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substituted相关的网络例句

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Based on this core reaction, two significant libraries of isoxazole and triazole substituted methane derivatives and triazole substituted triazine derivatives were synthesized concisely from the inexpensive and readily obtainable small molecular starting materials which had been used in previous two chapters mostly.

以此为核心,以价廉易得的小分子原料通过数步反应,分别合成了异噁唑、三氮唑杂环取代的甲烷衍生物和三嗪联三氮唑杂环衍生物这两个比较有意义的小分子化合物库,达到了分子的多样化。

This invention pertains to compounds of Formula I, their N-oxides and suitable salts wherein A is O or S; G is a 5- or 6-membered heteroaromatic ring or a 5- or 6-membered nonaromatic heterocyclic ring optionally including one or two ring members selected from the group consisting of C, SO or S2, each ring optionally substituted with from one to four R; each J is independently a phenyl ring, a 5- or 6-membered heteroaromatic ring or an aromatic 8-, 9- or 10-membered fused carbobicyclic or heterobicyclic ring system, wherein each ring or ring system is optionally substituted with from one to four R; and R, R, R, R and n are as defined in the disclosure.

本发明涉及式I的化合物、其N-氧化物和适当盐,其中A是O或S;G是任选地包含一个或两个独立选自C、SO或S 2 的环成员的5-或6-员杂芳环或5-或6-员非芳族杂环,各环任选地被1-4个R 2 取代;各J独立地是苯环,5-或6-员杂芳环或芳族8-,9-或10-员稠合的碳二环或杂二环系,其中各环或环系任选地被1-4个R 3 取代;R 1 ,R 2 ,R 3 ,R 4 和n如说明书中定义。

Tetra-O-benzyl-D-glucose reacted with bromine to give glucosylbromide. It reacted with hydroxyl phenyl acetonitrile or hydroxyl benzaldehyde to give substituted ph- enylacetonitrile or substituted benzaldehyde.11 New stilbenes were synthesized possessing 2,3,4,6-tetra-O-benzyl-D-glucoside by condensation reaction with pheny lacetonitrile or benzaldehyde, which had potential biological activity and would be sieved in the future.

由2,3,4,6-四芐氧基葡萄糖作为中间体,首先制备出的溴代糖和含有羟基的苯甲醛和苯乙反应制备出含有糖的取代苯甲醛和取代苯乙,再和简单的苯乙或苯甲醛缩合反应生成11种具有潜在的生物活性且含有2,3,4,6-四芐氧基葡萄糖的类化合物,这些新化合物有待于进一步进行药理活性筛选。

Four new compounds,substituted-benzyloxyindole-3-formaldehyde-(4′-nitro) phenylhydrazone ,were synthesized by the condensation of 4-nitrophenylhydrazine with substituted-benzyloxyindole-3-formaldehyde in ethanol.

以取代苄氧基吲哚-3-甲醛和4-硝基苯肼为原料,乙醇为溶剂,通过缩合脱水反应合成了4个新化合物——取代苄氧基吲哚-3-甲醛-(4′-硝基)苯腙,其结构经1H NMR,IR,MS和元素分析表征。

In order to improve the electrocatalytic activity of the anode in the Direct Methanol Feul Cell, three kinds of transition metal substituted phosphomolybdic acid modified platinum electrodes were prepared, and the electrochemical behavior in the sulphuric acid solution of transition metal substituted phosphomolybdic acid modified platinum electrodes and their electrocatalytic effects of methanol oxidation were studyed. The anti-poison effect to carbon monoxide of the prepared electrodes were studied by the carbon monoxide adsorbing.

为了提高直接甲醇燃料电池阳极催化活性,本文研究了三种过渡金属取代磷钼酸修饰铂电极在硫酸溶液中的电化学行为及对甲醇的电催化氧化作用,并利用一氧化碳吸附实验评价了三种过渡金属取代磷钼酸修饰铂电极的抗一氧化碳毒化性能。

The obtained potential energy curves disclosed that a four-state cycle existed in the ground and excited states. It was also found that the activation energy for the methyl transfer was higher compared to the phenyl transfer, which was consistent to the experimental results that the photoisomerization of the phenyl substituted derivative was more rapid than the methyl substituted derivatives.

