查询词典 red shift

Therefore, the energy of π(superscript *) orbit decreases, the probability of optical absorption increases, the n→π(superscript *) electronic transition enhances, and the absorption band broadens and shows red-shift. The above phenomenon will result in the degradation of optical properties of ZnO/silicone white paint under proton exposure.

同时Si-O-Si链内氧原子未成键的孤对电子与邻近硅原子的3d空轨道配位，降低了π轨道的能量，提高了对光吸收的几率，增强了n→π电子跃迁，使吸收带红移，从而导致ZnO/silicone白漆光学性能退化。

As compared to the l max absorption of regioregular poly(3-alkylthiophene)s (RR-P3ATs), the red-shift about 120 nm for RR-P3ATVs resulted from the more coplanarity and the longer conjugation length due to the additional vinylene linkage introduced to the conjugated chains.

与立体规则性聚(3-烷基噻吩)(RR-P3ATs)比较， RR-P3ATVs 之 UV-vis 最大吸收波长约有120 nm 的红外移，显示共轭主链导入乙烯基后，有较佳的共平面性与较长的共轭长度。

The results showed that a red-shift of the maximum absorption took place when the delocalization of the π electrons in the organic molecules increases.

计算结果表明，随着有机分子的π电子离域结构的增大，最大吸收峰红移。

The red shift is produced not only by the Doppler Effect, but also by the gravitational field .

除了多普勒效应产生的红移外，在引力场的影响下也会产生红移。

Under the wind fairing is a large tachometer with red shift point light.

在风展览会之下是有赤字的变化一个大的转速计点光。

The complex has a maxmium absorption at 480 nm with 9 nm of red shift compared to fluorescein itself.

研究了在生理条件下，荧光素与牛血清白蛋白相互作用形成复合物，最大吸收峰的波长480nm ，比荧光素红移9nm。

The most parts of thesis as follows:1. Five symmetrical intra-molecular charge transfer oligomeric phenylene vinylene light emitting materials were designed and synthesized using oligomeric phenylene vinylene as a framework.2. The structures of target molecule were characterized by ~1HNMR,~(13)CNMR, IR, MS and element analysis.3. In order to study the influence of the location and numbers of electron-donor and electron-acceptor on their photoelectric performance by changing length of OPV chain, the UV spectra and fluorescence spectra of target compounds has been compared. We have researched into main factors effecting on material emitting red-shift; organic electroluminescence device was prepared using the compound P4. The capability of eletroluminescence was researched.4. The photoelectric properties of P4 was explained by quantum chemical calculation (the Gaussian 98 quantum chemistry program). It is greatly contributed know the whole process of charge transfer to guide the design of red emitters.

本文研究的内容主要包括以下部分：(1)设计并合成5个对称的以齐聚苯乙烯类为骨架的分子内电荷转移型齐聚苯乙烯类发光材料；(2)通过IR，MS，~1H-NMR，~(13)C-NMR和元素分析对所合成的目标化合物进行表征；(3)通过对目标化合物的紫外光谱和荧光光谱比较分析，研究改变OPV的长度，电子给体和电子受体的位置及数量对其光电性能的影响，探讨材料发射红移的主要因素；选取性能良好的目标化合物P4制备成OELD器件，对其电致发光性能进行研究；(4)运用Gaussian98量子化学程序包，采用量子化学方法对目标化合物P4的光电性能从理论加以解释，进一步认识荷移跃迁的整个过程，为红光材料的设计加以指导。

The absorption bands observed for Pb-pheophytin a at 462nm and 673nm , while for Pb-pheophytin b at 480nm and 662nm . Compared with pheophytin a and pheophytin b, all these bands red shifted more or less. Among the reported metallochlorophylls, the degree of red shift of Pb-pheophytin in Soret band was the largest by 54nm and 44nm for Pb-pheophytin a and Pb-pheophytin b, respectively.

实验表明：对铅叶绿素a和b系列来说，它们在Soret带、Q带的特征吸收峰分别在462nm，673nm和480nm，662nm；与脱镁叶绿素a，b相比，铅叶绿素a，b在Soret带和Q带吸收峰均有不同程度的红移；与现已报道的金属叶绿素相比，铅叶绿素a，b在Soret带的红移程度最大，分别为54和44nm；铅叶绿素不具有荧光活性，并能猝灭脱镁叶绿素的荧光。

The fluorescing properties of the final products were characterized by PL spectrometer. The effect of the calcinations temperature and the amount of adding rare earth element to the property of the red shift and blue shift of powders had been studied.

在发光特性的研究中，本论文利用PL光谱仪对所合成之萤光粉体进行量测，并探讨不同温度、及掺入稀土元素的量之影响及波长红位移、蓝位移现象。

In the aqueous solution the Q band of iron phthalocyanine nanoparticles possess the properties of blue shift and red shift for about 100 nm by adjusting the concentration of surfactants on the basis of CMC with laser irradiation.

通过调节表面活性剂的浓度发现会对酞菁铁纳米颗粒胶状水溶液吸收光谱在Q带内峰值波长产生近100nm大幅度蓝移和红移的特殊现象。

Breath, muscle contraction of the buttocks; arch body, as far as possible to hold his head, right leg straight towards the ceiling (peg-leg knee in order to avoid muscle tension).

呼气，收缩臀部肌肉；拱起身体，尽量抬起头来，右腿伸直朝向天花板（膝微屈，以避免肌肉紧张）。

The cost of moving grain food products was unchanged from May, but year over year are up 8%.

粮食产品的运输费用与5月份相比没有变化，但却比去年同期高8％。