查询词典 solvolysis

Reactions in liquid HF are known that illustrate also amphoteric behavior, solvolysis, or complex formation .

已知在液态HF中，也能说明两性行为溶剂分解或络合物形成作用的反应。

Solvolysis is one of the important processes of biomass liquefaction.

溶剂溶解技术是生物质液化的重要过程之一。

With the size of alcohol ROH increasing, space steric block made solvolysis activity of propylene oxide decrease.

空间位阻的变化，使得环氧丙烷溶剂解反应活性随着醇类溶剂的分子增大而减小。

Effect of hydrogen peroxide concentration, acid or base adding in the raw-material, different solvent, etc. on solvolysis of propylene oxide in aqueous solutions was studied.

研究了双氧水浓度、原料中添加的酸或碱性物质和溶剂种类等因素对环氧丙烷溶剂解反应的影响。

These react with the filler surface via solvolysis generating an alcohol by-product.

这些钛酸酯是通过溶剂分解与填料表面发生反应的，还产生副产物醇。

The solvolysis activity can be inhibited remarkably if a small amount of base was added in the medium. And the activity can be enhanced if acid was added.

原料中加入碱性物质可以显著抑制TS-1催化环氧丙烷溶剂解反应的活性；原料中添加酸性物质可以增强TS-1催化环氧丙烷溶剂解反应的活性。

He minim acidity in TS-1 can catalyze the solvolysis reaction of PO to propylene glycol, 1-methoxy-2-propanol and 2-methoxy-1-propanol.

S-1中含有的微量酸中心能够导致环氧丙烷与溶剂反应生成丙二醇、1-甲氧基-2-丙醇和2-甲氧基-1-丙醇。

The results showed that hydrogen peroxide, silanols species and TiO〓 didn't have solvolysis activity of propylene oxide. While framework Al, coordinatively unsaturated Ti〓 ions as Lewis acid sites in the framework, Ti-OH and the five member ring active titanium species formed by TS-1, hydrogen peroxide and solvent can catalyze the solvolysis of propylene oxide.

研究结果表明：原料双氧水和TS-1沸石上的SiOH和TiO〓对环氧丙烷溶剂解反应无催化活性；而下列物种对环氧丙烷溶剂解反应具有催化活性：TS-1中的骨架铝，沸石骨架中配位不饱和的Ti〓形成的L酸中心，TS-1水解产生的钛羟基和由TS-1，双氧水和溶剂相互作用所生成的五元环中间活性钛物种。

During the reaction,the bromide component has been converted to catalytically inactive benzylic bromide.In pure acetic acid medium,the "catalyst failure" occurs owing to the formation of benzylic bromide while in acetic acid-water medium,the solvolysis of benzylic bromide by water maintains the catalytic activity to some extent.

反应过程中溴组分会转变为无活性的苄溴，在纯醋酸溶剂中，催化剂会因苄溴的形成而发生催化剂失活现象；在醋酸-水混合溶剂中，由于水对苄溴的溶剂化作用会使苄溴还原为溴离子，一定程度上保持了催化剂活性；并且在一定范围内，含水量的提高有益于生成醛选择性的提高，研究表明，将混合溶剂的初始含水量控制在5-10wt。

Being combining with products distribution in styrene oxidation, we propose the styrene epoxidation carry out with Ti metallacyclo intermediates, And at the same time Ti-ZSM-5 have properties both catalytic epoxidation and acid-catalysis, namely the skeletal Ti can catalyze styrene epoxidation to styrene oxide and the skeletal Ti and Al can provide Lewis acid site to cause the rearrangement of styrene oxide to phenylacetaldehyde rapidly, the solvolysis to glycols and the cleavage of C=C double bond. Ti-ZSM-5 can also provide Bronsted acid site simultaneously, which is also catalytic center for the solvolysis to glycols.

同时结合Ti-ZSM-5催化选择性氧化苯乙烯反应的产物分布结果，提出苯乙烯环氧化反应可能是通过金属有机环机理进行；Ti-ZSM-5同时具有催化环氧化和酸催化两种功能，其骨架钛可催化苯乙烯环氧化生成环氧苯乙烷，而骨架钛和骨架铝等可提供Lewis酸位使环氧苯乙烷迅速发生重排生成苯乙醛从而使其成为反应的主要产物，同时还可发生加成以及碳碳键的裂解等副反应：Ti-ZSM-5也提供Bronsted酸位，它也是生成加成产物的活性中心。

Neither the killing of Mr Zarqawi nor any breakthrough on the political front will stop the insurgency and the fratricidal murders in their tracks.

在对危险的南部地区访问时，他斥责什叶派民兵领导人对中央集权的挑衅行为。

In fact,I've got him on the satellite mobile right now.

实际上 我们已接通卫星可视电话了