对反应势能面的研究发现,在光异构化反应中化合物M21和M21、M31的基态和激发态虽然都可以构成四能级反应过程,但由于M21异构化过程的活化能较高,使其所构成的四能级反应难以进行,这就从理论上解释了迁移基团为甲基的M21变色性能低于迁移基团为苯基的M31的实验结果。

In the study of UV absorbing test, polyhydroxy substituted N-benzoylserotonin derivatives (compound 1-10) shows better ability to absorb UV and shows wider range of absorbing UVB than control group, octyl salicylate. With respect to octyl salicylate, octyl salicylate can abosorb the highest wavelength up to 306 nm under UVB (wavelength ranges 280 nm ~320 nm), and the ε is 4.03 × 103 ㎝-1M-1. However, the ε of polyhydroxy substituted N-benzoylserotonin derivatives (compound 1-10) under 306 nm range 4.14 × 103 ~ 11.45 × 103㎝-1M-1. It is reasonable that the compounds in this study can not only absorb the individual wavelength amoung the wavelenght of UVB, but also absorb wider range of wavelength.

在紫外线可见光吸收测试结果显示,相较於对照组水杨酸辛酯在UVB波长(280 ~ 320 nm)范围最大吸收波长为306 nm,其莫耳吸收系数为4.03 × 103 ㎝-1M-1,而多羟基取代之N-色洛冬宁苯甲醯胺衍生物(化合物1 ~ 10)在306 nm的莫耳吸收系数介於4.14 × 103 ~ 11.45 × 103㎝-1M-1,其吸收紫外线的效果皆优於对照组水杨酸辛酯,且其在UVB波长的范围吸收波长的光谱也较宽广,可知每个化合物并非只是对UVB波长范围内的单一波长有吸收度,而是对UVB波长范围具有较宽广的光谱吸收。

Thirdly, The preparation of 3-aryl-5-substituted-ethenyl isoxazoles and l-isoxazolyl-2-isoxazolinyl substituted-ethenes was developed through 1, 3-dipolar cycloaddition of nitrile oxides,α-alkylation reaction and another 1, 3-dipolar cycloaddition of nitrile oxides based on polystyrene-supported propargyl selenide.

三、从聚苯乙烯负载的炔丙基硒醚出发,经过腈氧化物的1,3-偶极环加成反应、α-烷基化反应和腈氧化物的1,3-偶极环加成反应固相分别合成了3-芳基5-取代--乙烯基异噁唑和1—异噁唑—2—异噁唑啉取代的-乙烯。

Fourthly, The preparation of 1 -triazolyl-2-isoxazolinyl substituted-ethenes was developed through an one-pot 1, 3-dipolar cycloaddition of NaN_3 and RI,α-alkylation reaction of substituted allyl bromides and 1, 3-dipolar cycloaddition of nitrile oxidesbased on polystyrene-supported propargyl selenide.

四、从聚苯乙烯负载的炔丙基硒醚出发,通过与叠氮化钠和碘化物的一锅法1,3-偶极环加成反应、取代烯丙基溴的α-烷基化反应和腈氧化物的1,3-偶极环加成反应固相合成了1—三唑—2—异噁唑啉取代的-乙烯。

A series of α-(fluoro-substituted phenyl)pyridines have been synthesized by means of a palladium-catalyzed cross-coupling reaction between fluoro-substituted phenylboronic acid and 2-bromopyridine or its derivatives. The reactivities of the phenylboronic acids containing di- and tri-fluoro substituents with α-pyridyl bromide were investigated in different catalyst systems.

利用钯催化的SUZUKI偶联反应,以氟取代的苯硼酸与2-溴吡啶为原料合成了系列新的邻吡啶芳香化合物,研究了二及三氟取代的苯硼酸与溴代吡啶在不同催化体系中的反应性质。

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