查询词典 stannous

The star shaped block copolymers were prepared by ring opening polymerization of ε caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε己内酯开环聚合，制备了PEG b PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了 3种水溶性大分子单体。

Inside benzene or toluene solvent, in the presence of stannous octoate as catalyst and under the conditions of no water, no oxygen, heating and stirring, MPEG and aliphatic cyclic monomer are ring-opening polymerized to obtain binary block MPEG-aliphatic polyester copolymer.

聚乙二醇单甲醚和脂肪族环酯单体，在苯或甲苯溶剂中，在无水无氧，加热和搅拌的条件下，用辛酸亚锡为催化剂，开环聚合得到聚乙二醇单甲醚-脂肪族聚酯二嵌段共聚物。

Due to the increasingly deep concerns about the cytotoxicity of stannous octoate, which is the most widely used catalyst for synthesizing polyesters derived from lactides (L-LA, D, L-LA, GA) via ring opening polymerization, a lot of new metal complexes of relatively low toxicity including Schiff base–Al complexes, Red-Al were developed and used to initiate the living, stereo-specific, and/or stereo-selective ROP of lactides.

由于合成聚乳酸类生物医用降解材料的最常用的催化剂辛酸亚锡 Sn2的细胞毒性问题已在世界范围内引起日益深切的关注，近年来国内外学者已研究开发出许多性能优异的低毒、非锡金属络合物催化剂（如：位阻西佛碱-Al 络合物， Red-Al 等）用于催化交酯类单体的活性、立构专一性及立构选择性聚合反应。

The aim of this study was to develop a novel amphiphilic functional block poly(ε-caprolactone) bearing ketone groups MPEG-b-P(OPD-co-CL. 2-oxepane-1, 5-dione was copolymerized with ε-caprolatone in which methoxy poly (MPEG, Mn=5 000) and stannous octoate were used as initiator and catalyst, respectively. The syntheses were conducted by bulk and solution polymerization. 1H NMR results showed that peak position and splitting of the polymers synthesized through solution polymerization were consistent with theoretical data, demonstrating the products were designed block copolymers. While in the bulk polymerization, polymer peak position was changed due to their high reaction temperature, suggesting their structural variation.

将带有羰基官能团的4-羰基己内酯和ε-己内酯分别在甲氧基聚乙二醇(MPEG，Mn=5 000)为引发剂，异辛酸亚锡为催化剂溶液和本体体系中开环聚合，合成了两亲性侧基带有羰基官能团的聚己内酯嵌段共聚物MPEG-b-P(OPD-co-CL.1H NMR结果表明采用溶液聚合法合成的聚合物各峰的峰位置和分裂情况与理论一致，证明了产物是实验所设计的嵌段共聚物，而采用本体聚合法合成的聚合物由于温度的影响，聚合物各峰的峰位置发生了变化，说明其结构发生了变化；差示扫描量热法分析结果表明随着OPD单体含量的增加，聚合物的熔点，玻璃化转变温度和熔融焓增加；热失重测试结果表明OPD单体的引入增加了聚合物的热敏感性。

Styrene-dimethylsiloxane block copolymers with types of andn were, synthesized under the existence of catalyst, lithium naphthalene, and couplins asent, stannous octoate or olisomer of dichlorodimethysiloxane.

本文用萘锂作为催化剂，辛酸亚锡或二氯二甲基硅氧烷的低聚物为扩链剂，设计和合成了分子量为6～13万苯乙烯与二甲基硅氧烷的結构单元数之比为1.0～9.1的嵌段共聚物和_n。

Microwave-assisted ring-opening polymerizations of DTC were carried successfully with lanthanum chloride (LaCl3) and stannous octoate Sn(Oct2 ascatalyst and the highest weight average molar mass of the obtained PDTC were 66800g/mol and 14600g/mol, respectively.

分别在氯化镧和异辛酸亚锡的催化下，DTC的微波开环聚合反应可以顺利地进行，所得PDTC的重均分子量分别达到66800g／mol和14600g／mol，二者比较而言，氯化镧的催化活性更高。

Linear and star-shaped hydroxy-terminated polys were synthesized by reacting L-lactide with co-initiators such as poly,hydroxyethyl methycrylate,trimethylolpropane,mannitol and sorbierite in the presence of stannous octoate as catalyst.

以辛酸亚锡为催化剂，分别以聚乙二醇、甲基丙烯酸羟乙酯、三羟甲基丙烷、季戊四醇、甘露醇和山梨醇等和L-丙交酯反应，得到末端为羟基的线形和星形聚L-丙交酯。

The Polyether Polyurethane elastomer were prepared from hydroxyle-terminated polybutadiene, isophorone diisocyanate, 1,4-butylcne glycol, stannous octoate and SiO_2 in direction.

以端羟基聚丁二烯、异佛尔酮二异氰酸酯、1，4-丁二醇、白碳黑、辛酸亚锡等为原料，采用一步法制备了聚烯烃型聚氨酯弹性体材料。

The grafting of polycaprolcatone on starch by ring-opening polymerization of e -caprolactone was initiated from the starch hydroxyl functions in the presence of a catalyst such as stannous octoate Sn(0ct2, Dibutyltin dilaurate or titanium tetrabutoxide. The grafting ration could reach 16%. IR, X-ray diffraction and DSC were used to investigate the grafting-polymer.

在辛酸亚锡Sn(Oct_2、二月桂酸二丁基锡和钛酸丁酯等催化剂作用下，淀粉羟基引发己内酯单体进行配位聚合，淀粉接枝率可以达到16％，并通过红外光谱、X—ray衍射及DSC等测试手段对反应产物进行了表征。

The star-shaped block copolymers were prepared by ring-opening polymerization of ε-caprolactone in the presence of multiarm PEG using stannous octoate as a catalyst.Based on these star-shaped PEG- b -PCL,soluble macromers terminated with acrylate groups were synthesized.

以辛酸亚锡为催化剂，通过星型聚乙二醇引发ε-己内酯开环聚合，制备了PEG- b -PCL嵌段共聚物，进一步以丙烯酸酯封端，合成了3种水溶性大分子单体。

Plunder melds and run with this jewel!

掠夺melds和运行与此宝石！

My dream is to be a crazy growing tree and extend at the edge between the city and the forest.

此刻，也许正是在通往天国的路上，我体验着这白色的晕旋。