查询词典 sieves

The appearance of the synthetic microspherical catalyst containing the SAPO molecular sieves is complete, the synthetic microspherical catalyst has a multi-level pore structure, and can be used for the reaction of producing alkene by converting an oxygen compound.

合成的含SAPO分子筛的微球催化剂形貌完整，且具有多级孔道结构，可以用于含氧化合物转化制烯烃反应。

ABSTRACT: Silicoaluminophosphate molecular sieves are microporous crystals with the structure of SiO2、AlO2－、PO2+ tetrahedral units.The physical—chemical properties of SAPO are not only similar to silicoalumino zeolites but also similar to some aluminophosphate zeolites.SAPO is a novel class of catalytic materials which exhibit excellent shape—selectivity、thermal and hydrothermal stability.

摘 要：磷酸硅铝分子筛是由SiO2、AlO2－、PO2＋三种四面体单元构成的微孔型晶体，它的物化性质不仅类似于硅铝沸石，同时具有某些铝磷酸盐分子筛的特性，是一种具有优异的择形选择性以及热稳定性和湿热稳定性的新催化材料。

Silicoaluminophosphate (SAPO–5) molecular sieves were synthesized by the hydrothermal method, using metakaolin with a certain degree of activity as the silicon and aluminum sources, phosphoric acid as the phosphorus source and triethylamine com- bined with hydrofluoric acid as the template agents.

以具有一定活性的偏高岭土兼作铝源与硅源、正磷酸作磷源、三乙胺和氢氟酸为复合模板剂，用水热方法合成了磷酸硅铝分子筛(SAPO–5)。

Large single crystals of many AlPO〓 or SAPO molecular sieves such as AlPO〓-41, AlPO〓-11, AlPO〓-CJ2, AlPO〓-5, SAPO-47, SAPO-11, and SAPO-31 was easily synthesized using normal synthesis method.

如AlPO〓-41、AlPO〓-11、AlPO〓-5、SAPO-47、SAPO-11、SAPO-31、AlPO〓-15、AlPO〓-CJ2、NKX-19、NKX-20。其中NKX-19、NKX-20为新合成化合物，AlPO〓-41分子筛单晶属于首次合成，AlPO〓-CJ2、AlPO〓-15是在不加任何有机模板剂的情况下合成的。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性，发现丁烷到异丁烯的一步转化无法在这一反应体系十有效实现。

In the catalytic tranformation of n-butane, Pd modified silicoaluminate molecular sieves were tested for n-butane's isomerization and dehydroismerization.

考察了硅铝分子筛为基质的双功能催化剂催化丁烷异构化的反应性能及催化丁烷一步异构脱氢反应的可能性，发现丁烷到异丁烯的一步转化无法在这一反应体系中有效实现。

MCM-41, HMS, and MSU mesoporous silica molecular sieves were prepared via S〓I〓, S〓X〓I〓, S〓I〓, and N〓I〓 assembly pathway, in which cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether was used as the template, respectively. The mesostructures were characterized and confirmed by XRD, N〓 adsorption/desorption, TG, and high resolution TEM. The difference and relationship between these mesophases were also investigated.

分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓X〓I〓、S〓I〓和N〓I〓&超分子组装模式&合成了具有MCM-41、HMS和MSU结构的介孔SiO〓分子筛，用XRD、N〓吸附/脱附、TG和高分辩TEM等方法对它们的骨架和孔道结构进行了表征，并系统地比较了这几种介孔结构之间的区别与联系

Titanium incorporated mesoporous molecular sieves Ti-MCM-41, Ti-HMS, and Ti-MSU were synthesized through S〓I〓, S〓I〓, and N〓I〓 pathways using cetylpyridium bromide, tetredecylamine, and polyoxyethylene (10) stearyl ether as the structure-directing agents, respectively. The framework structure and the titanium coordination environment of these materials were characterized by XRD, N〓 adsorption/desorption, TG, TEM, FT-1R, DR UV-Vis, and ICP-AES. It was confirmed that the titanium was highly dispersed in the silica-based framework positions, and all samples were free of extra framework titanium impurities. The catalytic performance of these titanium containing mesoporous materials was investigated in the oxidation of styrene with aqueous H〓O〓 as the oxidant.

以TEOS和TBOT为硅源和钛源，分别以溴代十六烷基吡啶、十四胺和十八烷基聚氧乙烯基醚为模板剂，通过S〓I〓、S〓I〓和N〓I〓方式合成了含钛的介孔分子筛Ti-MCM-41、Ti-HMS和Ti-MSU，用XRD、N〓吸附/脱附、TEM、FT-IR、DR UV-Vis和ICP-AES等方法对它们的骨架结构、孔道结构以及钛原子的存在方式等进行了系统表征，结果表明钛原子以高分散的形式存在于以SiO〓为基本单元的介孔分子筛的骨架结构中，制备过程中未形成聚集态的骨架外金属氧化物物种。

The silica MSU-X type mesoporous molecular sieves were synthesized by using the polyoxyethylene stearyl ether (C18EO10) as template, the tetraethyl orthosilicate and sodium silicates as silica source, respectively.

以十八烷基聚氧乙烯醚(C18EO10)为模板剂，以正硅酸乙酯和硅酸钠分别为硅源，研究了不同pH值、反应温度、反应时间、原料比等条件下，合成的全硅MSU-X型介孔分子筛产物的结构变化规律，并通过焙烧和水热处理，考察了MSU-X介孔材料的结构稳定性。

The optimum reaction condition for preparation of CoPcY is as follows: a , using CoCl2 as the exchanged salt ; b , complexation temperature of 180 ; c . complexation catalyst of NH4C1 and A1C13 .2, The unsymmetrically substituted cobalt phthalocyanine complexes were synthesized by statistical condensation of phthalic anhydride and tetrabromophthalic anhydride, and further immobilized in MCM-41 molecular sieves by zeolite synthesis method, as well as characterized by XRD,FT-IR,DRS, 1HNMRetc. The catalytic property of CoPcBrx/MCM-41was tested by cyclohexane oxidation using H2O2 or t-BOOH as oxidant.

2采用本路线制备CoPcY的最佳条件为：a、采用氯化钴作为待交换的金属盐；b、络合温度以180℃为宜；c、起始反应物为苯酐、尿素、氯化铵、氯化铝、CoY时，制备出的CoPcY的催化性能最好； 2、首次采用苯酐和四溴苯酐均相浓缩统计合成法制得了不对称取代的金属钴酞菁络合物，并采用~1HNMR、FTIR、DRS等对其进行了结构表征；此外，采用沸石合成法将其固定于MCM-41中孔分子筛，并对其催化性能进行了考察。

It has been put forward that there exists single Ball point and double Ball points on the symmetrical connecting-rod curves of equilateral mechanisms.

从鲍尔点的形成原理出发，分析对称连杆曲线上鲍尔点的产生条件，提出等边机构的对称连杆曲线上有单鲍尔点和双鲍尔点。

The factory affiliated to the Group primarily manufactures multiple-purpose pincers, baking kits, knives, scissors, kitchenware, gardening tools and beauty care kits as well as other hardware tools, the annual production value of which reaches US$ 30 million dollars.

集团所属工厂主要生产多用钳、烤具、刀具、剪刀、厨具、花园工具、美容套等五金产品，年生产总值3000万美元，产品价廉物美、选料上乘、质量保证，深受国内外客户的青睐