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In this thesis, the methods of surrounding rock masses stability classification on the basis of the geological documentation of muck and the boring parameters of TBM are approached, especially as follows:①The geological documentation of muck and the boring parameters of TBM in the Yellow River Diversion Project.of shanxi province is summarized systematically;②Based on the geological documentation of muck and the boring parameters of TBM, that whether the common methods of surrounding rock masses stability (the methods of regular factor classification) classification are feasible, is carried on the discussion;③According to the corresponding relation of muck and the boring parameters of TBM and the surrounding rock masses stability type, the extension assessment method of tunnel surrounding rock masses stability classification is set up, also the corresponding fortran calculation procedure worked out, and not only rational result in conformity with the reality can be obtained, but also the stability situation of surrounding rock masses in front of the working range can be predicted according to the change of the dependent value in the application instance of Yellow River Diversion Project;④Combining with the application instance of Yellow River Diversion Project, extension assessment method in the application of surrounding rock masses stability classification is compared and verificated in detail by applying fuzzy synthesis method by forefathers, and a certain degree discussion and summary about the application achievement of surrounding rock masses stability classification, which is assessed by extension assessment method and fuzzy synthesis method, are carried on.

本文基于渣料和TBM掘进参数的地质编录提供的地质信息进行了围岩稳定分类方法的探讨,重点进行:①对引黄工程中渣料和TBM掘进参数的地质编录的系统整理;②基于渣料和TBM掘进参数的地质编录获得的地质信息,对常用围岩稳定分类方法是否能够进行围岩稳定分类进行了探讨;③根据渣料和TBM掘进参数与围岩稳定类型的对应关系,应用可拓理论,建立了隧洞围岩稳定分类的可拓评价方法,还编制了相应的fortran计算程序,并在引黄工程的应用实例中不仅取得了与客观实际相符的合理结果,而且根据其关联度值的变化能够预测临近掌子面前方围岩的稳定情况;④结合引黄工程的应用实例运用模糊综合评判方法对可拓评判方法在围岩稳定分类中的应用进行了详细的验证、比较,并对前人在运用可拓学和模糊数学进行岩体稳定评判的应用成果方面,进行了一定的探讨、总结。

The study provided 2 kinds of finish systems which were pouring and anchoring rock-wool panel respectively. In general, galvanizing steel-meshwork using machine anchor can use all kinds of Rock-wool panel made in China. The interface mortar used in Rock-wool can prevent worker's hand from hurting and improve the water-proof capability and bonding intensity of rock-wool panel. The low-heat conductivity of polystyrene foaming granule paste improved the integer and anti-crack of system. The 2 kinds of rock-wool system all can resolve the current rock-wool panel applied difficulty in outer-wall external thermal insulation. The rock-wool external thermal insulation which has very nice fire-proof capability can apply any kinds of builds, especially high-rise buildings.

研究提出了现浇和锚固岩棉板2种涂料饰面构造做法,其中采用机械锚固热镀锌钢网施工可充分利用国产各类型岩棉板;岩棉板的界面砂浆处理可起到防止岩棉纤维扎手、增强岩棉板的防水性能和提高岩棉板与找平层的粘结强度的作用;聚苯颗粒的低导热系数过渡层提高了系统的整体性和抗裂性。2种构造做法经试验和工程试点证明均可解决目前国内岩棉难以应用在外墙外保温系统中的技术问题,具有优异防火性能的岩棉外保温系统可应用于任何类型的建筑中,在高层建筑和防火要求高的建筑中其优势更为明显。

In engineering application, we think that the rock laboratory experiments may simulate and reshow rock bursts considering the conditions of coupled static-dynamic loads and rock burst and their comparison. Energy demand of rock burst occurring is revealed through analyzing energy transition of rock failure process under coupled static-dynamic loads. At the same time, the rule of energy utilization under coupled static-dynamic loads is discovered; the measures for rock cracking by utilizing high stress condition in deep rock mass and energy utilization improving are found.

