查询词典 superacid

Acetophenone cylic ethylic ketal was synthesized by using acetophenon e and glycol as reactants,and rare-earth solid superacid SO 2- 4-La 3 +/TiO 2 as c atalyst.Factors affecting the product yield were investigated.

以稀土固体超强酸SO2 -4-La3 +/TiO2 为催化剂，苯乙酮和乙二醇为原料催化合成苯乙酮环乙二缩酮，并考察了影响反应的因素。

The yield of product was 56.1% when rare-earth composite solid superacid SO(superscript 2- subscript 4)/ZrO2-CeO2 was used as catalyst at dosage of 3 % of the mass of β-pinene, while mass ratio of borneol to isoborneol in the product reached 46.0:23.2, showing higher borneol selectivity than other catalysts.

当用稀土复合固体超强酸SO(上标 2-下标 4)/ZrO2-CeO2为催化剂，用量3%时，粗龙脑产率为56.1%，但对正龙脑的选择性高于其他催化剂，正、异龙脑比为

Thirdly, on the basis of the optimal reaction conditions of synthesis of borneolacetate, using borneol 、 isoborneol, acetic acid, propionate、 butyrate and isobutyric acid as the starting material and nanometer solid superacid (S_2O_8)~(2-)/ZrO_2 or (SO_4)~(2-)/ZrO_2-La_2O_3 as the catalyst ,a series of compounds ( borneol ester and isoborneol ester ) which had six new compounds were prepared.

以合成乙酸冰片酯的最佳反应条件为基准，采用纳米固体超强酸S_2O_8~(2-)/ZrO_2或SO_4~(2-)/ZrO_2-La_2O_3为催化剂，以冰片、异冰片、乙酸、丙酸、丁酸、异丁酸为原料，合成了系列正、异冰片酯(其中6个末见文献报道)。

The synthesis of butyl isobutyrate with n-butanol and isobutyric acid as reactants and rare-earth solid superacid SO_4~(2-)/TiO_2/La~(3+) as catalyst has been studied.

研究了以稀土固体超强酸 SO_4~（2－）／TiO_2／La~（3＋）为催化剂，异丁酸和正丁醇为原料合成异丁酸丁酯，并考察了影响反应的因素。

The results show that solid superacid catalysts have higher activities,reaction time being short,higher conversion rate of isovaleric acid.

结果表明：此法催化剂用量少、催化活性高、反应时间较短、异戊酸转化率高、工艺简单、在一定条件下催化剂可以重复使用多次。

Under these conditions, the yield of cyclohexanone glycol ketal could be reach 90.4%, indicating that rare earth composite solid superacid SO4(superscript 2-)/ZrO2(superscript 3+) is a good catalyst for the synthesis of cyclohexanone glycol ketal.

在此条件下，缩酮收率可达90.4%，说明稀土复合固体超强酸SO4(上标 2-)/ZrO2/Gd(上标 3+)是一种合成环己酮乙二醇缩酮的优良催化剂。

Five of their single crystals were obtained and their structures were determined by X-ray diffraction. By comparison, it was found that dithiocabamate complexes often formed an exactly planar MS4 unit, such as [Mo(R2dtc)2]; and also formed a special MS 5 unit, such as [Cu2(R2dtc)4], the copper atom lies in a distorted square-pyramidal environment.Four kinds of heteropoly acids were prepared and characterized; a series of solid superacid catalyst of supported heteropoly acid were prepared and characterized; regioselectivites of chlorobenzene mononitration with nitric acid with different heteropoly acid on different supports and reaction conditions have been investigated.

培养并解析了5个该类配合物的单晶结构，通过比较，发现二硫代氨基甲酸盐与过渡金属容易形成四配位结构，金属原子与4个硫原子共平面，比如二乙基二硫代氨基甲酸钼；也能形成比较特殊的五配位结构，比如二乙基二硫代氨基甲酸双核铜，Cu原子与5个S原子相连，处于一个变形的四方锥结构的配位环境。

Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO(superscript 2- subscript 4)/TiO2-ZrO2 solid superacid was investigated.

研究了SO(上标 2-下标 4)/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应，通过GC、GC-MS和红外分析，确定其主产物为4-（4-甲基－3-戊烯基）－4-环己烯-1，2-酸酐。

Synthesis and Structural Analysis of New Monoterpene Derivatives from β-myrcene ;2. Diels-Alder reaction between β-myrcene and maleic anhydride catalyzed by SO2-4/TiO2-ZrO2 solid superacid was investigated.

研究了SO42-/TiO2-ZrO2型固体超强酸催化剂的制备及其催化β-月桂烯与马来酸酐的Diels-Alder反应，通过GC、GC-MS和红外分析，确定其主产物为4-(4-甲基-3-戊烯基)-4-环己烯-1，2-酸酐。

Methyl α-naphthaleneacetate was synthesized by using α-naphthaleneacetic acid and methanol as raw materials and solid superacid TiO2/SO42- as a catalyst.

以固体超强酸TiO2／SO42-为催化剂，研究了α-萘乙酸与甲醇的酯化反应，探讨了催化剂种类、用量及活化温度等反应条件，发现固体超强酸TiO2／SO42-对α-萘乙酸与甲醇的酯化反应具有较高的催化活性，并使后处理简化。

We have no common name for a mime of Sophron or Xenarchus and a Socratic Conversation; and we should still be without one even if the imitation in the two instances were in trimeters or elegiacs or some other kind of verse--though it is the way with people to tack on 'poet' to the name of a metre, and talk of elegiac-poets and epic-poets, thinking that they call them poets not by reason of the imitative nature of their work, but indiscriminately by reason of the metre they write in.

索夫农 、森那库斯和苏格拉底式的对话采用的模仿没有一个公共的名称；三音步诗、挽歌体或其他类型的诗的模仿也没有——人们把&诗人&这一名词和格律名称结合到一起，称之为挽歌体诗人或者史诗诗人，他们被称为诗人，似乎只是因为遵守格律写作，而非他们作品的模仿本质。

The relationship between communicative competence and grammar teaching should be that of the ends and the means.

交际能力和语法的关系应该是目标与途径的关系。