查询词典 rhodium

Rhodium-catalyzed asymmetric 1,4-conjugate addition reaction is one of the most efficient methods for the carbon-carbon bond formation.

铑催化不对称1，4-共轭加成反应是一种非常有效的碳—碳键形成方法。

Other than conventional concept, the N→Rh bond, formed by rhodium in the complex and nitrogen at pyridine ring in the ligand, did not break in the course of the carbonylation reaction, but formed into new active species instead, i.e., the ligand and rhodium as a whole participated in the oxidative addition of CH3I and the formation of CH3COI.

配合物中铑与吡啶环上共轭N形成的N→Rh配键，在羰基化反应过程中并非通常认为的断裂而是形成新的活性物种，即配体与铑作为整体参与了CH3I的氧化加成及CH3COI的生成过程。

Trevor Houser, a China oil specialist at Rhodium Group in New York, said that the drop in inflation in May gave Beijing just enough breathing room to increase fuel prices.

纽约Rhodium Group的中国石油专家特雷弗豪泽表示，5月份通胀下降，正好给了中国政府足够的喘息之机，以提高燃油价格。

Rare precious metals company mainly engaged in electroplating and metal surface treatment, environmental treatment, washed clean of raw materials: silver nitrate, nitric acid and rhodium, palladium nitrate; Asia selenium acid, selenium dioxide, tellurium dioxide, mineral selenium powder Japan, Mitsubishi Se powder, Mitsui, Sumitomo, emerging, Germany selenium powder; molybdenum trioxide, DMF; TX-10, NP-9 series, EDTA series; sodium hypophosphite, nickel nitrate, metal thallium, rhodium, palladium, platinum , Beryllium, Ritek, zirconium products; sponge palladium; electrolytic nickel, nickel corner, hydrazine hydrate, Ultra-fine silver, nano-silver; Thallium sulfate, iodized Thallium sulfate, nickel, copper sulfate, copper chloride, copper oxide, nickel oxide , Lanthanum oxide, oxidation Er, bismuth oxide, bismuth ingots, tin ingots, indium ingot, indium foil, Xinding, zinc powder; SnCl2, sulfate-tin; hydrofluoric acid, white Vaseline, propylene glycol, dichloro Methane, the propylene glycol, triethanolamine, triethanolamine oleic acid soap, chloroform, pyrophosphate copper, Gioia sodium, polyacrylamide, PAC, oleic acid, Glycerol, phosphate and other domestic and imported chemical series.

公司主要经营稀贵金属及电镀金属表面处理、环保污水处理、洗涤清洗原料：硝酸银、硝酸铑、硝酸钯；亚硒酸、二氧化硒、二氧化碲、日本矿业硒粉、三菱硒粉、三井、住友、新兴、德国硒粉；三氧化钼、二甲基甲酰胺；TX－10、NP-9系列、EDTA系列；次亚磷酸钠、硝酸镍、金属铊、铑、钯、铂、铍、铼、锆系列产品；海绵钯；电解镍、镍角、水合肼、特细银粉、纳米银粉；硫酸铊、碘化铊、硫酸镍、硫酸铜、氯化铜、氧化铜、氧化镍、氧化镧、氧化铒、氧化铋、铋锭、锡锭，铟锭、铟箔、锌锭，锌粉；氯化亚锡、硫酸亚锡；氢氟酸、白凡士林、丙二醇，二氯甲烷，二丙二醇，三乙醇胺、三乙醇胺油酸皂、三氯甲烷、焦磷酸铜、焦亚硫酸钠、聚丙烯酰胺、聚合氯化铝、油酸、甘油、磷酸等国产、进口化工系列。

In the same time, water-soluble bidental phosphines ligand BISBIS sulfonated 2,2''-bis(diphenylphosphinomethyl-1,1''-biphenyl was synthesized, and water-soluble rhodium complex Cl was synthesized in situ. This complex which was used as catalysts to catalyze the hydrogenation of avermectin was also tested. Although the rhodium complex containing bidentate phosphine BISBIS showed a higher catalytic activity than one containing TPPDS, the selectivity for ivermectin was lower. How to improve the selectivity will be needed to studied in futur.

同时我们用磺化的2，2''-二-- 1，1''--联苯，以及它们的水溶性威尔金森型铑配合物和环辛二烯的阳离子铑配合物，在利用这些配合物作催化剂，考察它们在各种反应条件下对阿维菌素的选择加氢，由于反应条件以及复合催化剂体系的组成还需要进一步优化，虽然双齿膦配合物显示了较高的活性，然而选择性还有待进一步提高。

A process for the carbonylation of allylic butenyl ether (for example, methyl crotyl ether, 3-methoxybutene-1 and mixtures thereof) or mixture of butadiene and alcohol and production of beta-gamma unsaturated carboxylic acid esters (for example, methyl-3-pentenoate) utilizing a rhodium-containing catalyst for example, dicarbonylacetylacetonate rhodium(I or the like promoted with an iodide-containing compound (for example, HI, AlI3, SnI4, TiI4, CrI3, and CoI2 or the like).

