查询词典 salicylic acid

Salicylic acid is a simple hydroxybenzene in plant. As a endogenesis signal molecule, the effects of SA on many physiological progress in plant have been paid more and more attention.

水杨酸(salicylic acid，SA)是植物体内产生的一种简单酚类物质，作为植物内源信号分子，在植物许多生理过程中的作用越来越受到重视。

Salicylic acid is a phytohormone with ubiquitous distribution among plants. It was shown to regulate a large variety of physiological processes in plant.

水杨酸(salicylic acid ，SA)具有多种生理作用，已有研究表明它能提高植物的抗热性。

In this thesis,the AM1,MNDO,MINDO/3(mainly AM1)and INDO/S-CI semiempirical MO methods were used toinvestigate the excited-state intramolecular protontransfer reactions of salicylic acid derivatives—salicylic acid,methyl salicylate,salicylaldehyde,o-hydroxyaceto-phenone,salicylamide and 3-hydroxy-picolinamide (6 conformers and 2-3 anion species);2-(2'-hydroxy-5' methylphenyl) benzotriazole(4 conformers),2-(2' hydroxyphenyl) benzimidazole (3 conformers and 3anion species),Bis-2,5-(2-benzoxazolyl)hydroquinone(3 conformers),2-(2'-hydroxyphenyl)benzothiazole(2conformers) and 7-azaindole dimer (2 conformers).Theinvestigations were described as follows.Geometry optimization,relative stability andhydrogen bonding energy First,for sylicylic acid derivative molecules,the AM1,MNDO and MINDO/3 methods were used toinvestigate ground-state geometry optimization,energies,relative stabilities and hydrogen-bondingenergies on the five kinds of the molecules(designing 6 conformers and 2-3 anion species).Comparing with experimental data,the optimizedgeometry,the order of stability,the hydrogen-bonding energies and the distances between O-O in O-H..O hydrogen bonds by AM1 method were in agreementwith the experimental data,however,the C-C bondlengths optimized by MNDO and MINDO/3 were longer,C-O and O-H bond lengths were shorter;for C-N bondlengths,the results opitimized by MNDO method werethe same as those by AM1 method,nevertheless the C-Nbond lengths given by MINDO/3 method were muchshorter.For some sylicylic acid derivatives(e.g.methyl salicylate,salicylamide),the order ofstabilities on the conformers given by MNDO andMINDO/3 methods were not in agreement with theexisting conformers deduced by experimental methods,and the hydrogen bonding energies calculated by MNDO.and MINDO/3 methods were smaller.Second,the studyon the other systems found that the optimizedgeometry of the proton-transfered product with INDOmethod could not be obtained,only could theoptimized geometry of reactant be obtained,and thecalculated hydrogen bonding energies were greater.Many results of calculation indicated that the studyon the excited-state intramolecular proton transferreaction system using AM1 method was suitable andreliable.

本论文用AM1、MNDO、MINDO/3（主要是AM1）和INDO/S-CI半经验分子轨道方法对水杨酸衍生物系列——水杨酸、水杨酸甲酯、水杨醛、O-羟基乙酰苯酮、水杨酰胺和3-羟基吡啶酰胺（6种异构体和2-3种阴离子）；2-（2'-羟基-5'-甲基苯基）苯并三〓唑（4种异构体）；2-（2'-羟基苯基）苯并咪唑（3种异构体和3种阴离子）；2，5-二间氮杂氧茚氢醌（3种异构体）；2-（2'-羟基苯基）间〓杂硫茚（2种异构体）和7-〓吲哚二体（2种异构体）的激发态分子内质子转移反应在以下几个方面进行了较系统的理论研究：几何构型优化和相对稳定性及氢键能首先以水杨酸衍生物系列分子为例，用AM1、MNDO和MINDO/3方法考察了5种分子（每种分子设计6种异构体和2-3种阴离子）的基态几何构型优化，能量、相对稳定性和氢键能计算，通过和实验数据进行比较，AM1方法给出的优化几何构型、稳定性次序、氢键能和O—H。。。O氢键的0—0距离与实验数据吻合最好，MNDO和MINDO/3方法优化的C-C键长偏长，C-O键和O-H键长偏短；对于C-N键长，MNDO和AM1优化结果差别不大，而MINDO/3给出了过短的C-N键长，MNDO和MINDO/3方法给出的有些水杨酸衍生物分子（如水杨酸甲酯和水杨酰胺）异构体的稳定性次序和实验上推测的可存在异构体结果不一致，MNDO和MINDO/3方法给出的氢键能偏低，对其他体系的研究发现INDO方法常常不能得到质子转移产物的优化几何构型，只能得到反应物的优化构型，并且估算的氢键能偏高，大量的计算结果表明AM1方法对本论文研究的激发态分子内质子转移反应体系是适宜和可靠的。

In this thesis, a conductometric chemical sensor based on salicylic acid imprinted polymer has been described, which provides the possibility and basis of using the novel P based sensor for determination of the salicylic acid.

