查询词典 sulfonic acid

7-Hydroxy-4-methylcoumarin was synthesized from ethyl acetoacetate and m-dihydroxybenzene by the Pechmann condensation using phenyl sulfonic acid as catalyst under solvent-free conditions.

摘 要：以苯磺酸作催化剂，乙酰乙酸乙酯和间苯二酚为原料，通过Pechmann缩合反应合成7-羟基-4-甲基香豆素。

Procaine hydrochloride, ampicillin sodium and dapsone can react with 1,2-naphthoquinone-4-sulfonic acid to form salmon pink compound, respectively. Their maximum absorption wavelengtb.es were shifted from the range of ultraviolet to the visible light.

利用分光光度法研究了抗生素类药物氨苄西林钠，抗麻风病药物氨苯砜，局部麻醉药盐酸普鲁卡因与1，2—萘醌—4—磺酸钠的显色反应，建立了灵敏简便的分光光度法。

The experimental results indicate that the reaction rate exhibited first-order with respect to aniline and half-order to APS and dodecylbenzene sulfonic acid.

研究结果表明，苯胺的乳液聚合反应速率对苯胺是一级反应；对APS和十二烷基苯磺酸均为0.5级反应。

Therefore,it is necessary to develop new routes to prepare anion exchange membranes without such chloromethylation process.As for cation exchange membranes, mostly-perfluorinated sulfonic acid ionomers,such as Nafion~ series,have been wildly used due to their high proton conductivity and substantial durability.

对于强碱性的阴离子交换膜的制备，由于传统路线中的卤甲基化步骤中不可避免的采用强致癌物质二氯甲醚，因此无论是从经济成本还是环境保护方面，开发不采用氯甲基化步骤的阴离子交换膜制备方法是目前的一个迫切要求。

With regard to anion exchange membranes,the traditional preparation method involves a much complicated process—chloromethylation,in which the commonly used chloromethyl methyl ether and bis-chloromethylether are now considered carcinogens.Therefore,it is necessary to develop new routes to prepare anion exchange membranes without such chloromethylation process.As for cation exchange membranes, mostly-perfluorinated sulfonic acid ionomers,such as Nafion~?

对于强碱性的阴离子交换膜的制备，由于传统路线中的卤甲基化步骤中不可避免的采用强致癌物质二氯甲醚，因此无论是从经济成本还是环境保护方面，开发不采用氯甲基化步骤的阴离子交换膜制备方法是目前的一个迫切要求。

A type of modified methyl benzene sulfonic acid sodium salt was synthesized by Friedel-Crafts reaction,knoevenagel reaction and sulfonation reaction with methyl benzol as row material.

以甲基苯为初始反应物，通过付-克反应，knoevenagel反应，磺化反应，最后合成一种改性甲基苯磺酸钠。

The results of its intrinsic fluorescence spectroscopy and fluorescence phase diagram showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L, there existed a partially folded intermediate of Bacillus amyloliquefaciens a-amylase during its unfolding procedure, which followed a three-state model; the result of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L, there existed some stable hydrophobic regions, which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid, in the partially folded intermediate of Bacillus amyloliquefaciens a-amylase; and the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed the distribution of Trp residues in Bacillus amyloliquefaciens a-amylase in different denaturation solution, with the maximum number (8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciens a-amylase molecule could be quenched by potassium iodide; and the results of their protein electrophoresis and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciens a-amylase formed during the whole unfolding procedure of Bacillus amyloliquefaciens a-amylase induced by guanidine hydrochloride.

内源荧光光谱和荧光相图结果表明，当变性液中盐酸胍浓度约为1.0 mol/L时，芽孢杆菌a-淀粉酶的去折叠过程中出现一个部分折叠中间体，其去折叠过程符合&三态模型&；荧光探针结果表明，在溶液中盐酸胍浓度约为1.0 mol/L时，中间态芽孢杆菌a-淀粉酶分子中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域；荧光猝灭研究给出了不同程度变性的淀粉液化芽孢杆菌a-淀粉酶中的Trp的分布情况，结果表明中间态芽孢杆菌a-淀粉酶分子中能够被碘化钾猝灭的位于分子表面的色氨酸残基数目达到最大的8个；蛋白电泳和体积排阻色谱结果表明，在盐酸胍诱导的芽孢杆菌a-淀粉酶分子的整个去折叠过程中，不会以共价键或非共价键形式形成芽孢杆菌a-淀粉酶分子之间的集聚体或集聚体沉淀。