在工程应用方面,将动静组合载荷下岩石受力条件和岩石发生岩爆的条件及两者发生的现象进行了对比,认为室内动静组合加载试验可以模拟再现现场发生的岩爆,并通过分析动静组合载荷下岩石破坏过程中能量的转化来揭示岩石发生岩爆的能量要求,而且发现了动静组合加载能量利用的规律,找到提高能量利用率的措施和利用深部岩体受力状况来致裂岩石的手段。

Therefrom; heating said waste edible oil from which solid materials have been removed to a predetermined temperature, thereby removing moisture and materials of odor contained in the waste edible oil therefrom by evaporation; dissolving in alcohol a catalyst containing at least one type or more types of alkaline material selected from a group comprised of at least potassium hydroxide, potassium carbonate and potassium alcoholate, thereby preparing an alcoholic solution containing the catalyst; mixing said waste edible oil from which said solid materials, moisture and materials of odor have been removed with said alcoholic solution containing the catalyst and stirring the waste edible oil and alcoholic solution, thereby accelerating a catalytic reaction between the waste edible oil and the alcohol and obtaining a reaction product between the waste edible oil and the alcohol; separating said reaction product into a light solution and a heavy solution; mixing the light solution obtained in the separation step with a solid absorbent, thereby impurities such as residual catalyst, odor material, moisture contained in the light solution being absorbed by the solid absorbent; and separating and removing said solid absorbent from a mixture of the solid absorbent having absorbed the impurities and the light solution.

完成前述对象,根据这项发明的特点是获得的柴油燃油从废油脂透过几个步骤:去除固体材料包含在一个废油脂倾倒,从餐厅,食品厂,民政等因此;暖气说,废油脂从哪个固体材料已被调离到一个预定的温度,从而消除了水分和材料的气味,载于废油脂因此由蒸发;溶解在酒精的催化剂至少含有一种或更多类型的碱性材料选定由一组组成的至少氢氧化钾,碳酸钾和钾,醇,从而准备一醇溶液中含有催化剂;混合说,废油脂从哪个说,固体材料,含水率和材料的气味已被剔除与说,酒精性解决方案载有催化剂和搅拌废物食用油及含酒精的解决办法,从而加速催化反应之间的废油脂及酒精和获得反应产物之间的废油脂及酒精;分开说,反应产物成为一个轻型的解决方案和沉重的解决方案;混合轻解决方案,获得了在分离一步一个坚实的吸水性,从而杂质,如残留的催化剂,气味的物质,水分,载于轻解决方案,被吸收的固体吸收剂;分离和消除说,固体吸附剂从混合物对固体吸收剂吸收了杂质和轻便的解决办法。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area;2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support;3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier;4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling;5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene PolymerizationIn this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that:1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS;2.co-mlling time had no obvious effect on the texture of support after 12 hours;3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现;3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布;4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒;5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明:1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致;2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响;3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。

Dealcoholization temperature markedly influences the surface area and porosity of the resultant MAO-supports. When the support was pretreated at lower or higher temperature, the corresponding MAO-support shows very low surface area; 2.XRD and IR analyses indicate that MAO has reacted with the residual ethanol in the supports, which is an important manner to get MAO fixed on the carrier. Morever, XPS analyse indicates that MAO can also be coordinated with MgCl_2, which is another way to get MAO fixed on the support; 3.ICP and EDX analyses indicate that dealcoholization temperature not only determined the element content on the solid catalyst, but also influences the element distribution on the carrier; 4.The activities of the supported phenoxy-imine catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature. The support (MSP-5) obtained by treating MgCl_2·2.56C_2H_5OH at 160℃for 4 h, then modified by MAO is very effective for immobilizing complex 3, the resultant solid catalyst (MSPC-5) shows very high activity in ethylene polymerization, and its kinetics of polymerization is stable during the reaction process. Finally, PEs with spherical morphology and high bulk density (over 0.35g/ml) were obtained, without reactor fouling; 5.In this work, polymerization conditions such as alkylaluminums, Al/Zr ratio, temperature and H_2 had a pronounced effect on the activity of MSPC-5 and properties of PE;(3). New MgCl_2-Supported Single-Site Catalysts for Ethylene Polymerization In this work, a kind of new MgCl_2 support was obtained by anhydrous MgCl_2 co-milled with solid MAO, and it is a creative contribution. Then some single-site catalysts were supported on the new MgCl_2 support, and the resulted solid catalysts were tested in ethylene polymerization, the results indicated that: 1.XRD and IR analyses indicate that MAO does be coordinated with MgCl_2, which is in good agreement with the results obtained by XPS; 2.co-mlling time had no obvious effect on the texture of support after 12 hours; 3.In this work, MgCl_2 was co-milled with solid MAO for different hours, and then complex 3 was supported on these co-milled supports. It was found that co-milling time markedly influences the activity of solid catalysts, but it had negligible effect on the kinetic profile and the properties of resultant PE.

