查询词典 sterically

To identify cytoskeletal proteins that change conformation or assembly within stressed cells, in situ labeling of sterically shielded cysteines with fluorophores was analyzed by fluorescence imaging, quantitative mass spectrometry, and sequential two-dye labeling.

从蛋白质的氨基酸序列来预测它的三维结构是计算生物学和计算化学长期面临的挑战。研究人员40多年前就知道蛋白质的结构完全是由其氨基酸序列决定的，但是用序列信息来做结构的预测极为困难。

There are more and more acid gas components,〓 and 〓, from petroleum refinery gasesbecause China will import mass sour crude oil in the near future. In order to improve theselective absorption behavior of desulfurizer, new sterically hindered amine desulfurizers aredeveloped.

本论文以处理炼油厂加工进口含硫原油产生的大量含〓和〓的酸性炼厂气为背景，开发新型位阻胺脱硫剂以达到选择性脱除炼厂气中〓的目的。

Aim To prepare sterically stabilized liposomes modified with chimeric TNT-3 monoclonal antibody （chTNT-3） and investigate their immunoreactivity and in vitro targeting.

目的 研究人鼠嵌合抗肿瘤细胞核单抗（chTNT-3）-空间稳定脂质体的制备方法、免疫活性及体外靶向性。

LY series desulfurizers are synthesized by sterically hindered fatty amine, ethylene oxide andpropylene oxide, which is a ring-splitting polymerization reaction at the catalysts.

采用带有空间位阻基团的脂肪胺在催化剂的作用下与环氧丙烷和环氧乙烷开环聚合，合成LY系列脱硫剂。

In the presence of DMSO as co-solvent and under vigorous agitation, baker\'s yeast in water was found to reduce substituted fluorenones to the corresponding fluorenols in good to excellent enantioselectivies (52%~ 100% ee). The experimental results clearly revealed that when mass transfer limitations are overcome, baker\'s yeast is able to reduce even highly sterically hindered ketones, such as substituted fluorenones.

在强烈的搅拌、并使用DMSO作为底物助溶剂的反应条件下，面包酵母对取代芴酮显示出较高得还原活性，得到立体选择性很高的相应的芴醇(52%～100%ee)。

So, there is an especial significance in the case of energy sources shortage and huge energy consumption nowadays. Based on reaction mechanism of alkanolamines with acid gases in this work, selective absorption of H_2S from mixed-gas streams into the aqueous solution of blended amines of MDEA-TBEE has been studied using a static and a dynamic evaluation setup, respectively. TBEE, a severe sterically hindered amine, was added into MDEA to form the blended amines.

开发高效活化剂是酸性气体吸收领域重要的研究方向之一，研究工作采用一乙醇胺为原料，氢气为反应氛围，低压下有机气相通过管式催化反应器合成活化剂哌嗪，考察合成催化剂组成和操作参数对合成反应的影响；将合成产物应用于膜吸收装置和再生装置上考察其吸收和解吸CO_2的性能。

Continuous determination of a polymer chain end group(initiating and chain growth species) at various times by electrospray ionization mass spectrometry indicates that the sterically hindered strong organic base predominately plays an initiator of polymer-chain growth in the copolymerization process.

利用飞行时间质谱对聚合物链端进行了跟踪检测，直接观察到了聚合反应的引发及链增长过程，证明大位阻有机碱在共聚反应过程中对聚合物的链增长起着重要的引发作用。

Second,the sterically demanding substituted magnesium alcoholates can be prepared from dialkylmagnesiums R_2Mg and alcohol.The main disadvantage of this synthesis route lies in the fact that relative expensive dialkyl magnesium compounds,such as Et_2Mg for example,have to be used as starting materials.For this problem,a convenient preparation route of pure dialkylmagnesium from a Grignard reagent.

二、烷基镁法：具有空间位阻效应的仲醇镁和叔醇镁可以直接用烷基镁R_2Mg和醇进行反应来制备，这条路线的主要缺点是烷基镁比较昂贵，为了解决这个问题，本文采用格式试剂来制备烷基镁，将制得的烷基镁与叔丁醇反应制得叔丁醇镁。

The arylation showed high regioselectivity and only occurred on the less sterically hinderd ortho-C—H bond. The reaction could be compatible to diverse functional groups such as CH3, CH3O, and CH3CO, as well as Br and Cl substituents, which would permit to be functionalized further to construct new compounds with more complicated structures.

实验结果表明，反应表现出明显的区域选择性，芳基化只发生在空间位阻较小的sp2 C—H键上，反应可以采用多种取代基(如CH3O， CH3CO， Br和Cl)进行，这有助于通过进一步反应构建更为复杂的新化合物。

The electron-rich and sterically hindered ligand 9d provides the best enantioselectivities (up to 97.8 % ee) for various chalcones as the substrates.

其中富电子且空间位阻较大的配体gd对查耳酮类底物表现了最好的手性诱导能力，加成产物的ee值达到94.7一97.8%。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。