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The atomic resolved density of state shows that there is density of Ru on the HOMOs. All the density is localized on the ammine, which reveals that the excited electrons in the Ru complex are delocalized over the ammine ligand.

首先原子分辨的态密度显示HOMO上的密度主要在Ru上，LUMO 上的态密度在ammine上，这说明Ru上激发的电子会转移到ammine配体上。

The initial apparent rate constant, reaction order in term of Ru(superscript 3+)+ or (superscript 3+) concentration, equilibrium constant for the reaction of bipyridyl and Ru(superscript 3+) or (superscript 3+) in the presence of hydroxylamine hydrogenchloride were determined.

在盐酸羟胺存在下，测定了Ru(上标 3+)和(上标 3+)与bipy的反应表观速率常数、浓度级次及反应平衡常数。

The most significant improvement was obtained upon introducing Co(superscript 2+) as a modifier. The yield of crotyl alchol reached 5.5%, however the activity lowered from 150.4 mol CAL/mol Ru·h to 96.7 mol CAL/mol Ru·h.

尤其是经Co(上标 2+)修饰后，巴豆醇的最高产率为5.5%，而催化活性由150.4 mol巴豆醛／mol Ru·h降至96.7 mol巴豆醛／mol Ru·h。

Both catalytic activity and selectivity of Ru(PPh_3)_3Cl_2 were improved in ionic liquid BMImPF_6/DME medium.The conversion of hexene and selectivity ofβ-adduct for the hydrosilylation reaction of 1-hexene with triethoxysilane catalyzed by Ru(PPh_3)_3Cl_2 in ionic liquid BMImPF_6DME (V/V=1/4) medium at 90℃were 100% and 89.0%,respectively.

实验结果表明，在乙二醇二甲醚/离子液体1-丁基-3-甲基咪唑六氟磷酸盐(BMImBF_6)(V/V =1/4)介质中，于90℃下，己烯与三乙氧基硅烷反应的转化率为100%，β加成物的选择性可达89.0%，而用Rh(PPh_3)_3Cl作为反应的催化剂，在纯离子液体BMImPF_6中，就可以高效催化烯烃与三乙氧基氢硅烷的加成反应，过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化剂/离子液体BMImPF_6催化体系，不仅解决了产物与催化剂分离困难这一难题，同时，离子液体BMImPF_6的存在提高了过渡金属Rh(PPh_3)_3Cl，Ru(PPh_3)_3Cl_2催化硅氢加成反应的活性，特别是β加成物的选择性。

In this mechanism, a phosphine ligand in the Ru hydride complexes is replaced by protonic solvent ROH to generate the chain carrier.

三、反应机理论文提出，在固载Ru基催化剂上的scCO〓加H〓生成HCOOH的反应中，CO〓的活化在Ru配合物的作用下，以反插入Ru-H键，生成金属-羧酸配合物的形式进行。

In chapter 1, the progress in study of the ruthenium complex oxides. especially the coexistance of magnetism and superconductivity in 〓 and 〓 are introduced. The introduction makes conclusion that all of the Ru-1212 and Ru-1222 compounds reported are accompanied by small amounts of SrRuO〓 impurities, this is to say that, it is difficult to synthesize pure samples of these two compounds by traditional solid state reaction. So the author think that the studies for new synthesis methods of ruthenate superconductors which is beneficial to the synthesis of new type precious metals superconductivity is very important till now.

第一章重点综述了钌系复合氧化物的研究进展，特别是其中超导电性的发现及其钌系1212、1222相铜氧化物超导电性和铁磁性共存的特征，在此基础上可以看出，至今文献报道所获得的Ru-1212和Ru-1222相化合物都含有少量的SrRuO〓杂相，即很难通过原有的固相反应方法得到纯相化合物，由此作者提出，现有钌系超导氧化物合成的新方法研究仍具有重要的现实意义，这也将更有利于探索合成新型贵金属超导体。

A spontaneous deposition approach was developed to form a Pt ultrathin overlayer onto a Ru nanoparticle film (simplified hereafter as Ru/Pt film) in which the freshly electroreduced Ru film wereas subsequently immersed in a deaerated H2PtCl6 solution without potential control.

采用自发沉积法在Ru膜上生成超薄Pt层，即在开路状态下将电化学还原后的Ru膜浸于除去氧的H2PtCl6溶液中进行自发沉积。

The phenomenon of MC concentrated around the thrombosed vessels occurs after PTE. Maintaining the duration of a certain ru-PA concentration in blood is contribute to MC concentration around the thrombosed vessels, thrombolysis and repair induce by ru-PA after PTE.

PTE血管栓塞处有MC聚集现象；维持ru-PA在血中一定浓度的持续时间，促进MC聚集于栓塞血管部位，该时间越长，趋化MC向栓塞处迁移、聚集越多，并加强ru-PA的溶栓效果。

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数字天空拥有俄罗斯招聘网站HeadHunter.ru与社交网站Vkontake.ru的大量股份，并凭借内容提供商Forticom的股权，成为校友录网站Odnoklassniki.ru的大股东。

The results indicated that a dependable kinetic model could be obtained by modifying the Temkin equation by considering the H2 and NH3 adsorption factors. Activation energy for the ammonia synthesis reaction was obtained as 90.2 kJmol^(-1) after linear fitting the kinetic and thermodynamic parameters k, K(subscript H2) and K(subscript NH3) with the Arrhenius and Van't Hoff equation, which was much lower than that over iron-based catalyst, which indicated that the activation energy barrier of N2 dissociative adsorption on Ru was far lower than that on either the conventional magnetite-based catalyst or wustite-based catalyst; the hydrogen adsorption heat was 76.2 kJ mol^(-1), indicating that the adsorption of hydrogen on the Ba-Ru-K/AC catalyst was so strong that it inhibitied the dissociative adsorption of nitrogen.

结果表明，在Temkin方程中加入H2和NH3的吸附项能够获得可靠的动力学模型，用Arrhenius和Van't Hoff方程对动力学和热力学参数k、K(下标 H2)和K(下标 NH3)进行线性拟合，得到氨合成反应的活化能为90.2 kJmol^(-1)，远低于铁基催化剂，说明Ru上N2的解离吸附活化能垒远低于传统磁铁矿基催化剂和维氏体基催化剂。H2的吸附热为76.2 kJmol^(-1)，证明Ba-Ru-K/AC催化剂上H2的吸附较强烈，对N2的吸附有强烈的抑制作用。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。