查询词典 synthesis method

The process does not depends on catalytic hydrogenization method, has simple reaction condition, high reactant yield all over 75%, can use TLC to track the whole reaction process, and is more suitable to the transformation of function group in the organic synthesis field as the result of N-Boc or N-Cbz derivative is easy to loss protective reaction, which has spreading application prospect.

该方法不依赖于催化氢化方法，反应条件简单，反应产物产率高，均在75％以上，反应过程可用TLC进行跟踪，且由于N-Boc或N-Cbz衍生物更易发生去保护反应，在有机合成领域更适宜于官能团的转化，具有广阔的应用前景。

In order to reduce synthesis times and prepare zeolite membrane with high quality. In chapter three, a good seed layer was prepared on the substrate surface by vapor phase transformation method and then subjected to microwave heating. The highly compact NaA membranes obtained above were composed of intergrown crystals.

为了减少合成次数，降低膜的厚度，制备出高质量的NaA分子筛膜，本论文第三章采用汽相预涂纳米晶种的方法在载体上制备出高质量的纳米晶种层，然后在微波加热条件下合成出高度致密的NaA分子筛膜，膜是由高度孪生的晶体组成。

In this paper, the 3-D finite element relocating mesh method is used to calculate the temperature field and the thermal creep stress field of spillway dam and mid level outlet dam in certain roller compacted concrete gravity dam, sensitivity analysis have been down with different parameters, such as placing temperature, the location of cooling pipe, cooling temperature, time for water supply, ascended-layer of concrete, intermissive time and different placing time, and the commendatory construction scheme have been put forward in such analysis; according by the test result on the two scheme of concrete aggregate combination (basalt as coarse aggregate and limestone as fine aggregate, basalt as coarse aggregate and basalt as fine aggregate), simulation analysis on temperature field and thermal creep stress field of the commendatory construction scheme have been down, and analysis have also been down on temperature field and thermal stress field of the two different aggregate combination, the result indicates that the spillway dam and mid level outlet dam which adopted these two aggregate combination can both satisfy the require of design crack resistance in concrete, furthermore limestone as fine is better than basalt as fine aggregate; the effect of summer water storage and winter water storage on the temperature field and thermal stress field have been analyzed, comparing with winter water storage, in summer water storage scheme the maximum tensile stress at abnormal concrete in upstream fill is decreased by 0.1～0.3MPa and there are no evidence change of the maximum tensile stress at other parts, which indicate that summer water storage is avail for the crack resistance of upstream fill; according to the simulation calculating result and comparing temperature simulation calculating results and temperature controlling measures of some similarity projects both completed and construction, synthesis appraise have been carried to the design temperature controlling measures of dam, and the temperature controlling measures of this project have been brought forward, all these have great reference value on the design of temperature controlling measures and the optimization of the construction scheme.

本文采用三维有限元浮动网格法仿真计算程序，对某碾压混凝土重力坝的溢流坝段和中孔坝段分别进行了三维有限元温度场和温度徐变应力仿真计算分析，对浇筑温度、冷却水管的布置方式、冷却水温、通水时间、浇筑升程和间歇时间、不同开始浇筑日期等参数进行了敏感性分析，在此基础上提出了推荐的施工方案；根据两种骨料方案(玄武岩粗骨料+灰岩细骨料方案；玄武岩粗骨料+玄武岩细骨料方案)的混凝土性能试验研究成果，对推荐的施工方案进行了温度场和温度徐变应力仿真计算，并对比分析了两种不同骨料情况下的温度场和温度应力，结果表明溢流坝段及中孔坝段采用上述两种骨料均能满足混凝土的抗裂设计要求，且灰岩细骨料优于玄武岩细骨料；计算分析了夏季蓄水和冬季蓄水对坝体温度场和温度应力的影响，夏季蓄水方案与冬季蓄水方案相比，坝体上游变态混凝土区域最大拉应力小0.1～0.3MPa，其他部位最大拉应力无明显变化，夏季蓄水对坝体上游面混凝土的抗裂有利；根据仿真计算成果并通过比较国内一些已建和在建的类似工程的温度仿真计算成果及采取的温控措施，对大坝的设计温控措施进行了综合评价，并提出了该工程的温控措施，对温控设计和优化施工方案具有重要参考价值。

A method for synthesis of isobutyl acetate based on paratoluenesulfonic acid as catalyst was developed.

