查询词典 salts

Most direct substitution of groups bound to an aromatic nucleus is limited to diazonium salts.

大多数连于芳核能被直接取代的基团仅限于重氮盐。

4622 Have reviewed the use of diazonium salts as substrates in cross-coupling reactions.

2006年，106、622已检讨为衬底，在使用重氮盐偶联反应。

The authors have shown that diazonium salts are attractive substrates for Heck couplings, in particular.

作者显示为啥米重氮盐偶合基板有吸引力，尤其。

In the use of diazonium salts as electrophiles in the Suzuki-Miyaura coupling there are fewer reported examples, which also goes for Stille and carbon-heteroatom couplings.

在使用重氮盐作为亲电在铃木-miyaura耦合的少报事例这也是一样的，和Stille碳-杂偶合。

A series of azobenzenes with different electron effect substituents were prepared from diazonium salts and benzoguanamine.

将含有不同取代基的芳胺在盐酸介质中进行重氮化反应，制得相应的重氮盐，再与苯代三聚氰胺发生偶合反应，最终得到一系列含有不同取代基的偶氮化合物。

Diazonium Salts as Substrates in Palladium-Catalyzed Cross-Coupling Reactions.

重氮盐类为衬底在钯催化交叉偶联反应。

The photochemical and thermal decomposition of various diphenylamine diazonium salts in ethanol were studied. It was found that, the major products in photochemical decomposition are their corresponding substituted diphenylamino-4-ethyl ethers while their corresponding diphenylamines were obtained as only one product in the case of thermal decomposition.

并研究了二苯胺型重氮盐的光、热分解，结果表明：在醇中，二苯胺型重氮盐的光解主要生成重氮基被乙氧基取代的产物；热解几乎生成唯一的重氮基被氢取代的产物。

Some of yellow azo pigments have been synthesized by coupling of acetoacetarylide derivates with different substituted nitroaniline diazonium salts. The relationship between pigment structure and shade, m. p., and thermal stability, and the, effect of addition of surface active agent on coupling reaction product have been studied. TGA and differential thermal analysis in air of the pigments and the variance of visible spectra reflectance have also been determined.

以不同取代的硝基苯胺衍生物为重氮组分与乙酰基乙酰芳胺衍生物为偶合组分，合成数种黄色颜料，观察了不同表面活性剂对其偶合产物性能的影响；研究了颜料分子结构与色光、熔点及热稳定性之间的关系；测定了颜料热重曲线及加热试样对可见光反射性能的变化。

Seven 7-styrylcoumarins were synthesized by palladium-catalyzed Heck reaction of coumarin diazonium salts with substituted styrenes.

采用钯催化香豆素重氮盐的Heck反应合成了七个7-位苯乙烯基取代香豆素化合物，该方法反应条件温和且收率较高。

A series of diazonium salts of 4-(N-methyl-N-phenylamino)-3-amino-1,8-naphthalic anhydride 5a, its naphthalimide derivative 5b, and 5e were designed and synthesized,and it was the first time to discover that aromatic radical-induced intramolecular aromatic 1, 5-hydrogen transfer was also involved in the nitrogen-contianed system during Pschorr cyclization.

实验设计合成了4--3-氨基-1，8-萘酐的重氮盐5a、其衍生物N-丁基-4--3-氨基-1，8-萘酰亚胺的重氮盐5b和N--4--3-氨基-1，8-萘酰亚胺的重氮盐5c，并首次发现了通过普朔尔环化反应以氮甲基化的氮为桥原子的体系存在着芳香自由基诱导的芳香1，5-氢转移。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。