查询词典 ruthenium

Methylpyridine-coordinated ruthenium benzylidene complex 62 shows thehighest catalytic activity. TOF=960 h~(-1) is achieved during RCM reaction of 50, TOF=4 h~(-1)is obtained during the CM reaction of acrylonitrile with 1-decene.

其中，2-甲基吡啶配位的钌卡宾配合物62的催化活性最高，在催化烯烃50闭环交互置换反应时TOF可达960 h~(-1)；催化丙烯腈与1-癸烯交叉交互置换反应时TOF达到4 h~(-1)。

Based on studies of RCM reaction of 50 and CM reaction ofacrylonitrile with 1-octene or 1-decene catalyzed by pyridine derivative-coordinatedruthenium benzylidene complexes, it can be concluded that ruthenium benzylidene complexwith the more labile dissociating ligand exhibits the higher initial activity and better catalyticperformance.

吡啶衍生物配位的钌卡宾配合物催化含氰基烯烃50闭环交互置换反应和丙烯腈与1-辛烯、1-癸烯交叉交互置换反应表明，催化剂中吡啶衍生物配体越易解离，其初活性越高，催化活性越好。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62)，1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基-(2，4-二甲基吡啶)-二氯合钌(63)中，邻位取代的吡啶作为解离配体，通过邻位基团的空间效应削弱钌-氮配位键，使配体更易解离，提高了催化剂的初活性。

It is based on a fact that oxytetracycline reacts with tris (2,2'-bipyridine) ruthenium [Ru(superscript 2+ subscript 3)] to produce enganced electrochemiluminescence signals.

基于土霉素在铂电极上增强三联吡啶合钌[Ru(上标 2+下标 3)]的电化学发光信号，并结合流动注射分析技术，建立了1种测定土霉素的电化学发光分析新方法。

A method of capillary electrophoresis with tris (2,2′-bipyridyl) ruthenium electrochemiluminescence detection has been applied to the simultaneous determination of proline and hydroxyproline in human urine.

1引言胶原蛋白中常含有丰富的脯氨酸和羟脯氨酸，其中Hyp几乎为胶原蛋白所特有。在胶原蛋白代谢中，Pro通过羟基化形成Hyp，胶原蛋白降解释放的Hyp从尿中排泄[1]。

In order to solve the backward electron transfer problem, 9 kinds of rhenium bipyridyl photosensitive dyes with different electron donating groups on the p or m-position of the pyridine rings, 2 kinds of rhenium bipyridyl and 2 kinds of ruthenium tris-bipyridyl photosensitive dyes with two tyrosine ethyl ester groups on the bipyridyl rings were designed and synthesized.

本文针对该类太阳能电池中存在的电子回传问题，设计合成了在吡啶配体的间位和对位带有不同供电基团的9种铼联吡啶光敏染料，在联吡啶配体上带有两个酪氨酸基团的2种铼联吡啶和2种钌三联吡啶光敏染料。

Zeolite Y sieves are used for preparation of ECL sensor for the first time by immobilizing tris (2, 2'-bipyridyl) ruthenium Ru (bpy 〓 in their supercages, which is achieved through the ion exchange properties of the sieves.

Ru〓固定于分子筛修饰碳糊电极的电化学发光与可更新无试剂海洛因传感器研究制备了一种能简单、快速、灵敏地测定海洛因的电化学发光传感器。

Epoxycedrane was firstly synthesized at home and abroad from α-cedrene by epoxidation of hydrogen peroxide under the catalysis of ruthenium trichloride and pyridine-2, 6-dicarboxylic acid.

以三氯化钌和2，6-二羧基吡啶为催化剂，双氧水为氧化剂，时α-柏木烯进行环氧化反应合成环氧柏木烷。本合成方法在国内外尚未见报道。

Using dichloropinacolone as starting material, ruthenium dioxide/celite as catalyst and sodium hypochlorite as oxidant, 3,3-dimethyl-2-oxo-butyric acid is prepared through hydrolization and oxidation two reaction steps.

以二氯频哪酮为起始原料， RuO2/Celite 为催化剂， NaOCl 作氧化剂，经水解、氧化两步反应制得3，3-二甲基-2-氧代丁酸。

The selective hydrogenation of crotonaldehyde to crotyl alchol was carried out over finely dispersed polyvinylpyrrolidone-stabilized ruthenium clusters.

以聚乙烯吡啶烷酮稳定的钌纳米金属簇为催化剂，进行了巴豆醛的选择性催化氢化。

The work of this paper is as follows: 1. Looking back the progressing history of the linear motor, introducing the features of the elevator driven by linear induction motor, radicating the topic of this paper "the digital frequency variable control of the elevator bi-side direct driven by linear induction motor". The research of this paper covers the conventional VVVF control, space vector based VVVF control, vector control and DTC.

本文主要开展了以下几个方面的工作： 1 回顾了直线电机发展历史，电机的驱动技术演变，特别是针对直线电机的驱动，简要介绍了直线感应电机驱动电梯的优点和不同结构类型，对传统的v／f控制，基于空间矢量法的v／f控制，矢量控制，和基于电压空间矢量的直接转矩控制进行了比较，确立了本课题的研究主题：直线感应电机双边直推式驱动电梯的全数字变频控制。

The article combines with the treatment of a superficial civil air defense work to introduce how the grouting method to improve the performance of the backfill soil.

文章从治理漂浮人防工事的角度提出了注浆技术在改善回填土性质方面的应用，并详细阐述了注浆技术的施工流程。