查询词典 synthesis method

In the third chapter, the synthesis of5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde oxime(2) from5-[(1"S)-1",2"-diacetyl-oxyethyl]-1-phenylpyrazol-3-carboxaldehyde(1) and phenyl-hydrazine were introduced firstly. The synthesis of nine dioxapyrrolino[3,4-c]pyrazoles containing chiral pyrazolyl moiety(6a-i) from 2 with N-substituted-phenylmaleimide by nonmetal oxidant IBD-initiated intermolecular 1,3-dipolarcycloaddition was described in detail.

第三章首先以5-[(1′S)-1′，2′-二乙酰氧基乙基]-1-苯基吡唑-3-醛(1)和苯肼为原料，合成了化合物5-(1′S)-1′，2′-二乙酰氧基乙基1-1-苯基吡唑-3-醛-苯腙(2)；再用化合物(2)与N-取代苯基马来酰亚胺反应，利用无金属氧化剂—IBD引发1，3-偶极反应，发生分子间的环加成，合成了9种新型手性吡唑连二氧代吡咯啉并

Synthesis of PPA are intermediate ester methoxy-pyrimidine main raw material; for quinoline acid synthesis; are prepared quinolones (such as: Pipemidic, Ciprofloxacin quinolinic acid, such as containing the quinolone drugs) of raw materials; also are manufacturing and other chemical products dyes intermediates.

是合成PPA的中间体甲氧基嘧啶酯的主要原料；用于喹啉酮酸的合成；是制备喹诺酮类药物(如：吡哌酸、环丙氟哌酸等含喹啉酮酸的喹诺类药物)的原料；亦是制造染料及其他化工产品的中间体。

In chapter 1, the progress in study of the ruthenium complex oxides. especially the coexistance of magnetism and superconductivity in 〓 and 〓 are introduced. The introduction makes conclusion that all of the Ru-1212 and Ru-1222 compounds reported are accompanied by small amounts of SrRuO〓 impurities, this is to say that, it is difficult to synthesize pure samples of these two compounds by traditional solid state reaction. So the author think that the studies for new synthesis methods of ruthenate superconductors which is beneficial to the synthesis of new type precious metals superconductivity is very important till now.

第一章重点综述了钌系复合氧化物的研究进展，特别是其中超导电性的发现及其钌系1212、1222相铜氧化物超导电性和铁磁性共存的特征，在此基础上可以看出，至今文献报道所获得的Ru-1212和Ru-1222相化合物都含有少量的SrRuO〓杂相，即很难通过原有的固相反应方法得到纯相化合物，由此作者提出，现有钌系超导氧化物合成的新方法研究仍具有重要的现实意义，这也将更有利于探索合成新型贵金属超导体。

The application of samarium reagents in organic synthesis is one of the highlights of the methodology in organic synthesis.

钐试剂在有机合成中的应用是近年来有机合成方法学研究中的热点之一。

Synthesis and Thermoelectric Properties of Nano-Skutterudite Compounds by Chemical Methods;2. Thermoelectric Properties and Nanostructuring of Skutterudites;3. The synthesis approaches and its characteristic of skutterudite compounds,such as smelting,solid-state reaction,mechanical alloying and spark plasma sintering etc were reviewed.

回顾了熔融法、固相反应法、机械合金化和放电等离子烧结技术等方钴矿热电材料的制备方法及其特点，重点阐述了在方钴矿化合物中固溶Fe，Ni等元素，以及在方钴矿化合物中填充碱土或稀土元素对热电性能的改进；同时介绍了低维化对方钴矿化合物的热电传输特性的影响。

Beta-thalassemia major is a serious hereditary hemolytic anemia which does great harm to human being.It is a monogenic disease characterised by a reduced synthesis of beta-globin chains,which dues to the Doint mutation or deletion of beta-globin gene and its control region.It not only decreases the hemoglobin level,but breaks the balance of alpha/beta synthesis ratio.The major cellular pathogenetic mechanisms in beta thalassemia are based primarily on the deleterious effects produced by the accumulation of the excess alpha globin chain.These excess alpha-globin chains cannot form stable tetrameric structure and deposit in erythroid cells.They cause large ineffective erythropoiesis on their own,accelerate red cells destruction,and lead to hemolysis.

地中海贫血是一种对人类健康危害严重的遗传性溶血性贫血病，是因β-珠蛋白基因及其调控序列的点突变或缺失致使β-珠蛋白肽链合成减少或完全停止，这不仅使患者血红蛋白水平降低，而且使原来在数量上与之持平的α-珠蛋白肽链相对过剩，这些相对过剩的游离α-珠蛋白肽链并不能形成稳定的四聚体，它们沉积在红细胞中导致了大量无效红细胞生成和红细胞寿命缩短，引起了严重的溶血性贫血。

Synthesis and Characterization of MWNT-containing Polyurethane-urea Based on the typical two-step polyurethane-urea synthesis, self-crosslinkable polyurethane-urea compounded of PTMO Poly (tetramethylene oxide, MDI (4,4'-diphenylmethane diisocyanate) and extended by AEAPS (aminoethyl aminopropyl trimethoxysilane) were prepared.

含有纳米碳管的聚氨酷的合成、表征及性质研究首先通过典型的两步法合成了软段为pTMOPoly(tetramethyrene oxide，叠年东师范大李博士后么站银告硬段为MD！(4，4'一diPhenylmethane diisocyanate)，扩链剂为AEAPS (aminoethylaminoProPyltrimethoxysilane)的聚氨醋。

Author had started the research on design and synthesis of heterocycles several years ago, mainly focused on the design and synthesis of imidazole, thiazole, tetrazole derivatives and their glucosides, in which most of them may have some particular bioactivities.

本论文主要是围绕具有生理活性含氮杂环化合物的设计与合成而展开的，在论文工作中我们应用液相&一锅法&和固相组合化学方法进行了咪唑环、噻唑环、四氮唑环等具有生理活性的杂环化合物及其糖苷的合成。

Study on synthesis of phosphonic acid with thiadiazole and corrosion resistance on copper;2. Synthesis of N,N-dimethyl-1-aminomethane-1,1-di phosphonic acid N-oxide and researches on its corrosion and scale inhibition performances;3. Two phosphonic acid s: dodecylamine-N,N-dimethylene phosphonic acid and dodecyl phosphonic acid,were used to modify zirconia stationary phase in this paper.

通过红外、元素分析对2种不同类型的膦酸化合物改性氧化锆的改性条件和改性机理进行了研究，结果表明：十二烷基膦酸通过Lewis酸碱作用改性，室温浸泡即可达到满意的吸附量；而具有螯合结构的十二胺-N，N-二亚甲基膦酸与氧化锆结合时存在较强的络合作用，最佳改性条件为酸性条件下加热回流。

The facile N-participated transannular reductive rearrangement supports the postulated biogenesis of CET, and accordingly the current synthesis might be regarded as a biomimetic synthesis.

第三章记述了我们在三尖杉碱合成的基础上，应用跨环Clemmensen还原重排关键步骤，成功地构筑了百部碱5-6-7三环核心骨架的研究。

You can do some assertiveness training.

你可以进行一些自信训练。

We were well on the path to making a rear-wheel-drive global platform," says Mays."

我们正致力于建立一个后轮驱动的平台，"Mays这样说道。"