查询词典 sulfonyl

To avoid the influence of ammonolysis, alcoholysis and hydrolysis on molecular structure identification, in this paper, derivational estimation is utilized to confirm molecular structures ofβ-naphthol-containing sulfonyl chloride intermediates. Then the structures of corresponding sulfonamide dyes are also confirmed by FTIR,~1H NMR and mass spectrometry.

为了避免磺酰氯化合物发生水解、醇解和胺解等衍生化反应影响磺酰氯化合物分子结构表征，本文采用衍生化反推法证明了β-萘酚结构磺酰氯化合物的分子结构，并利用红外光谱、核磁共振氢谱、质谱表征了含β-萘酚结构磺酰胺染料的分子结构。

Amino(9-deoxy)epicinchonine was synthesized from cinchonine through the Mitsunobu reaction and was treated with p-toluenesulfonyl chloride,4-chlorobenzene sulfonyl chloride respectively to give two new chiral sulfonamide s.

以辛可宁为原料，经Mitsunobu反应合成了9-氨基(9-脱氧)表辛可宁，然后分别与对甲苯磺酰氯、对氯苯磺酰氯反应，合成了两个新手性磺酰胺，其结构经红外光谱和核磁共振确证。

Amino(9-deoxy)epi cinchonine was synthesized from cinchonine through the Mitsunobu reaction and was treated with p-toluenesulfonyl chloride,4-chlorobenzene sulfonyl chloride respectively to give two new chiral sulfonamides.

以辛可宁为原料，经Mitsunobu反应合成了9-氨基(9-脱氧)表辛可宁，然后分别与对甲苯磺酰氯、对氯苯磺酰氯反应，合成了两个新手性磺酰胺，其结构经红外光谱和核磁共振确证。

In the reaction of a-stannyl radical addition to carbonyl to form six-membered ring, we constructed a sulfonyl group at the a position of the formyl group to inhibit 1,5-H shift in order to increase the cyclization product yield. We obtained 41 % yield of the cyclization product in this system.

在 a-锡基自由基加成到醛基形成六员环的系统中，我们在醛基的 a 位上加入碸基来抑制 1，5-氢转移并提升环合产物之产率，在这个系统中，我们得到了 41 %的环合产物。

Additionally, on account of unstable properties of sulfonyl chlorides in MS and 1H NMR analyses, a new analytical method using stable sulfonamide is put forward to testify the molecular structures of sulfonyl chlorides indirectly.

此外，鉴于磺酰氯在质谱与核磁分析中的不稳定性，以稳定的磺酰胺分析代替直接的磺酰氯分析，间接地证明了磺酰氯的分子结构。

When the reaction time was longer than 5 h with temperatures under 150°C, the sulfonyl group decreased and the iodine value increased in the reaction product.

当 这个反应时间和温度超过5小时在150℃，sulfonyl组和碘酒价值增加反应产品。

NMR results also showed the existence of a 1-sulfonyl group, with the alkyl group having an aromatic group attached to the 3 or greater carbon (counting from the end with the sulfonyl group).

核磁共振结果还表明，存在一种1-sulfonyl集团，用烷基具有芳香集团 3个或更多的二氧化碳(计数和sulfonyl结束集团)。

A new family of sulfonate surfactants, in which the sulfonyl group is attached to one of the alkyl chains, has gained interest owing to their biodegradability, low sensitivity to water hardness, foaming ability, and lower skin irritability than the conventional alkylbenzene sulfonate.

一个新家庭的盐表面活性剂，sulfonyl集团隶属于链条之一，已获得利息烷基是由于它们生物降解性、低敏感性对储层水硬度、发泡能力和较低的皮肤过敏性比传统的烷基苯磺酸盐黄。

Then two series of yellow sulfonamide dyes are synthesized by the reaction of the sulfonyl chlorides and ammonia or different fatty amines in the presence of acid-binding reagent. The structures of sulfonyl chloride intermediates and sulfonamide dyes are confirmed by FTIR,~1H NMR and mass spectrometry.

将所合成的磺酰氯化合物在缚酸剂作用下分别与含有不同碳数的饱和脂肪胺发生缩合反应，合成了两个系列黄色偶氮型磺酰胺染料，并利用红外光谱、核磁共振氢谱和质谱表征了磺酰氯中间体和磺酰胺染料的分子结构。

Starting from the hydroxylamine (dimethyl amino ethanol, triethanolamine) and 1, 3-propane sultone, a series of hydroxyl and sulfonyl dual-functionalized zwitterionic salts were synthesized. Then dual-functionalized ionic liquids containing both hydroxyl and sulfonyl functional groups were produced successfully by zwitterionic salts and three kinds of strong acids (p-toluene sulfonic acid, trifluoromethanesulfonic acid, methanesulfonic acid) respectively. The structure of zwitterionic salts and dual-functional ionic liquids were confirmed by the 1H NMR and IR.

以羟基有机胺(N，N-二甲基乙醇胺，三乙醇胺)为原料与1，3-磺酸内酯反应合成了一系列含有羟基和磺酸基双官能团的内盐，并将所得到的内盐分别与三种强酸(对甲苯磺酸，三氟磺酸，甲磺酸)反应，成功地合成了双功能化室温离子液体，并通过红外光谱、核磁氢谱测定，证实了内盐和双功能化离子液体的结构。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。