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substituted相关的网络例句

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The beta-thioalkoxyalcohols could be obtained in good yields by the reaction of dialkyl-substituted propargylic dithioacetals with a series of carbonyl compounds.

我们发现在铁触媒和格林那试剂的存在下,利用双烷基取代炔丙基硫缩酮和羰基化合物反应生成的beta-硫烷氧基醇,可以进行不常见的beta-氧消去反应,而得到烯炔衍生物。

However, alkyl-substituted propargylic dithioacetals could be synthesized by the displacement reaction of the corresponding terminal alkynes with alkyl iodides.

烷基取代的炔丙基硫缩酮衍生物,则能利用相对应的末端炔和碘烷亲电基进行取代反应所获得。

In previous results, Alkyl substituted propargylic dithioacetals treating with butyl lithium then were allowed to react with carbonyl compounds to form homopropargylic alcohol with high yields and highly regioselective.

在本实验室先前的研究中发现,烷基取代炔丙基硫缩酮与正丁基锂进行开环反应后,若是与羰基化合物反应,能够以高产率、具位向选择性的生成高炔丙基醇。

In the presence of palladium catalyst and triphenylphosphine, alkynyl Grignards or alkynyllithiums could successfully couple with alkyl bromides and iodides. Aryl-substituted propargylic dithioacetals could also be obtained by this strategy.

在钯触媒和三苯基磷的存在下,我们可利用炔基格林那试剂或炔基锂和简单的卤烷进行偶合,而这样的反应条件也能应用在苯基取代炔丙基硫缩酮衍生物的合成上。

The present invention is directed to substituted propylamine derivatives of formula I or a pharmaceutically acceptable salt thereof, compositions containing these derivatives, and methods of their use for the prevention and treatment of conditions ameliorated by monoamine reuptake including, inter alia, vasomotor symptoms, sexual dysfunction, gastrointestinal and genitourinary disorders, chronic fatigue syndrome, fibromylagia syndrome, nervous system disorders, and combinations thereof, particularly those conditions selected from the group consisting of major depressive disorder, vasomotor symptoms, stress and urge urinary incontinence, fibromyalgia, pain, diabetic neuropathy, and combinations thereof.

本发明涉及式I的取代丙胺衍生物或其医药学上可接受的盐、含有这些衍生物的组合物、和其用于预防和治疗通过单胺再摄取改善的病状的使用方法,所述病状尤其包括血管舒缩症状、性功能障碍、胃肠道和泌尿生殖道病症、慢性疲劳综合症、纤维肌痛综合症、神经系统病症和其组合,特别是那些选自由严重抑郁症、血管舒缩症状、压力性和急迫性尿失禁、纤维肌痛、疼痛、糖尿病性神经病变和其组合组成的群组的病状。

In order to discuss the regioselectivity of nitrile oxide 1,3-dipolar cycloaddition to propyne , 1,3-dipolar cycloaddition reaction of substituted nitrile oxide (RCNO, R=F, NO2, OCH3, OH, COOCH3, CHO, CONH2, H, CH3) with propyne was studied using density functional theory at the 6-311++G** level, and the reaction rates were calculated at different temperature from 200 to 400 K.

用密度泛函B3LYP/6-311++G**方法研究了氧化腈(RCNO,R=F,NO2,OCH3,OH,COOCH3,CHO,CONH2,H,CH3)与丙炔的1,3-偶极环加成反应,并且计算了不同温度下的反应速率常数,讨论了氧化腈上不同取代基R的取代效应和温度对反应区域选择性的影响。

We generalized the above model of the point defect to Cd〓Zn〓Te, which was taken as ideal cation substituted pseudobinary alloy.

把二元化合物CdTe的点缺陷模型加以推广,建立了三元化合物Cd〓Zn〓Te的点缺陷模型。

Biaryl substituted pyrazole compounds are sodium channel blockers useful for the treatment of pain and other conditions.

联芳基取代吡唑化合物为钠通道阻滞剂,用于治疗疼痛和其它病症。

In order to find new pyrazole leading compounds, 14 1--4-(pyrazol- 5-ylcarbony)semicarbazide devivatives were synthesized from 4-chloro-3-ethyl-1-methyl-5-pyrazole car-bonydrazide and substituted phenylisocyanate.

为了寻求新的吡唑先导化合物,用4-氯-1-甲基-3-乙基-5-吡唑甲酰肼与取代苯基异氰酸酯反应得到了14个新的1-吡唑酰基-4-芳基氨基脲类化合物。

When a strong electron-withdrawing group (e.g., nitrobenzene group) is located on the position 3, the twisted configuration between pyrazoline ring and the substituted phenyl group on the position 3 is the fluorescence emission configuration of this kind of 2-pyrazolines, and the planar configuration between two moieties is also the best non-radiative decay configuration of these compounds.

对于C3位取代基为强的拉电子基团的化合物,C3位取代基与吡唑啉环相扭曲的构象是化合物分子的发光构象,而两者处于同一平面的构象是化合物的最佳非辐射衰变构象,与N1所联取代基的旋转扭曲无关。

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