM合成中,制备技术的革新是改进PILM性能的重要方法,为此我们探索了微波合成法和超声波合成法在制备Fe/Cr-PILM中的应用;最后,我们选择龙口褐煤和神华煤液化残渣为研究对象,探索了Fe/Cr-Si-PILM催化剂在煤炭液化中的应用,希望能开拓PILM应用的新领域。

Dihydro safrol is mainly used to synthesize piperonyl butoide which is a widely used insecticide synergist.

二氢黄樟油素主要用于合成高效、用途广泛的农药增效剂———胡椒基丁醚。

In this paper, two different methods have been used to synthesize the LiInS2 polycrystalline materials.

本文采用两种方法合成了LiInS2多晶原料,对所获LiInS2多晶原料进行了X射线粉末衍射和差示扫描量热分析。

It has been reported that sulfation of polysaccharides affect strongly on their immunocyte activity and anti-tumour bioactivities, but the sulfatation of polyporus umbellatus polysaccharides has not been reported.The thesis synthesize the sulfate polyporus umbellatus polysaccharides for the first time.

据报道,多糖的硫酸酯化对多糖的免疫细胞活性、抑制肿瘤等生物活性等有很大影响,但是国内外未见猪苓多糖硫酸酯化的相关研究与报道,本实验首次制备得到猪苓多糖硫酸酯,具有创新性。

Synthesizing new compounds are always the goal of chemist. Recent ly, the progress of the hydrothermal synthesis method is giving a new method to synthesize new compounds. The hydrothermal synthesis method is prefectly applied to synthesizing the tunnling materials, micro-and meso-porous mat erials as well as some new materials, so this method obtained the intrest of che mist.

中文题名含有杂原子的金属-氧簇(V,Mo,W,P,As)的合成与结构副题名外文题名论文作者李亚丰导师裘式纶教授学科专业无机化学研究领域\研究方向学位级别博士学位授予单位吉林大学学位授予日期2002 论文页码总数70,68页关键词金属-氧簇化学多酸化学无机合成化学馆藏号BSLW /2003 /O611 /3 合成新结构和新组成的化合物一直是化学家们的目标,近代水热合成技术的发展为合成亲新化合物提供了一种新的方法,水热由于在合成具有孔道结构、微介孔材料以及一其它一些新型材料具有其它方法无可比拟的优越性,因此,越来越受到人们的重视。

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As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸,那乌黑、忧郁的眼睛,她便会相信,他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失

But because of its youthful corporate culture—most people are hustled out of the door in their mid-40s—it had no one to send.

但是因为该公司年轻的企业文化——大多数员工在40来岁的时候都被请出公司——一时间没有好的人选。