查询词典 surface coating

A Si-HA coating was prepared on titanium by a biomimetic method. The surface of the Si-HA coating was porous, and there was coralloid gibbosity on the surface. Si concentration was descent in Si-HA coating from outside to inside. When the Si content increased, the coating became denser and thinner.

钛表面仿生制备的Si-HA涂层表面多孔，有珊瑚状凸起，涂层中的硅由内向外呈梯度分布；随着涂层平均含硅量增加，表面逐渐致密，涂层厚度减小。

When the surface of the coating is not gluey, you can smear new coating . To sprinkle the rough sand on the coating surface before the coating becomes sold, so that you can get a protection layer.

如需做保护层，可在涂料未固化前，在其表面上粗沙，可使保护层和防水层之间粘结牢固。

Calcium carbonate and soluble glass and so on were confected as alkaline antifouling agent. The Infrared Spectrometry results showed that 2275-2250 cm~(-1) diagnostic absorb wave crest in part A and 3390-3200 cm~(-1) in part B and 1730 cm~(-1) in coating film strongly proved polymers reacted just as the reacting mechanism, that means polysiloxane which offer low-surface-energy property linked Polyurethane system by —OH groups reacting with —NCO groups. Relative molar mass of part A and part B was determined by Gel Permeation Chromatography and the results were appropriate. Surface-energy was determined and results were between 33.6-47.17 mN/m and it increased when alkaline antifouling agent was put into the coating. Alkaline antifouling agent was releasing steadily when the coating film was dipped in seawater. As time gone, the pH value of seawater was increasing. Solubility parameter and results showed that there was no corrasive phenomenon between the polyethylene strand and the coating.

红外光谱分析结果表明，出现在A组分中的2275～2250cm~(-1)处的异氰酸酯特征吸收峰、B组分中的3390～3200cm~(-1)处硅羟基的特征吸收峰及出现在固化后涂膜中的1730cm~(-1)处氨基甲酸酯基团的特征吸收峰证明了涂料成膜物质交联固化符合本文的设计要求，即赋予涂膜低表面能特性的有机硅组分通过—OH基团与—NCO基团的反应已经链接到聚氨酯体系中；凝胶渗透色谱结果表明，成膜物质的A、B组分均为低分子量，符合预聚物的要求；涂膜表面能的测算结果表明，涂膜的表面能在33.6～47.17mN／m之间；加入碱式防污剂后涂膜的表面能略有升高；碱式防污剂的释放平稳，随着涂膜在海水中浸泡时间的增长，pH值有增加的趋势；用溶解度参数原则来评价涂料与网绳的涂装，结果表明，本试验研制的防污涂料对聚乙烯网绳无溶蚀作用。

Through designing of composition and structure of the bioactive graded coating,innerstress and its distribution in the coating were analyzed and calculated, the resultsshowed that when composition distribution coefficient n was 1.5, a reasonable stressdistribution could be got, that was at the beginning of deposition the suspension containingrichly BG granules was used so that a rich BG granules layer, a good transitional layerbetween BG layer at the bottom and the coating could be obtained at the titanium alloy side,the bottom of the coating; the stress value near the interface and surface and its character,pressure stress or tensile stress, were decided by the character of its composition itself.Changing composition distribution coefficient n could only change the variation tendency ofstress in the coating, but did not change the stress distribution rule in the coating. Thethinner the coating is, the sharper stress variation in the coating is, which does not mean thatthicker coating is better because the thicker the coating is, the little the permitteddeformation of coating is, so the coating thickness should be thinner, for example, about50μm for bending applications, but for applications only bearing pure shear stress, such asroot of tooth implant, the coating can be thicker little, for instance, about 80～100μm. The study on electrification characteristic and electrophoresis deposition of HAand BG granules in aqueous and non-aqueous solution system found that EPD almost didn'toccur in aqueous solution system. However, because HA granules take position charges inabsolute alcohol, a homogeneous EPD be carried out on the cathode titanium alloy slice, but taking negative charge in absolute alcohol the BG granules not be deposited on the cathode. A guided HA crystallizing, 100～300nm, on surface of the BG granules be realized by metathetical reaction, which cover BG granules with HA microcrystals and make the covered BG granules taking position charges in absolute alcohol, sequentially realize the EPCD of the BG and HA granules on the cathode, so it is feasible to make a titanium alloy/BG/HA bioactive graded coating by making use of EPCD technology. The corrosion experiment of rich boron bioglass coating and plasma spray coating showed that split phase, rich boron and rich silicon phase, occurred during its preparation. In basic medium the corrosion behavior of 〓 BG coating showed uniformity corrosion, the corrosion mostly occurred at rich boron phase area, therefore batch formula design of BGshould avoid the occurring of split phase. The corrosion appearance of plasma spray coatingappeared a non-uniform corrosion, mostly occurred at the edge of the laminated HA moltendrops, and emerged an accelerated corrosion tendency, which will easyly lead to corrosioncrackles extending to the interface and the happening of osmotic interfacial corrosion, thatmay be one of the major reasons leading to the coating cracking-off in the later period. Thetesting results of thermal expansion coefficient of 〓 and 〓BG showed the thermalexpansion coefficient of 〓 BG matched with that of titanium alloy better, and 〓 BG couldsinter with titanium alloy into densification enamel layer at low temperature (720℃).

