查询词典 synthesis method

Advances on the development of new oxidation reagents and methodologies and their applications in both target-and diversity-oriented synthesis have been regularly surveyed and constituted one of the most extensively and actively investigated areas of current organic synthesis.1 In this context,a plethora of oxidants,including those small organic molecule-based reagents (such as Dess-Martin periodinane,Swern oxidation,Moffatt oxida- tion,Corey-Kim oxidation,and 三氧化硫/pyridine)and metal-based systems(such as Jones reagent,Collins reagent,pyridinium chlorochromate,pyridinium dichromate,barium permanganate, manganese dioxide,ruthenium tetroxide,silver carbonate,and Oppenauer oxidation),have been identified to be powerful tools promoting conversion of various alcohols into their corresponding aldehyde or ketone products and thus evolved as a most important class of tools in synthetic chemists'arsenal.

关于新的氧化试剂和方法，在两个目标和多样性为导向的发展及其应用合成的进步定期调查，构成一个最广泛，积极探讨在这方面，过多的地区目前有机合成。1氧化剂，包括有机小分子为基础的试剂（如Dess - Martin氧化剂，斯文氧化反应，氧化法特，科里，金氧化，三氧化硫/吡啶）和金属为基础的系统（如琼斯试剂，柯林斯试剂，吡啶氯铬，吡啶铬，钡锰，二氧化锰，四氧化钌，银碳酸盐和开瓶器氧化），已被证实为推动中相应的醛或酮醇转化的各种产品，功能强大的工具，因而作为一个最重要的阶级演变在阿森纳的工具合成化学家。

Part Four: Attempt of the Abnormal Beckmann Rearrangement to the Synthesis of Indole Alkaloids Indole alkaloid is one of the most significant important alkaloid and its synthesis is a continuing interesting work.

Scheme 3 〓四、手性吲哚类生物碱的合成初探手性吲哚类生物碱是一类具有重要生物活性的生物碱，它们的合成研究是有机化学家持续感兴趣的课题。

Then use a pen or other tool to modify the layer from the scorching-tone, the concept of frequency with color, white is the zone that you want to display black is I don't want to display, the correct use of black and white image synthesis allowing more tonighttoo and you can make a synthesis of the work.

然後搁置喷笔或其他东西编削图层遮色片，跟色频的概念差别，不不不不不暗色是给表现的地区，暗色是我不想表现的地区，不对的诳骗暗与不暗不离可以让影像分解更为力不从心，并且可以怠工不出有条理的分解息品。

Traditional slice synthesis technics have been replaced gradually by the powder synthesis technics because of its high cost and low conversion rate.

传统的片状合成技术成本高，转化率低，已逐步被先进的粉末合成技术取代。

The effects of technical parameters on diamond synthesis with powder materials were investigated. The selection principles of technical parameters in diamond synthesis were discussed.

通过实验考察了粉末材料合成金刚石中工艺参数对合成效果的影响，讨论了粉末材料合成金刚石中工艺参数的选取原则。

The paper analyzed the mechanism of diamond synthesis, stated and compared the processes and differences of diamond synthesis by slice and powder catalyst , and proposed the view of single room production mechanism.

文章分析了金刚石合成的机理，论述和比较了片状触媒和粉状触媒合成金刚石的过程和差异，提出了&单间生长机制&的观点，认为在粉状触媒工艺中金刚石生长的环境条件优越，合成出的金刚石晶体均匀对称，品质良好。

The main contents and conclusions are as follows:(1) Synthesis of 1,6-hexamethylenedicarbamate catalyzed by yttrium nitrate Yttrium nitrate was employed as the catalyst in the synthesis of 1,6-hexamethylenedicarbamate from alkyl carbamates.

主要内容和结论如下：(1)硝酸钇为催化剂合成1，6-己二氨基甲酸酯采用硝酸钇作为小分子氨基甲酸烷基酯和1，6-己二胺合成1，6-己二氨基甲酸酯的催化剂。

Latest researches in the catalysts for synthesis of carbamate by ammonolysis of dimethyl carbonate;2. Progress in the catalysts for synthesis of carbamates by ammonolysis of dimethyl carbonate;3.4,4′-Methylene diphenyl carbamatewas synthesized by ammonolysis of dimethyl carbonate, a substitute of phosgene, and 4,4′-diaminodiphenyl methane with anhydrous zinc acetate as catalyst.

用碳酸二甲酯代替光气，以4，4′-二氨基二苯基甲烷为原料，在无水醋酸锌催化剂的作用下，经胺解反应合成了4，4′-二苯甲烷二氨基甲酸甲酯；测定了MDC的熔点；采用傅里叶变换红外光谱和氢核磁共振对产品结构进行了表征；考察了反应温度、DMC用量、反应压力、反应时间、催化剂用量对MDC收率的影响。

Then we completed the first total synthesis of-Plakoridine A using Eschenmoser couping reaction as akey step. During the synthesis we found the choice of protecting groups and the configuration of the chiralcenter of the substrate play an important role to the key Eschenmoser reaction,so we think our successwould be of guide for synthesizing other polysubstituted pyrrolidines or piperidines.

在论文的第一章中，我们先以易得的对羟基苯乙酸乙酯为原料经多步反应制得了所需的β氨基酸酯，然后利用立体选择性的Aldol缩合反应和内酰胺化反应制得了Plakoridine Alactam，随后，以Eshenmoser缩合反应为关键步骤完成了生物碱-Plakoridine A的首次不对称全合成。

Pulse width modulation is also exploited in sound synthesis, especially subtractive synthesis, as the process gives a chorus effect or that of slightly detuned oscillators played together.

脉宽调制也是利用声音合成，尤其是减法合成，随着这一进程提供了合唱效果还是略失谐振荡器共同出战。

You can do some assertiveness training.

你可以进行一些自信训练。

We were well on the path to making a rear-wheel-drive global platform," says Mays."

我们正致力于建立一个后轮驱动的平台，"Mays这样说道。"