XPS研究结果表明,MAO不仅仅只和乙醇作用,MAO还与MgCl_2本身有一定的作用,这是一个极为重要的发现; 3、通过ICP和EDX表征,发现载体的脱醇温度直接影响着元素在固体催化剂中的含量及分布; 4、脱醇温度极大地影响着负载苯氧基亚胺类催化剂的活性和聚合物的性能,特别是原始载体经160℃活化4小时制备得到的固体催化剂MSPC-5的活性明显高于其他脱醇温度条件下制得的固体催化,并且催化剂寿命长,表现出稳定的动力学行为,最终获得了高堆密度(大于0.35g/ml)的球形聚乙烯颗粒; 5、本文选择MSPC-5为研究对象,考察了聚合反应参数对催化剂的活性及其聚合物的影响,研究发现:不同的烷基铝对催化剂具有非常重要的影响,特别足TIBA对MSPC-5的助催化活性最高,烷基铝的加入量有一个较佳值,聚合温度为80度时活性最高,H_2的加入使催化剂的活性明显降低且聚合物的分子量也减小;、新型氯化镁载体负载单活性中心催化剂催化乙烯聚合本文创造性采用固体MAO与无水氯化镁直接进行共研磨,制备出了一种的新型的氯化镁载体,并将该载体用于多种单活性中心催化剂的负载化研究,研究表明: 1、通过BET、XRD的表征,再次证实了MAO与MgCl_2之间具有直接作用,与XPS的研究结果相一致; 2、当研磨时间高于12小时时,延长研磨时间对载体的结构没有显著的影响; 3、将配合物3负载于共研磨时间不同的一系列载体上,乙烯聚合结果表明,尽管共研磨时间对负载催化剂的活性具有明显的影响,但是它对聚合物的性能以及催化剂的影响不明显。

According to the change regularity of deformation modulus, combining with the rock mass structure characteristic of region studied, using interpolation method, the deformation modulus of rock mass in 36# adit can be deduced. The average vertical deformation modulus of rock mass during 0-70 zone is 39Gpa, and the horizontal deformation modulus of rock mass is 51. 3GPa in nature stress state and 50.8GPa in engineering load state. The average vertical deformation modulus of rock mass during 70-140 zone is 32. 2Gpa, and the horizontal deformation modulus of rock mass is 41GPa in nature stress state and 42. 6GPa in engineering load state. It will be a good reference of engineering design and evaluation.

9根据节理岩体变形模量变化规律,结合研究区岩体的结构特点,采用插值的方法对36号平硐岩体进行变形模量的推测,得到0-70段岩体的平均铅直向的变形模量为39GPa,水平向的变形模量:天然应力状态下为51.3GPa,工程荷载作用下为50.8GPa;70-140段岩体的平均铅直向的变形模量为32.2GPa,平向的变形模量:天然应力状态下为41GPa,工程荷载作用下为42.6GPa,这为工程设计、评程设计、评价等提供了必要的参考。

The main environment geological question is: The earth"s crust where the faultage and earthquake are active is unstable; collapse , landslide, mud-rock flow and soil erosion ; The underground karst subsides, seepage question; Basic rock expand, expend and compress soil body, the salt deposit corrode out of shape and groundwater"s corrodent harm; The soft soil question of basin; The soft rock body, cracked rock and the weathering rock are relatively poor stability; High and cold regional highways and railways" frozen soils freeze and melt calamity problem; The around rock of tunnel are unstable because of the coal seam gas, spring water, underground developed area; Project cutting slopes, constructed abandon soil and reservoir, lake"s ecology geological environmental protection issue; Thedangerous shoal of the channel % submerged reef question; The problem of rebuilding channel project and dock etc.; And the problem of unstable ground and groundwater corrosivity during building airport; At the same time, with the international big pathways" implementation and completions of constructions, adjusting the cities and counties" constructions , the crowd occupy changing , the cultivated land distribute changing and the adjustments of structure, will cause local environmental geological issues outstanding; According to multiple statistical analysis , value calculate and integrated appraise result, in the northwest and southwest of Yunnan, the traffic relatively low density, traffic engineering is relatively weak impact on environment, It is the area where a environme

