查询词典 reactions

The calculated result shows that three reactions belong to exothermal reactions.And the decomposition activation energy in the HF catalyst is the smallest , the decomposition of H2CO3 in the role of HF is the most easily.

计算结果表明3 个反应都是放热反应，且分解反应的活化能在HF 催化作用下最小，说明H2CO3 的分解在HF 作用下最容易进行。

It is proved the sensor is fitted to use in detecting antibody-antigen reactions of these diseases. The results of detecting antibody-antigen reactions of Fasciola gegatica, ND, IBD and EDS by using the sensor basically conform to that with standard samples.

在实验研究中，我们先后应用电化学免疫传感器测试了大片形吸虫，鸡新城疫、鸡传染性法氏囊病、鸡减蛋综合征等的抗原抗体反应，结果与我们先前初步设定的判断标准基本相符。

The addition reactions with phosphine anion andthe CsF promoted Strecker reactions were chose to evaluate the relationship of thesetwo chiral groups in the diastereoselective additions of the imino group.

通过亚磷酸负离子的加成反应和CsF促进下的Strecker反应研究了这两个手性基团的不对称诱导的匹配情况。

Chapter 6: Iodobenzene diacetate-mediated reactions of methylenecyclopropanes, vinylidenecyclopropanes and a methylenecyclobutane with phthalhydrazine give the corresponding [3+2] cycloaddition products in good yields under mild conditions. In these reactions, phthalhydrazine was transformed to a 1,3-dipole intermediate in the presence of iodobenzene diacetate. A plausible reaction mechanism has been proposed.

本论文对亚甲基环丙烷类化合物的一些化学反应性能进行了研究，发现了亚甲基环丙烷类化合物在不同试剂或不同催化剂作用下的一些新的化学转化并合成了一些结构简单但具有潜在应用价值的有机小分子。

The Diels-Alder reactions forming one C—B bond and one C—C bond are always more favorable than the corresponding Diels-Alder reactions forming two C—C bonds, both thermodynamically and kinetically, which is in agreement with experimental observation.

形成一个C—B键的杂Diels-Alder反应都比相应的Diels-Alder反应在热力学和动力学上容易进行，这与实验结果一致。

The dissertation mainly consists of two parts:1. The Reaction Chemistry of Alkynes under Palladium Catalysis Part 1 studies the reaction α,β-unsaturated carbonyl compounds with alkenylpalladium intermediate generated by nucleopalladation, and discovered 1 the Pd-catalyzed tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls,2 the four-component tandem addition reaction of halides, alkynes and α,β-unsaturated carbonyls, 3 the tandem intramolecular oxypalladation-conjugate additionreaction of alkynoic acids with α,β-enals. These new reactions provide notonly efficient highly stereoselective methods for the synthesis of γ,δ-unsaturated,polyunsaturated carbonyl compounds and γ-lactonic aldehydes, but also thebasic transformations for a number of C-C bond formation reactions which can be usedto design synthesis of many acyclic, cyclic or polycyclic compounds.

本论文的主要工作分为两个部分：一、钯催化下炔烃的反应化学在本小组前人工作的基础上，我们详细研究了炔烃亲核钯化产生的烯基钯中间体与α，β-不饱和羰基化合物的反应，发现两价钯催化下卤离子-炔烃-α，β-不饱和醛酮的串联加成反应、卤离子-炔烃-α，β-不饱和醛酮的西组分串联加成及炔酸分子内氧钯化-串联Michael型加成反应；由此发展了γ，δ-不饱和醛酮、多不饱和羰基化合物和带有醛酮基侧链的γ-丁内酯衍生物的高立体选择性合成方法，这一过量卤离子存在下的烯基钯对α，β-不饱和羰基化合物共轭加成反应的发现，为大量碳-碳键形成反应的实现提供了基础，使我们能够从这一基本反应出发，设计和开发多种分子内、分子间的碳碳成键反应，以好的立体、区域选择性组建开链、环状及多环类型的化合物。

The reactions catalyzed by the Lewis acids occupy an important place in organic synthesis, but these reactions are normally processing under strict moistureless conditions.

路易斯酸催化的反应在有机合成中占有重要的比重，但这些反应通常需要在严格的无水条件下进行。

Mononitration, dinitration and trinitration of toluene are very important reactions. Products of these reactions are widely used in medicine, dyestuff, explosive, pesticide, etc.

甲苯的多段硝化是重要的化学反应过程，其各段硝化产物在医药、染料、炸药、农药等方面应用广泛。

9 Major adverse reactions (much less common than the minor adverse reactions) include inhibition of myelopoiesis, drug fever and hepatitis.

较重的不良反应包括抑制骨髓细胞生成，药物热及肝炎。

9 Major adverse reactions (much less common than the minor adverse reactions) include inhibition of myelopoiesis, drug fever and hepatitis.65i

较重的不良反应（远不及轻度不良反应常见）包括抑制骨髓细胞生成，药物热及肝炎。65i

According to our present broadcasting situation,the thesis proposes using new technology to update and reform the present HFC. It also suggests broadcasting using self-advantage and arranging EPON in order to win the supermarket.

论文从我国广电的现状出发，结合实际，积极倡导采用新技术更新、改造我国现有的HFC网络；倡导广电现阶段利用自身优势，部署EPON网络来赢取市场。

A new general kinetic equation was derived in which the effect of the removal of condensation water was taken into account completely, and was applied to the polyesterification kinetic study of AA/HPHP and AA/NPG. It was found that the reaction order of self-catalyzed polyesterification was not constant. For these polyesterifications, the reaction order was 2.5 at a low temperature, while 3.0 at a high temperature.

考虑缩合水的排除对反应体系的影响，用体积浓度单位推导出一个新的聚酯反应总包动力学方程，并应用到AA/HPHP和AA/NPG两个聚酯化反应的动力学研究中，研究发现，自催化聚酯反应的反应级数并不是固定值，对于AA/HPHP和AA/NPG两个聚酯化反应而言，低温时反应级数为2.5，高温时反应级数为3.0。