查询词典 stereochemical

On the basis of our research on Stellera chamaejasme L. and the literatures, the spectral and structural characteristics, the stereochemical researching methods, the distribution in the 3 subtribes of Thymeleaceae and chemotaxonomy of biflavonoids were concluded. We found that biflavonoids played a very important role in the chemotaxonomy of Thymelaeaceous plants.

通过对瑞香狼毒中双黄酮类化合物的研究，结合文献，总结了瑞香科中双黄酮类化合物的结构特点、波谱规律和立体化学研究方法；同时对双黄酮类化合物在瑞香科植物中的分布规律进行了总结，发现双黄酮类化合物在瑞香科的植物化学分类学方面具有重要作用。

The structures and properties of the compounds are profoundly affected by the unusual stereochemical effects of the so-called lone-pair electrons in heavy p-block elements in lower oxidation states.

其与过渡金属，特别是前过渡金属的复合氧化物在催化、快离子导体、铁电材料、压电材料、光学材料等领域具有重要的实际应用和广阔的应用前景。

The stereochemical structures of two new compounds, 5-(3-chlorophenyl)-2-furfur-aldehyde-N-4-methylphenyloxyacetylhydrazone and 5-(3-chlorophenyl)-2-furfuraldehyde-N-4-nitrophenyloxyacetylhydrazone, were determined by DPFGSE-NOE experiments performed in DMSO-d\-6 at 25 ℃ and variable-temperature ~1H NMR The ~1H chemical shifts of the compounds were completely assigned at 25 ℃ and 90

利用变温实验和DPFGSE NOE实验，确定了 5 (3 氯苯基) 2 呋喃甲醛 N 4 甲基苯氧乙酰腙和5 (3 氯苯基) 2 呋喃甲醛 N 4 硝基苯氧乙酰腙两个新化合物25 ℃时在二甲基亚砜中的空间构型，并对这两个新化合物在 25 ℃和 90 ℃时的质子的化学位移进行了全归属。

Objectives 1. To observe the course, anastomosis, distribution, stereochemical structure of the arteries in the anterolateral thigh flap and provid morphology for clinic application.

目的 1。观测股前外侧区体被组织穿支动脉的走行、吻合方式、立体结构特点等，为临床修薄皮瓣应用提供形态学依据。

The stereochemical studies of PPCs derived from the copolymerization of CO_2 with chiral PO at various conditions reveal that the polymer enantioselectivity is proportional to its head-to-tail linkages with regard to regioselective ring-opening of the epoxide.

通过研究聚碳酸酯的立体化学发现聚合物的对映体选择性与环氧丙烷区域选择性开环存在一定的影响作用。

The present invention concerns a compound having the formula a N-oxide form, a stereochemical isomer, racemic mixture, salt prodrug, ester or metabolite thereof.

本发明涉及具有式的化合物、其N-氧化物形式、立体化学异构体、外消旋混合物、盐、前体药物、酯或代谢物。

The stereochemical effect of the chiral amino acid residues on the formation of penta-coordinate phosphorus intermolecular mixed carboxylic-phosphoric anhydride from N-phosphorylamino acids was studied with density functional theory calculations at B3LYP/6-311G level.

用密度泛函方法在B3LYP/6-311G水平上对N-磷酰化氨基酸生成五配位磷酸羧酸混酐反应中手性氨基酸残基侧链的立体化学效应进行了研究。

Organic matrixs coming from cells play role in nucleation, growth, morphology, polymorphology of inorganic materials. This control of organic matrixs are mainly behaved by the interfaction between organic matrix and inorganic materials .The processing of organic matrix controlling inorganic material is called as molecular recognition. The mechanism of organic-inorganic molecular recognition contains three facts such as electrostatic attraction, lattice geometry matching and stereochemical complimentary.

细胞分泌的有机基质在无机矿物的成核，生长，形貌，多型和结晶学定向等过程中起到了调控作用，基质对矿化的这种调控作用具体表现在有机或生物大分子和无机离子在界面上的相互作用，有机质对无机晶体的成核，生长，晶形及结晶学定向等的控制过程称为分子识别，有机-无机界面分子识别机制主要包括静电作用，晶格几何匹配和立体化学互补三个方面。

This Ph.D. thesis describes further studies on theformation of fluorinated phosphorus ylide-anions resultingfrom organometallics and their reactions, stereochemistry andapplications in organic synthesis. We found that inverse stereochemical results wereobserved in the reaction of the fluorinated ylide-anions withvarious proton donors.

本博士论文进一步研究了用有机金属试剂对含氟膦叶立德的亲核加成导致的叶立德阴离子的反应性、立体选择性及其在有机合成中的应用：首次发现含氟叶立德阴离子在与不同的质子化试剂作用时，反应呈现完全相反的立体化学结果。

Structures of seven compounds were elucidated mainly by the use of spectroscopic methods, especially by detailed analyses of 〓 and 〓 NMR spectra with the aid of 2D NMR spectroscopy including 〓 COSY,〓 COSY, HMQC, HMBC, COLOC, and MS techniques including EI-, CI-, SI-, ESI-MS and HR-EI-MS. Stereochemical structures of some of them were also determined on the basis of results of their NOEDS, NOESY and coupling relation.

利用现代的各种波谱学方法，特别是在确定未知化合物结构中起重要作用的各种NMR技术（-维〓、〓 NMR、DEPT、NOEDS和二维〓COSY、〓COSY、HMQC、HMBC、COLOC、NOESY谱等）和MS技术（EI-、CI-、SI-、ESI-MS及HR-EI-MS等），鉴定了这7个化合物的平面结构和部分立体结构。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失