主要的环境地质问题是:活动性断裂、地震带的地壳不稳定;崩塌、滑坡、泥石流及水土流失;地下岩溶塌陷、渗漏问题;基础岩体膨胀、胀缩土体、含盐层侵蚀变形和地下水的腐蚀危害;盆地软土问题;软弱岩体、碎裂、风化岩体稳定性较差;高寒地带公路、铁路建设的冻土冻融灾害问题;煤层瓦斯、涌水、地下采空区等隧道围岩不稳定问题;工程切坡、施工弃土及水库、湖泊生态地质环境保护问题;航道险滩、暗礁问题;渠化工程、码头等库岸再造问题;以及机场建设中的不稳定地基及地下水腐蚀性问题;同时,随着大通道建设的实施和完成,城镇建设的调整、人群居落的变化和耕地分布及结构的调整组合,都可能造成局部环境地质问题的突出等等。经多元统计分析数值计算、综合评价结果,滇西北、滇西南地区交通密度较低,交通工程对环境的影响程度较弱,是环境地质状况好的区域;有主要高原湖泊分布区的,包括昆明、个旧、文山的滇东南区域,环境地质状况较好;大姚、楚雄、篙明及会泽、昭通一镇雄的区域,即滇中北部中生界红层和滇东北岩溶区,环境地质状况中等;而包括保山、德宏、大理、临沧的滇西地区及景东一墨江以东、双柏一石屏一河口以西及东川一寻甸一曲靖地段的滇中一滇东地区,环境地质状况较差。云南国际大通道建设涉及全省区域,如何利用地质环境、实现可持续发展,就必须依赖于国际大通道建设与地质环境之间良性关系的建立。应本着对区域地质环境客观存在的科学认识原则、建设过程中环境效益优先的可持续发展原则、法制性原则、对大通道建设中环境地质的因地制宜及其可防治性原则。并且从组织管理、不同类型大通道、不同环境地质问题类型等方面,提出了对策措施。最后,提出了建立国际大通道建设与环境地质良性关系的宏观建议。

The comparative investigation of the characteristics of deformation and AE were conducted and the results are presented as followed: 1. The characteristics of rock AE are correlated to the strength, joints, cracks, and the size and hardness of crystalline grain. 2. The sequence of AE can be divided into four phases: beginning phase, tempestuousness phase, drop phase and dreariness phase. The loss and the duration of the phases are correlated to the rock character and flaws in the rock. 3. The AE rate characteristics are not almost concordant with the AE energy rate. 4. Besides the homogeneity, the strength of rock contributes the activity of AE. The higher the strength is, the lower the activity is. 5. There is a dreariness phase before the failure of most kinds of rock. 6. Whether the precursor is obvious is correlated to rock the character, and the precursor of AE rate is more apparent than the precursor of AE energy rate comparatively.

通过对比研究这六种不同岩石的变形和声发射特征发现,岩石声发射受到岩石强度、节理裂隙和晶粒软硬大小等的影响;岩石声发射过程存在初始区、剧烈区、下降区和沉寂区,各个阶段是否存在及持续时间与岩石强度、内部缺陷等有关;岩石的声发射事件率特征与能量率特征并不完全一致;岩石的声发射活性除了受其均匀性影响外,还受到岩石的强度影响,强度越小,声发射活性越强;大多数岩石破坏前存在一声发射沉寂区;岩石的破坏前兆是否明显跟岩性有关,相比较而言,岩石破坏时的声发射率前兆比声发射能量率前兆更为明显一些。

The study provided 2 kinds of finish systems which were pouring and anchoring rock-wool panel respectively. In general, galvanizing steel-meshwork using machine anchor can use all kinds of Rock-wool panel made in China. The interface mortar used in Rock-wool can prevent worker's hand from hurting and improve the water-proof capability and bonding intensity of rock-wool panel. The low-heat conductivity of polystyrene foaming granule paste improved the integer and anti-crack of system. The 2 kinds of rock-wool system all can resolve the current rock-wool panel applied difficulty in outer-wall external thermal insulation.

研究提出了现浇和锚固岩棉板2种涂料饰面构造做法,其中采用机械锚固热镀锌钢网施工可充分利用国产各类型岩棉板;岩棉板的界面砂浆处理可起到防止岩棉纤维扎手、增强岩棉板的防水性能和提高岩棉板与找平层的粘结强度的作用;聚苯颗粒的低导热系数过渡层提高了系统的整体性和抗裂性。2种构造做法经试验和工程试点证明均可解决目前国内岩棉难以应用在外墙外保温系统中的技术问题,具有优异防火性能的岩棉外保温系统可应用于任何类型的建筑中,在高层建筑和防火要求高的建筑中其优势更为明显。

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Rock The Shocker
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Article 144 The Government of the Hong Kong Special Administrative Region shall maintain the policy previously practised in Hong Kong in respect of subventions for non-governmental organizations in fields such as education, medicine and health, culture, art, recreation, sports, social welfare and social

第一百四十四条香港特别行政区政府保持原在香港实行的对教育、医疗卫生、文化、艺术、康乐、体育、社会福利、社会工作等方面的民间团体机构的资助政策。原在香港各资助机构任职的人员均可根据原有制度继续受聘。

Small wonder, then, that the Chinese spend more in the shop than any other group of foreign visitors do .

这样的小惊喜,使中国顾客比任何国家的人消费得更多。

A heavy dark cloud presaging rain or a storm .

预兆雨或暴风雨的沉重的黑云。