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In the present work, diatomaceous silica samples in some typical deposits of China were studied by using of combined analyses of chemical and spectroscopic methods.

本项目以我国的典型硅藻质二氧化硅样品为研究对象，采用化学分析法与现代谱学新技术相结合的方法，研究硅藻质二氧化硅表面功能基的性质及其与硅藻种属、微结构、微形貌间的关系，分析功能基活性产生的机理及控制因素。

The UV and IR spectroscopic studies of the monomer films showed that the photoreaction ratio of monomer (about 50%) was higher than the corresponding photosensitive polymer (about 10%, PVCi). The polarized IR spectra proved that obvious anisotropic absorption was displayed in the irradiated photosensitive film. With polarizing microscopy method, we found that these kinds of photoalignment films exhibited good alignment ability, and the stability of the photoalignment film could reach about 100℃. 2 A photosensitive self-assembled monolayer was fabricated that contained photo-cycloadditable groups, such as, coumarin and cinnamate. The reaction process were detected by contact angle method because the IR absorption of monolayer was very weak. The photosensitive self-assembled monolayer promote uniform alignment of nematic liquid crystals by LPUV, and it thermal stability could reach about 130℃. 3 A cationic bolaform amphiphiles was synthesized that had two photosensitive double bonds, and can be polymerized by ultraviolet. A layer-by-layer self-assembled deposition film was prepared in aqueous solution by using this material and poly (sodium 4-styrenesulfonate). The UV-Vis. spectra proved that the multilayers film was uniform and layer-by-layer. When LPUV irradiated the film, the photopolymerizable double bond underwent [2+2] cycloaddition, and the production of the reaction distributed along the polarized direction of incident LPUV. Polarized UV-Vis. spectra indicated that the irradiated self-assembled multiplayer film was anisotropic, and the dichromic ration is about 0.09, it is higher than the spin-coating method of photosensitive polymer or monomer. We used this anisotropic film as alignment layer of nematic liquid crystals, and obtained a uniform and stability alignment result, the static contrast ratio is about 100, which is very close to application of liquid crystal device. This thesis is an instance that the photochemical material was used in the physics region of liquid crystals, the route that was from photosensitive monomer, self-assembled monolayer film to self-assembled multiplayer film was undergone, by this logical research method photoailgnment of liquid crystal was extended and consummated.

围绕上述思路开展了如下工作：1合成了三种可进行光二聚反应的光敏小分子单体，LPUV 辐照制作了光控取向膜；用紫外-可见光谱法和红外光谱法分析了薄膜中的光化学反应，发现小分子的光反应程度可达到50%以上，至少比光敏高分子高出5倍；薄膜的偏振红外光谱证实，经过LPUV 辐照后薄膜出现了明显的各向异性；将小分子光控取向膜制成液晶器件，在偏光显微镜下观察看到均匀一致的液晶取向；并且热稳定性达到100℃左右，接近实用化要求。2制备了含肉桂酸、香豆素基团的自组装单层膜；采用接触角的方法监测自组装反应的动力学过程；紫外-可见光谱证实了自组装单层膜在石英基板表面形成；自组装单层膜经LPUV 辐照后能诱导液晶均匀取向，而且热稳定性可达130℃，热稳定性进一步提高。3合成了含有光敏双键的双季铵盐，在水溶液状态下将它和聚乙烯基苯磺酸钠沉积生成layer-by-layer 自组装多层膜，紫外-可见光谱证实这是一个逐层均匀的沉积；在LPUV 照射下，自组装膜中的光敏双键按照偏振方向发生[2+2]环加成反应，形成取向膜，用二向色性值评价的分子取向度高于高分子及小分子光控取向膜的水平；实验证明用自组装多层膜制成的液晶器件亮暗态均匀，静态对比度约为100，达到实用化器件的水平。

As a part of a search for new antitumor agents from Chinese medicinal plants, the roots of Salvia prionitis, collected in Jiangxi Province, was investigated. From the roots of this plant, a new diterpene, saprirearine (95), a new anhydride-type compound, saprionide (96), a new 7, 8-seco-abietane diterpene derivative, 7, 8-seco-paraferruginone (99), and a new 4, 5- seco-5, 10-friedo-abietane diterpenoids, 3-keto-4-hydroxysaprorthoquinone (102), have been isolated along with 6 known compounds. Their structures were established by spectroscopic methods and chemical transformation.

在对红根草的乙酸乙酯提取物进行分离，纯化和结构研究中，共得到10个化合物，其中4个是新化合物，3个新化合物具有新颖的重排松香烷型二萜骨架，新化合物99为首次从本属植物中分得的7，8-开环的松香烷型二萜醌类化合物。

Firstly,two novel rare earth complexes(CH_2=CHO)Ln~Ⅲ[2,6-_2PhNSiMe _3]_2Li_3Ln=Y(2,Yb(3)containing arylamido and enolate mixed ligands have been synthesized by treatment of 2 equiv of of 2,6-~iPr_2PhNHSiMe_3 with exces n-BuLi at -78℃in THF for 12h,followed by reaction with 1 equiv of LnCl_3at 80℃for 24h in one-pot.All the two compounds were characterized by spectroscopic methods,elemental analyses,and a single-crystal X-ray diffraction study.