将Ti6Al4V合金在1000℃下进行真空热处理会降低其力学性能，且合金内的V元素会向表面富集，因此，钛合金真空热处理和表面涂层的烧结温度不能过高，即应低于其相转变点；通过对生物活性梯度涂层的组成和结构的设计，分析和计算了梯度涂层内的应力大小和分布，结果表明：对于本研究，当成分分布系数n=1.5时，可以获得较合理的涂层力学性能，即在沉积开始时，采用富含BG颗粒的悬浮液，以便在钛合金侧获得同底层BG有良好过渡的富BG涂层；梯度涂层界面和表面的应力大小、性质由材料组成本身的性质决定，改变成分分布系数，只能改变涂层内应力变化的趋势；涂层的厚薄不影响涂层内的应力分布规律，但涂层越薄，涂层内的应力变化越快，但这并不意味着涂层越厚越好，因为涂层越厚，涂层允许的变形越小，对于应用于弯曲受力部位的涂层而言，涂层应薄一点为好(50μm)；而对于仅纯受剪切应力的部位，如牙根种植体，涂层可适当加厚(80～100μm)；通过对HA和BG颗粒在水溶液体系和非水溶液体系中的带电特性和电泳沉积的研究发现，它们在水溶液体系中很难发生电沉积；在无水乙醇溶液中，HA颗粒带正电，可在阴极钛合金片上发生均匀的电泳沉积，而BG颗粒则带负电荷；利用复分解反应法，可以制得100～300nm的HA，通过诱导HA在BG颗粒表面结晶，可对BG颗粒进行表面包覆，获得了被HA包覆的BG颗粒，改变了BG颗粒表面的带电特性，使BG和HA颗粒在无水乙醇中均带上正电荷，从而实现了HA和BG颗粒在阴极上的共沉积。

The invention discloses an electrochemical method for preparing a hydroxylapatite particle thin coating on the surface of a metal implant, which comprises the following steps: electrolyte is put into a container equipped with a constant temperature heating system and heated to be 30 DEG C to 95 DEG C, and then the temperature is kept; platinum is taken as the anode and evenly distributed around the container, and the metal implant is taken as the cathode, put in the middle of the container and totally soaked in the electrolyte; DC voltage of 2V to 4V is added between the anode and the cathode, the surface of the metal implant has cathode reduction reaction, the pH value is increased and the supersaturation degree of the hydroxylapatite is also increased, so as to crystalize on the surface of titanium; after 0.5h to 5h of deposition, a layer of hydroxylapatite particle thin coating which can be excellently adhered to the matrix metal is formed on the surface of the implant.

本发明公开了一种在金属植入体表面制备羟基磷灰石颗粒薄涂层的电化学方法，在装备了恒温加热系统的容器中装入电解液，并将电解液加热到30～95℃恒温；将铂作为阳极均匀分布在容器四周，金属植入体作为阴极置于容器中间，完全浸没在电解液中，两极之间加直流电压2～4V，金属植入体表面发生阴极还原反应，pH值升高，羟基磷灰石过饱和度增加，从而结晶在钛金属表面；经过0.5～5小时沉积后，在植入体表面即可形成一层与基体金属结合优良的、薄的羟基磷灰石颗粒薄涂层。

They are FF testing methods, surface treatment technique, evaluation of the properties of surface modification layer, coating induced embrittlement, selection of coating materials, effects of SP and other surface modification on fretting fatigue resistance . A new coating technology combined with shot peening is proved in improving FFR of titanium alloy. The relation between fretting wear and fretting fatigue mechanism of titanium alloy are discussed on the basis of the experimental results. The main contributions are as follows:(1) Shot peening is the most efficient way in improving fretting fatigue resistance of titanium alloys. Working hardening, roughening and compressive residual stress are involved in the shot peened surface.

