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reductive相关的网络例句

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2-Substituted-3,4-dihydro-1(2H)-isoquinolinones were synthesized from methyl 3-hydroxy-ben- zoates via allyl etherification, Claisen rearrangement, oxidation, reductive amination and aminolysis for the first time.

以3-羟基-4-甲氧基苯甲酸甲酯等为原料,通过烯丙基醚化、Claisen重排、氧化、与伯胺反应、还原、分子内酯的胺解六步反应合成了一系列2-取代-3,4-二氢-1-异喹啉酮类化合物。

The tricyclic system 5-6-7 of Stenine skeleton was finished, At the same time, also finished the skeleton of Aspidosperma via reduction free radocal cyclization and Clemmensen reductive rearrangement.

并在此基础上应用三丁基锡氢的还原自由基环化和跨环Clemmensen还原重排为关键反应,完成了Aspidosperma的骨架化合物的构筑。

Typically, in one direction, the pathway is oxidative, dissimilatory, and produces adenosine 5'-triphosphate, and in the opposite direction, the pathway is reductive, assimilatory, and energy consuming.

经典的循环可以概括为,在一个方向上是氧化,异化,产生三磷酸腺苷即能量,在另一个方向还原,同化,消耗能量。

In this thesis, a reductive amination was used to prepare compound 16 with the boronic acid moiety. The moiety can provide covalent interaction with sugars.

本论文中,合成化合物16,是将化合物15与2-甲醯苯硼酸用还原胺化法而得到;其含有硼酸部分,可以与醣类分子以共价键键结。

The result showed that the volume, dry weight and total sugar content of root gradually reduced with the harvest frequency, but the reductive sugar content in root increased. While the harvesting frequency was two times per year, the volume and dry weight of alfalfa root showed an decreasing at beginning and then increasing when the first harvesting was at different growth stages and the lowest values were at flowering period however, it was not significant for brome.

结果表明:随刈割次数增加,两种牧草根体积、根干重和根部总含糖量逐渐减小,而根系还原糖含量呈逐渐增加的趋势;在年刈割两次,首次刈割分别在不同生育时期试验处理中,苜蓿根体积和干重呈先减后增趋势,首次刈割在盛花期根体积和干物质含量均最低,而无芒雀麦变化不明显。

Ethoxycarbonyl-4,5-dimethyl-pyrrole (7) was prepared from ethylacetoacetate, ethyl formate and methyl ethyl ketone via oximination, Claisen condensation, and reductive condensation. The bromization of compound 7 gave 2-ethoxycarbonyl-3-bromo-4,5-dimethyl-pyrrole(8), which could be transferred to 2-ethoxy-carbonyl-3-brome-4-methyl-5-formyl-pyrrole (9) by the formolation.

由乙酰乙酸乙酯、甲酸乙酯及丁酮等原料经过肟化、Claisen缩合、还原缩合成环得到2-乙氧羰基-4,5-二甲基-吡咯(7),溴化生成2-乙氧羰基-3-溴4,5-二甲基-吡咯(8),最后经过甲酰化反应得到目标产物2-乙氧羰基-3-溴-4-甲基-5-甲酰基-吡咯(9)。

And then the intermolecular reductive cyclization reaction of N,N-diethyl-o-nitrobenzenesulfonamide with nitriles promoted by samarium diiodide was studied. 2H-1,2,4-Benzothiadiazine 1,1-Dioxides were prepared in good yields under mild and neutral conditions.

然后研究了二碘化钐促进的邻硝基N,N-二乙基苯磺酰胺与腈发生的分子间交叉还原偶联反应,一步合成了2H-1,2,4-苯并噻二嗪-1,1-二氧化物。

The recent advances in the main clean processes to synthesize diphenylmethane diisocyanates are reviewed, such as BTC method, condensation of aniline, reductive carbonylation of nitrobenzene, oxidative carbonylation of aniline, methoxycarbonylation of aniline, alcoholysis of N,N'-diphenyl urea and the coupling process.

回顾了清洁合成二苯甲烷二异氰酸酯的几种主要方法,如BTC法、苯胺缩和法、硝基苯还原羰基化法、苯胺氧化羰基化法、碳酸酯法、二苯基脲法和反应耦合法等合成路线。

For the fermentation coupled with distillage recycle,every five days,the total backset distillage collected was directly used to mix the corn powder,and the experimental results revealed that the concentrations of ethanol,residual reductive sugar,inorganic phosphate and total solids in the broth were maintained s.

实验结果表明,在稀释速率0.05 h-1,废糟液全循环条件下,装置达到稳定状态后,乙醇、残还原糖、无机磷、无机氮、蛋白和总固型物浓度分别稳定在9.4%、26 g/L、11 g/L、3.36 g/L、0.136 g/L和85 g/L左右;乙醇浓度与对照组相差不大,但残还原糖、无机磷及总固形物在废糟液循环使用的初期出现积累,但随运行时间的延长而趋于稳定,说明对酵母生长和乙醇发酵没有产生明显影响。

This protocol could also be used for the selective reduction of the endocyclic double bond of the 3-electron withdrawing group substituted coumarins. This method is clean, mild, and efficient.2 ZrCl_4 / HEH was found to be a selective and efficient reagent combination for the direct reductive amination of electron rich aldehydes and ketones with weakly basic amines after scanning various catalysts such as InCl_3, BiCl_3, CF_3COOH and so on.

图一 1。我们用汉斯酯作为有机还原剂,乙醇为溶剂,实现了4-甲叉基噁嗯唑酮和吡唑酮环外双键的高选择性还原;此外,我们还将这一还原体系用于3-吸电子集团取代-3,4-二氢香豆素环内双键的选择性还原。

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