查询词典 rearrangement

Room temperature ionic liquids are the hot points of the current research fields of chemistry, chemical engineering and functional materials. Since 1998, the preparation and application of ionic liquids as environmentally benign reaction media and functional material have been carried out in Lanzhou Institute of Chemical Physics. The detailed research work, including the design and preparation of novel ionic liquids, ionic liquid as catalyst and reaction medium in sulfuric acid free Beckmann rearrangement,...

离子液体介质与材料研究是当前化学化工、功能材料的热点领域之一。1998年底以来，我们以发展离子液体清洁反应介质和软功能材料为研究内容，以实现新离子液体的设计与合成，离子液体中无硫酸Beckmann重排反应、非光气异氰酸酯合成、二氧化碳吸收与活化、反应-升华分离一体化，微孔硅胶限制纳米尺度离子液体材料的设计合成和应用及离子液体-电化学技术集成等为目标开展了一系列研究工作并取得良好进展。

The vapor phase Beckmann rearrangement of cyclohexanone oximeover RBS-1 catalyst was carried out in a continuous flow fixed bed reactor under atmosphere pressure.

在常压连续流动固定床反应装置上，考察了反应温度、环己酮肟质量空速、溶剂种类、环己酮肟浓度、载气流量、水的质量分数等反应条件或反应氛围对环己酮肟气相Beckmann 重排反应的影响。

It was found that the Beckmann rearrangement of cyclohexanone oxime could be performed smoothly in the catalytic media consisting of room temperature ionic liquid and acidic phosphorated compounds, and excellent conversion and selectivity were achieved under mild conditions without any additional organic solvents.

发现酸性含磷化合物，如五氯化磷等在离子液体中可以高效地实现环己酮肟重排制己内酰胺，具有不需另加有机溶剂，选择性高等优点。

The Beckmann rearrangement of cyclohexanone oxime, phosphorus pentoxide (P_2O_5) and dimethyl formamide raction system into caprolactam was studied.

研究了以环己酮肟、五氧化二磷(P_2O_5)、二甲基甲酰胺组成的反应体系进行Beckmann重排制备己内酰胺工艺，考察了不同溶剂、催化剂用量、温度、浓度及水分含量对重排反应的影响。

Beckmann rearrangement of several ketoximes.

3室温离子液体中酮肟的Beckmann重排。

Room-temperature ionic liquids; Synthesize; Spectra; Characterize; Beckmann rearrangement

工程科技I，化学，有机化学离子液体；合成；光谱；表征； Beckmann重排反应

The Beckmann rearrangement of cyclohexanone oxime was effectively realized to prepare e-caprolactam by using phosphorous trichloride (PCl3) as catalyst in a two-phase system composed of 1-n-butyl-3- methylimidazolium tetrafluoroborate ([BF4]) ionic liquids and toluene.

在1丁基3甲基咪唑四氟硼酸盐([BF4])与甲苯组成的两相体系中，以三氯化磷(PCl3)为催化剂，实现了由环己酮肟制备己内酰胺的液相贝克曼重排反应，两相体系有利于反应控制和体系取热。

Our finding revealed two target regions of frequent rearrangement in mt genomes of decapods, even in that of the nonhexapod arthropods.

研究结果揭示了十足目动物，乃至非六足节肢动物线粒体基因组发生高频重排的2个靶区。

The analysis also indicates that a rearrangement of atoms has occurred in the Si (001) surface and, while a majority of surface atoms form bonds and dimerize, a minority still exist as non-bonding atoms.

本论文对Si（001）2×1表面再构、低能粒子轰击对再构表面的影响以及在Si（111）表面低能沉积类金刚石膜进行了分子动力学模拟研究。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应，高度非对映选择性地一步控制了含有季碳的三个相邻立体中心，有效地构建了&2-季碳1，3-二醇&结构单元，首次实现了此类重排—还原过程的催化循环，其中对于两个C1位的差向异构体底物，此反应具有明显的非对映选择性放大特点。

However, as the name（read－only memory）implies, CD disks cannot be written onorchanged in any way.

然而，正如其名字所指出的那样，CD盘不能写，也不能用任何方式改变其内容。

Galvanizes steel pallet is mainly export which suits standard packing of European Union, the North America. galvanizes steel pallet is suitable to heavy rack. Pallet surface can design plate type, corrugated and the gap form, satisfies the different requirements.

镀锌钢托盘多用于出口，替代木托盘，免薰蒸，符合欧盟、北美各国对出口货物包装材料的法令要求；喷涂钢托盘适用于重载上货架之用，托盘表面根据需要制作成平板状、波纹状及间隔形式，满足不同的使用要求。