本文针对上述问题，从影响FF行为的关键环节：FF实验方法、表面处理工艺技术及表层性能评价、镀层引起的钛合金脆化行为、脆化机制及镀层材料的选择、喷丸强化因数和表面涂层对钛合金FF抗力的影响、FF与微动磨损的联系等，深入系统地研究影响钛合金FF抗力的控制因数，探讨FF机理，并通过喷丸形变强化与新型表面镀或渗层合理复合，达到进一步提高钛合金FF抗力的目的。

The weight percentage for the components of the hyaline coating is as follows: SiO2 45 to 54 percent, B2O3 15 to 20 percent, one or more of Na2O, K2O and Li2O, 10 to 24 percent, one or more of TiO2, ZrO2 and ZnO, 6 to 18 percent , and the rest is one or more of CaO, MgO and CeO2. Firstly, the glass powder is mixed with the mill additions to be pulped and then plated on the surface of titanium or the titanium alloy. After being dried, the surface of titanium or the titanium alloy is directly used for a thermal hydrogen treatment or smelted at a temperature of 900 to 1, 000 DEG C for 15 to 30 minutes and then a hyaline coating with a thickness of 20 to 70 micrometers is formed on the surface of titanium or the titanium alloy; secondly, titanium or the titanium alloy plated with the coating is conducted a thermal hydrogen treatment. After the treatment technique is finished, the coating flakes off automatically in the process of cooling; and finally, a surface treatment is supplemented to meet the requirement of the workpiece surface.

该玻璃质涂层成分按重量百分比：45-54SiO2，15-20B2O3，10-24Na2O、K2O、Li2O中的一种或多种，6-18TiO2、ZrO2、ZnO中的一种或多种，余量CaO、MgO、CeO2一种或多种，将玻璃粉与磨加物混合制浆并涂覆在钛或钛合金表面，干燥后直接用于热氢处理，或在900-1000℃下熔烧15-30min，在钛或钛合金表面制得20-70微米玻璃质涂层，随后将制有该涂层的钛或钛合金置于氢气气氛下进行热氢处理，处理工艺结束后，涂层在冷却过程中自剥落，最后辅以表面处理即可满足工件表面要求。

In this thesis, the research about surface modification of titanium alloy was carried on starting with improving stability of calcium phosphate biomedical coating by force of chemical treatment, Physical Vapor Deposition of titanium metal at high temperature and Electrophoresis Codeposition and sintering technology of the coating. By way of the studying of graded design of microstructure and composition of coating and EPCD and sintering technology, a systemic technology by which a calcium phosphate graded ceramic coating was prepared and sintered rapidly on the surface of a complex shaped product was obtainedand a high function titanium alloy/bioglass/hydroxyapatitegraded coating wasdeveloped.

本文从改善钛合金表面钙磷生物涂层的稳定性入手，采用化学处理、高温真空镀钛和电泳共沉积--烧结等技术对钛合金的表面进行了改性的研究，通过对涂层的结构和组成的梯度设计和EPCD--烧结技术的研究，获得了较系统的能在复杂形状的制品表面涂覆钙磷梯度涂层及其低温快速烧结技术，并研制出了高性能的钛合金／生物玻璃／羟基磷灰石梯度涂层。

Main -cassava starch Hanmei special starch powder candy fillings wrapped with modified starch powder used cationic modified starch paper surface sizing starch paper coating starch dedicated Wet add starch layers dedicated spray starch dedicated plasterboard dedicated starch re-wet adhesive tape with exclusive -starch tapioca starch Hanmei dedicated powder candy fillings wrapped with modified starch powder used cationic modified starch paper surface sizing starch paper coating starch dedicated dedicated add in Wet starch layer dedicated inter-spray starch starch gypsum board dedicated re-wet adhesive tape with exclusive -starch tapioca starch Hanmei dedicated powder candy fillings wrapped with Modified Starch Modified Starch powder with cationic surface sizing starch paper coating special paper made of starch wet end of paper to add a dedicated starch

公司朝着管理严谨，经营有序的现代化企业的方向前进。

The construction tools must be dipped in the solution mixed with xylene and butyl alcohol to clean the surface coating of the tools, and to avoid damage of the equipments.

I、施工器具应浸泡在二甲苯-丁醇溶液中，以清除沾在器具上的涂料，防止损坏设备。

I didn't watch TV last night, because it .

昨晚我没有看电视，因为电视机坏了。

Since this year, in a lot of villages of Beijing, TV of elevator liquid crystal was removed.

今年以来，在北京的很多小区里，电梯液晶电视被撤了下来。