The results of its fluorescence probe showed that when the guanidine hydrochloride concentration in denaturation solution was about 1.0 mol/L,there existed some stable hydrophobic regions,which could interact with a hydrophobic reagent 8-anilino-1-naphthalene sulfonic acid,in the partially folded intermediate of Bacillus amyloliquefaciensα-amylase;with the denaturation concentration increasing,the stable hydrophobic regions disappered.the results of fluorescence quenching using acrylamide and potassium iodide as quenchers showed that using acrylamide as quenchers,with the protein denaturation extent increasing,the number of Trp that can be quenched increased untill all the Trp residues were quenched;Using potassium iodide as quenchers,with the maximum number(8) of tryptophan residues in a partially folded intermediate Bacillus amyloliquefaciensα-amylase molecule could be quenched by potassium iodide;with the denaturation concentration increasing,the number of Trp that can be quenched decreased to 5.the results of their protein electrophoreses and SEC showed that no aggregate or aggregate precipitation of Bacillus amyloliquefaciensα-amylase formed during the whole unfolding/refolding procedure of Bacillus amyloliquefaciensα-amylase induced by guanidine hydrochloride or urea.

ANS外源荧光探针结果表明：盐酸胍诱导的芽孢杆菌α-淀粉酶分子去折叠过程中存在着能够与探针分子1-苯胺基-8-萘磺酸结合的稳定的疏水区域；而随着芽孢杆菌α-淀粉酶分子在盐酸胍溶液中变性程度的加深，这一疏水区域逐步被瓦解。丙烯酰胺和碘化钾猝灭结果表明：在盐酸胍溶液中，随着芽孢杆菌α-淀粉酶分子变性程度的进一步加深，其分子内能够被丙烯酰胺接近的色氨酸残基逐渐增多，直至全部被猝灭。但位于芽孢杆菌α-淀粉酶分子表面的能够被碘化钾猝灭的色氨酸残基，在中间态芽孢杆菌α-淀粉酶分子中数目达到最大的8个，而随着其分子变性程度的进一步加深，反而减少至5个。

Similar lamellar hybrids can be obtained from octa(y-chloroammoniumpropyl) polyhedral oligomeric silsesquioxanes dodecyl benzene sulfonic acid sodium salt C_(18H_(29)NaO_3S, DBSS. Further research shows that different POSS to surfactant ratios result in different arrangement of layers: when there exists excessive POSS, the layer is arranged in a "Alkyl-POSS-POSS-Alkyl" sequence; while on the contrary, the layer is in "Alkyl-POSS" sequence.

实验研究表明，通过调整POSS和表面活性剂的物质的量比例可以改变片层结构，发现当POSS成分大大过量的时候，片层重复单元按照&烷基-POSS-POSS-烷基&顺序排列，对应较大的层间距；当表面活性剂成分大大过量的时候，片层重复单元按照&烷基-POSS&顺序排列，对应较小的层间距。

By comparing the electrodeposition rate and the particlesize of nanometer Ag film prepared by methyl sulfonic acid silver system with those of nanometer Ag film prepared by nitrate silver system under the same conditions, it is found that the particlesize of nanometer Ag film electrodeposited with nitrate silver is smaller and the growth rate of the nitrate silver nanometer film is faster. During the experiment, the silver grain was smaller and the distribution was more uniform in the nitrate silver electrolyte than in the methylsulfic silver electrolyte.

通过对甲磺酸银体系和硝酸银体系中纳米银膜的电沉积速率及纳米银膜颗粒进行比较发现，相同条件下硝酸银体系得到的纳米膜晶粒粒径比较小，膜的生长速率较快。

I am accused of being overreligious," she said in her quiet, frank manner,"but that does not prevent me thinking the children very cruel who obstinately commit such suicide.""

客人们在卡罗利娜·埃凯家里，举止就文雅一些，因为卡罗利娜的母亲治家很严厉。

Designed by French fashion house Herm è s, this elegant uniform was manufactured in our home, Hong Kong, and was the first without a hat.

由著名品牌 Herm è s 设计，这件高贵的制服是香港本土制造，是我们第一套不配帽子的制服。