合成了以水杨酸分子为模板的印迹高聚物，并将其成功运用于电导型化学传感器的设计和研究。

The main results are as following:(1) Arabidopsis in planta transformation were made by Agrobacterium tumefaciens carrying the activation tagging vector pSKI015 with herbicide-resistant Bar gene as a selective marker. About 12 000 independent transformant lines were acquired by the above method, from which two mutants related to plant defense response and development, asr1 (auxin and .salicylic acid responsive 1.) and dai1 (brought tolerant and obscisic acid insensitive 1) were isolated.

本文以拟南芥为实验材料，以激发标签为技术平台，构建了拟南芥的功能获得突变体库，从中筛选具有抗病、抗逆表型的突变体，克隆基因并进行基因的功能研究，取得的主要结果如下：(1)利用含激发标签质粒pSK1015的农杆菌直接转化拟南芥植株，以抗除草剂的Bar基因为筛选标记，获得了约有12000个独立转化株系的突变体库，并从中筛选到2个与抗病、抗逆和发育相关的突变体asr1(auxin and salicylic acid responsive 1)和dai1(drought tolerant and abscisic acid insensitive 1)。

The main work of this dissertation is constructing Arabidopsis gain of function mutants pool, screening mutants related to plant defense response, cloning the genes and studying their functions. The main results are as following:(1) Arabidopsis in planta transformation were made by Agrobacterium tumefaciens carrying the activation tagging vector pSKI015 with herbicide-resistant Bar gene as a selective marker. About 12000 independent transformant lines were acquired by the above method from which two mutants related to plant defense response and development, asr1 (auxin and salicylic acid responsive 1) and dai1 (drought tolerant and abscisic acid insensitive 1) were isolated.

本文以拟南芥为实验材料，以激发标签为技术平台，构建了拟南芥的功能获得突变体库，从中筛选具有抗病、抗逆表型的突变体，克隆基因并进行基因的功能研究，取得的主要结果如下：(1)利用含激发标签质粒pSKI015的农杆菌直接转化拟南芥植株，以抗除草剂的Bar基因为筛选标记，获得了约有12000个独立转化株系的突变体库，并从中筛选到2个与抗病、抗逆和发育相关的突变体asrl(auxin and salicylic acid responsive l)和dail(dought tolerant and abscisic acidinsensitive l)。

At the same time, with reference to the conditions of synthesis of methyl ester of salicylic acid, we combined ethyl ester of salicylic acid, salicylic acid-n-butyl, isobutyl salicylate, amyl salicylate, isoamyl salicylate and salicylic acid benzyl ester,besides, experimented the possibility for series of ester synthesis catalyst with Sodium bisulfate as a catalyst .

同时参照水杨酸甲酯的合成条件合成了水杨酸乙酯、水杨酸丁酯、水杨酸异丁酯、水杨酸戊酯、水杨酸异戊酯和水杨酸苄酯，实验了以硫酸氢钠为催化剂合成系列酯的可能性。

Thus we conclude that JA might be one of the potent factors, other than auxin, involving in the regulation of LR formation.3. Relationship between JA and SA on LR formation in rice seedlingMouse monoclonal antibodies against salicylic acid was produced and characterized for the first time. The McAb S2-8F, were derived from an immunogen in which 5-aminosalicylic acid (5-ASA) was conjugated to KLH (hemocyanin from keyhole limpets) through its-NH2 group.

实验结果还表明IBA对水稻幼苗侧根发生的促进作用可能并非是通过转化为吲哚乙酸(indole-3-acetic acid，IAA)而实现，因为外源IAA不能促进水稻幼苗侧根的发生，荣莉酸对水稻幼苗侧根发生的诱导效应及其与生长素和水杨酸的关系却和 IBA一样可以抑制种于根伸长及促进侧根伸长，只是IAA具有这种效应需要的浓度是IBA的20多倍。3。

Mouse monoclonal antibodies against salicylic acid was produced and characterized for the first time. The McAb S2-8F, were derived from an immunogen in which 5-aminosalicylic acid (5-ASA) was conjugated to KLH (hemocyanin from keyhole limpets) through its -NH〓 group. The antibody showed high specificity to SA and even more high specificity to 5-ASA (the cross-reaction is 144. 8％), but very little cross-reactivity with 5-sulfosalicylic acid (0.9％) and 4-aminosalicylic acid (0.3％). Other compounds structurally similar to SA, such as 4-hydroxybenzoic acid, 4-aminobenzoic acid and salicylaldoxime, were not found to exhibit any cross-reactivity.

以5-氨基水杨酸(5-aminosalicylic acid，5-ASA)的5位氨基为偶联位点，血蓝蛋白(hemocyanin from keyhole limpets，KLH)为载体合成了SA-NH-CH〓-NH-KLH，以此为免疫原免疫小鼠，利用杂交瘤融合技术得到三株可产生针对SA抗体的细胞株，并对其中编号为S2-8F的细胞株产生的单克隆抗体的特性进行了研究，发现它对SA和5-ASA具有高亲和力。

Methods The acid-base titrations was used for determination of benzoic acid and salicylic acid,UV was used for determination of salicylic acid.

用中和法测定两酸的总量，用紫外分光光度法测定水杨酸的含量，从总量中减去水杨酸的含量即为苯甲酸的含量。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。