以冰醋酸、异丁醇为原料，对甲苯磺酸为催化剂合成乙酸异丁酯，通过正交实验考察了原料比、催化剂用量、带水剂用量和反应时间等因素对反应的影响。

Completion of the synthesis involved displacement of the remaining alcohol through a three-step, telescoped sequence featuring an efficient cleavage of an aryl mesylate, and a practical method for introduction of the isobutyric acid fragment.

完成剩余的位移所涉及合成酒精通过三个步骤不胜顺序展出了高效率的卵裂甲磺酸芳、而实际的方法引入异丁酸片段。

Supported solid bases and metal oxide catalysts were prepared successfully by isochoric impregnation and the co-precipitation method, and were used for synthesis of biodiesel from transesterification of rapeseed oil and methanol. The high active solid base catalysts: KF/Al2O3, ZnO/La2O3 and La2O3 were found in this paper.

本文用等体积浸渍法和共沉淀法制备了负载型和金属氧化物型固体碱催化剂，并应用于催化菜籽油与甲醇酯交换合成生物柴油的反应，筛选出了高活性的KF/Al2O3，ZnO/La2O3和La2O3三种固体碱催化剂。

A mild and convenient method for the synthesis of 4(3)-substituted 3(4)-nitro-1H-pyrroles and 3-substituted 4-methyl-2-tosyl-1H-pyrroles from nitroolefins and tosylmethyl isocyanide in ionic liquid 1-butyl-3- methylimidazolium bromide was developed.

本文以离子液体－溴化1-丁基-3-甲基咪唑为溶剂，采用对甲苯磺酰基甲基异腈与硝基烯反应生成4(3)-取代-3(4)-硝基-1-氢吡咯或3-取代-4-甲基-2-对甲苯磺酰基-1-氢吡咯。

In this thesis, we describe a facile and economical synthesis of-abscisic acid from keto-isophorone and 3-butyn-2-ol through ketalization, oxidization, Witting-Horner reaction, reduction with chromium sulfate and other steps in 13% total yields. Compared to the previous routes, the starting materials are more commercially available and cheaper and the synthetic process is more easily controlled in our method, but the yield of this route is still to be improved.As to isostere principle, cyclopropyl and methyl vinyl are a couple of isostere.

本论文设计并完成了一条全新的外消旋脱落酸(1)全合成路线，从廉价的工业原料氧化异佛尔酮和丁炔醇出发，经过缩酮化反应、氧化反应、Wittig-Horner反应、CrSO_4选择性还原反应以及水解等七步反应实现了脱落酸的全合成，总产率达13％，与以往路线相比，该路线所用试剂廉价、合成路线简单，但产率有待提高。

Pymetrazine is chosed as the lead compound, and 21 compounds were firstly designed and synthesized. These compounds were characterized by introducing phenyl derivatives with different functional groups to replace pyridine ring with the isosteric principle and the method of homogeneous synthesis and reasonable biologically designing in order to find new compounds with potential biological activity. These compounds were confirmed by IR, H NMR and MS spectra.

本文选取吡蚜酮为先导化合物，运用电子等排理念，综合类同合成、生物合理设计的方法，引入含有不同官能团的苯基衍生物替代吡蚜酮的结构中心吡啶环，设计合成了21个未见文献报道的化合物，寻找具有潜在生物活性的新三嗪酮类化合物，通过核磁共振氢谱、红外光谱、质谱等手段进行了结构表征，并验证正确。

A reversed-phase high performance liquid chromatographic method was established for determination of isothiocyanates in human urine , which used the reaction of propyl isothiocyanate with 1,2-benzenedithiol as reference instead of the synthesis of 1,3-benzodithiole-2-thione.

省去合成1，3 苯二硫杂环五烯 2 硫酮这一步骤，直接用异硫氰酸丙基酯与1，2 苯二硫酚反应作标准，建立了尿液中异硫氰酸酯的反相高效液相色谱测定方法。

And Pharaoh spoke to Joseph, saying, Your father and your brothers have come to you.

47：5 法老对约瑟说，你父亲和你弟兄们到你这里来了。

Additionally, the approximate flattening of surface strip using lines linking midpoints on perpendicular lines between geodesic curves and the unconditional extreme value method are discussed.

提出了用测地线方程、曲面上两点间短程线来计算膜结构曲面测地线的方法，同时，采用测地线间垂线的中点连线和用无约束极值法进行空间条状曲面近似展开的分析。