首先，-78℃下，在两当量的2，6-~iPr_2PhNHSiMe_3(1)THF溶液中加入过量的n-BuLi，反应12小时，再加入一当量的LnCl_380℃下，反应24小时，一锅法合成了含胺基、乙烯醇基混合配体的新型稀土金属配合物(CH_2=CHO)Ln~Ⅲ[2，6-_2PhNSiMe_3]_2Li_3Ln=Y(2、Yb(3)，上述化合物结构经单晶X-ray衍射、光谱和元素分析表征，表明我们得到的是一类新型的三价稀土配合物。

The compounds were identified by physical and spectroscopic techniques.Result:Six compounds were isolated and identified as 4,4′-biisofraxidin(1),esculetin(2),fraxetin(3),scoparone(4),isofraxidin(5),scopoletin(6),respectively.Conclusion:Compound 1 is a novel natural product.

结果：首次从草珊瑚干燥全草中分离得到6种具有抗菌活性的香豆精类化学成分，分别为4，4′-双异嗪皮啶(4，4′-biisofraxidin，1)，秦皮乙素(esculetin，2)，秦皮素(fraxetin，3)，滨蒿内酯(scoparone，4)，异嗪皮啶(isofraxidin，5)，东莨菪内酯(scopoletin，6)。

In situ FTIR spectroscopic studies suggest that ethylene dialkoxide(-OCH_2CH_2O-) is an intermediate over polymeric Mo species while ethoxide(-OC_2H_5) might be an intermediate over the monomeric Mo species.

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These compounds are of substantial interest both inviewpoints of theory and practical applications, mainlyunder the stimulus to achieve synthetic models either foractive sites of iron-sulfur proteins or for transitionmetal catalysts. This thesis describes the synthesis, structures andconformations of 51 new iron-sulfur cluster complexes,which have been characterized by elemental analysis andstandard spectroscopic methods. In addition, single-crystalX-ray diffraction analyses were performed for 4 representa-tive new compounds. Reactivities of μ-〓 with mono- and di- Grig-nard reagents derived intermediates toward various organicelectrophilic substrates were studied, along with complexa-tion of arynyl-containing iron-sulfur clusters by 〓Thus, several bridged, non-bridged, monomeric, dimeric,homonuclear, heteronuclear iron-sullfur and iron-sulfur co-balt-carbon cluster complexes were synthesized. A novelreaction and convenient route for the synthesis in highyield of tetranuclear iron complexes 〓 containing atetracoordinated sulfur atom was discovered, whereas aplausible mechanism based on experimental results was propo-sed for the formation of the new cluster type.

鉴于有机铁硫原子簇化学在基础理论发展和应用方面的重要意义，因此我们开展了这一课题的研究，并取得以下主要成果： 1、本文共合成了51个新有机铁硫及含钴碳簇基的有机铁硫原子簇配合物，除用元素分析，NMR，IR，MS法表征其结构和构象外，还用X-光衍射技术测得四个代表性配合物的单晶结构和构象； 2、我们业已发现炔基Grignard试剂同〓可形成一种&开环&与&闭环&中间物的平衡混合物，研究该平衡混合物同各种亲电试剂的反应； 3、研究发现了一种可高产率地形成〓含〓四配位硫挛合簇的新化学反应并对此反应提出了—种有趣的反应机理； 4、首次由1，4-二溴丁烷双Grignard试剂与〓制得一种新型铁硫簇双硫阴离子活性中间体，并进而研究了它的亲核反应性能； 5、找到了通过〓的光化学反应来合成簇合物〓-〓的一条有实用价值的新路线。

The results of the CV study showed that the interaction was mainly of an electrostatic one in phosphate buffer solution at pH 4.4,whereas intercalative binding played a dominant role at pH 6.5 and 7.4 solutions.The results of the UV-Vis spectroscopic study further confirmed them.

电化学测量结果表明，在pH4.4的磷酸盐缓冲液中，AE与DNA之间以静电作用为主，而在pH6.5和7.4的磷酸盐缓冲液中，则以嵌入结合为主，紫外-可见吸收光谱也证明了这一结论。

The electrochemical results indicated that the interaction between TH and CT-DNA is in the intercalative mode in the pH 7.2 phosphate buffer solution, but both intercalative and electrostatic modes exist in the pH 6.5 phosphate buffer solution. Fluorescence spectroscopic results showed that the fluorescence intensity of TH is efficiently quenched by CT-DNA bases.

电化学测量结果表明，在pH7.2的磷酸盐缓衝溶液中，TH与CT-DNA之间的作用方式以嵌入结合为主，在pH6.5的磷酸盐缓衝溶液中，TH与CT-DNA之间的作用方式既存在嵌入结合也存在静电作用。

The main applications in the spectroscopic studies and lifetime measurement of highly ionized ions are summarized.2 The experimental principle and method of beam-foil spectroscopy are presented, andthe application of the isoelectronic sequence in the analyses of spectra is described, Cowan program for the theoretical calculations is introduced.3 The main facilities in our experiment are introduced.

本文对高离化态Cu和Ge离子的光谱进行实验研究，得到了一些新的实验结果，论文的主要内容如下： 1 回顾了束箔光谱法的发展历史，介绍了束箔光谱法的优点；总结了束箔光谱法在高离化态原子能级研究，高离化态原子能级寿命测量等方面的主要用途。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了