查询词典 synthesis

Monascus anka is not only better color and flavor for food, but also had the functions of antioxidation, inhibiting cholesterol synthesis and antiseptic.

研究证实红麴不但具有令食物呈现良好色泽及独特风味之外，还具备有抗氧化、抑制胆固醇合成、抗腐败菌等功效。

A one-pot synthesis of indoles by a palladium-catalyzed annulation of ortho haloanilines and aldehydes is reported by the group of Zhu J.

一个锅合成吲哚的钯催化圆环邻haloanilines报道，由77醛朱 J查看。

The strategy toward the synthesis of spirotryprostatin B is focused on MgI2-catalyzed intramolecular annulation reaction of cyclopropanyl spiroox--indole and imine.

以天然产物的全合成为目标，设计了MgI_2催化的螺氧吲哚化合物与亚胺分子内环合反应，构建目标分子骨架的策略。

L-prolinamide/PPTS system was developed to catalyze Robinson annulation of 1,3-cyclohexanedione derivatives. Using this system, the functionalized carbon chain of Wieland-Wiescher ketone could be synthesized in high enantioselectivity, which was a useful synthon for structural diversity of total synthesis of natural product.

二、发现了L-prolinamide／PPTS体系可以催化Ronbinson环化1，3-环己二酮衍生物，实现含季碳且具有多官能团侧链的Wieland-Wiescher酮高对映选择性的合成，为天然产物结构多样性的合成奠定了基础。

A novel endocyclic enamine cyclopentenone annulation was discovered and rationalized as an unusual Nazarov-type electrocyclization, which would have broad applications in the synthesis of natural alkaloids and other heterocycles.

我们在合成路线一、路线二中用的6-6元环系到7-5元环系的还原重排反应，在温和的酸性还原条件下即能发生，这说明在三尖杉碱的生物合成中6-6元环到7-5元环的还原重排步骤是非常有可能发生的；因此，我们的合成路线二中可认为是生物合成过程。

In this thesis, a convenient and efficient synthesis of highly functionalizeddihydropyrido[2,3-d]pyrimidines via a double [5 + 1] annulation strategy startingfrom easily available α-alkenoyl-α-carbamoyl ketene--acetals 1 and cheapreagents (NH4OAc, DMF, and POCl3) has been developed.

本论文探索了一种简便有效的合成高度官能化的二氢吡啶并[2，3-d]嘧啶的方法，此方法由易得的α-乙酰基-α-氨基乙酰基二硫缩烯酮1和便宜的试剂(醋酸铵，二甲基甲酰胺和三氯氧磷)通过两步[5 + 1]加成而实现。

For the synthesis of NHC precursors, there are also several routes: condensation of glyoxal, amines and paraformaldehyde; alkylation of imidazole or monosubstituted imidazole with alkyl halide; annulation of ortho esters and 1,2-diamines; ring closure of hydrazines or amides with acetic anhydride; reduction of thiones with Na/K in THF.

关于N-杂环卡宾前体的合成途径主要有：乙二醛、伯胺和多聚甲醛的缩合反应；卤代烷与咪唑及其取代咪唑的烷基化反应；原甲酸酯与1，2-二胺的成环反应；肼或酰胺与酸酐的环化反应；用Na/K对环硫脲化合物的还原反应。

THE FIRST TOTAL SYNTHESIS OF TAXAMAIRIN B Taxamairin B, representive of rare naturally-occuring rearrang-ed 9(10→20)-abeo-8, 11, 13-triene diterpenoids, has been firstsynthesized by a eleven-step route in an overall yield of 8.19%,starting from commercially available catechol and 1,3-cyclohexan-dione. The improved Friedel-Crafts annulation, thermodynamicallycontrolled-geminal pairing methylation, the selective oxidation ofallyl group and the selective reduction of the less-hindrancecarbon-carbon double bond are the key steps.

二。美丽红豆杉素B的全合成研究 1，美丽红豆杉素B的首次全合成以价廉，易得的邻苯二酚和1，3-环己二酮为原料，经过改良的Friedel-Crafts烷基化反应，热力学控制的α，β-不饱和酮结构的α一位双烷基化，烯丙位的选择性氧化，以及选择性还原位阻较小的碳碳双键等十一步反应，以8.19％的总收率首次完成了美丽红豆杉素B的全合成。

The system of synthesis appraisal emphasize particularly on colligation ornament characteristics of Lycoris.Herb, the species with orderly and bizarre anthotaxy has the highest appraisal, such as L.aurea, L. rosea .

在综合评价中，评价系统侧重于石蒜属植物的总体观赏效果，十三种石蒜中忽地笑、玫瑰石蒜等花朵整齐，花形奇特，出叶期长的评价效果好；长筒石蒜、中国石蒜等则次之。

The synthesis of a fulleropyrrolidine containing anthracene dyad (compound 1) was reported.

设计合成了一种新的C60-蒽吡咯烷衍生物1。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。