一种将烯丙型丁烯基醚(如甲基巴豆基醚、3－甲氧基丁烯－1及其混合物)或者丁二烯与醇的混合物羰基化的方法，以及由含碘化物化合物(如HI、AlI3、SnI4、TiI4、CrI3和CoI2或等效物)促进，用含铑催化剂如二羰基乙酰丙酮酸铑(I或其等效物制备β－γ不饱和羧酸酯(如甲基－3－戊烯酸酯)的方法。

The reason may be that complex formed by rhodium and halide was difficult to produce the catalytic active species. Therefore halide ion was the poison for the rhodium catalyst in hydroformylation of olefins in ionic liquid. The effect of double long chain cationic surfactant (DCMAB, dicetyl dimethylammonium bromide) on selective hydrogenation of cinnmaldehyde catalyzed with RuCl3·x H2O/TPPTS was studied.

进一步的研究表明在使用有良好反应活性的两种催化剂HRh3 、Rh_2进行催化反应时，向体系中加入含有卤离子的化合物时将使反应活性大大降低，而且随着卤化物加入量的增加，催化剂的活性迅速下降，这是卤离子可能和金属铑作用使它难于生成催化活性物种，进一步证明卤素离子是引起催化剂活性下降的极其重要的因素。

Also, the type of dispersion of four gasliquid-liquid systems: air-decane-aqueous solution of sodium sulfite and surfactant, airmixture of decane and dodecene-aqueous solution of rhodium complex, ligand, and surfactant, air-mixture of decane, dodecene and tridecyl aldehyde-aqueous solution of rhodium complex, ligand and surfactant, and air-mixture of decane and dodeceneaqueous solution of trisodium salt of tri (m-sulfophenyl) phosphine, and surfactant is determined by electric conductivity.

本文采用电导率测量的方法实验研究了空气—正癸烷—亚硫酸钠和十六烷基三甲基溴化铵水溶液、空气—正癸烷和1-十二碳烯混合物—铑膦络合物催化剂和十六烷基三甲基溴化铵水溶液、空气—正癸烷、1-十二碳烯和十三醛混合物—铑膦络合物催化剂和十六烷基三甲基溴化铵水溶液、空气—正癸烷和1-十二碳烯混合物—三间磺化苯基膦三钠盐和十六烷基三甲基溴化铵水溶液四个三相体系的液液分散特性。当有机相与水相体积比分别为7／3、1／1和3／7时，前三个体系均形成水包油型分散，并有稳定的乳状液生成。

China is making prices cheaper in renewables today, by lunging into oversupply, as it does in most industries,' says Daniel Rosen, principal of consulting firm Rhodium Group.

咨询公司Rhodium Group负责人罗森说，中国目前在通过过剩的供应来拉低可再生能源的价格，就像它在大部分行业的做法一样。

Long-term cash at high prices to buy a smart card chip after punching strip of waste, scrap lead frame and other waste, electronic waste plant paste / brush machine cloth / Electronic feet / Dross, electroplating plants plated / silver / platinum / palladium / Rhodium liquid and sludge waste, waste Goldfinger, line factory or other electronic components such as membrane switch factory Factory / monolithic capacitor plant / plants and so on gold-plated connectors silver platinum palladium rhodium scrap / waste water / sludge, chemical plants or Plant a variety of other precious metal catalyst waste, waste¨°/ sensitive film, metallurgical plant borax slag / furnace ash / activated carbon / zinc wire, jewelry factory watch factory polished powder and other gold-bearing, silver, palladium, rhodium, platinum scrap, etc..

长期现金高价收购智能卡芯片冲切后的废条带、引线框架边角料及其它废品、电子厂废银浆/擦机布/电子脚/锡渣、电镀厂镀金/银/铂/鈀/铑废品废液及污泥、废旧金手指、线路板厂或其它电子元件厂如薄膜开关厂/独石电容厂/连接器厂等镀金银铂钯铑废品/废液/污泥、化工厂或其它厂各种废贵金属催化剂、废定影液/感光胶片、冶金厂硼砂渣/炉灰渣/活性炭/锌丝、首饰厂表厂打磨粉及其它含金、银、钯、铑、铂等的废品。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。