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Analysis based on the experimental results demonstrated the plausible reaction mechanism is that vit C first converts Cu(superscript 2+) to its reduced state and vit C becomes vit C radical itself, thereby stimulating the formation of peroxyl and alkoxyl radicals, and bimolecular reaction of peroxyl radicals results in (superscript 1)O2 production in the systems studied.

根据实验观察的结果,分析了这一体系中(上标 1)O2形成的可能途迳,认为首先是维生素C将Cu(上标 2+)转变为还原态,而自身失去一个电子转变为维生素C自由基,从而刺激了过氧自由基和烷氧自由基的形成,过氧自由基的双分子反应很可能就是体系内(上标 1)O2产生的反应机制。

Syntheses of PPVs derivatives containing oxadizole by Heck reaction Chromophore of oxadizole was introduced into the chain of PPVs derivatives with alkoxyl as side-chain by Heck reaction.

二。通过Heck反应在PPV主链结构中引入噁二唑基团通过Heck反应将噁二唑引入了不同烷氧取代的PPV高分子主链,所得高分子在THF、DMF等常见溶剂中有较大的溶解度。

During the low temperature plasma polymerization, different factors (reaction power, pulse duty factor, reaction time, bias voltage and pressure) were investigated to get the best film. The results of X-ray photoelectron spectroscopy and Fourier transformed infrared spectoscopy implied that polymer nano-film containing carboxyl or amido were deposited successfully by using allylamine or acrylic acid as a reagent, respectively.

低温等离子聚合过程中,研究了反应的功率、脉冲占空比、反应时间、偏压、反应室压强这五个因素对薄膜性质的影响,确定了最佳的工艺参数。X光电子能谱和傅立叶转换红外光谱分析结果表明,以丙烯胺和丙烯酸为反应物可以在样品表面分别得到含有羧基或氨基的有机薄膜。

Because of the rapid development of allylation reaction in aqueous media, allylation reaction mediated by new metal systems or metal systems, and its mechanism are reported increasingly.

水相烯丙基化反应由于其发展速度较快,新的金属及金属体系参与的烯丙基化反应以及水相烯丙基化反应的机理研究不断被报道。

This article summarizes the latest research progress of the allylation reaction mediated by metals in aqueous media, and the new reaction mechanism is explained briefly.

本文综述了水相中金属参与烯丙基化反应的最新研究进展,并对新的反应机理作了简要的阐述。关键词:谢斌,冯建申邹立科,张秀兰

Amino-sulfonic acid single aromatic ring type high range water reducer was synthesized form aminobenzene sulfonic acid, phenol and formaldehyde. The influence of monomers ratio, reaction temperature reaction time, pH value, the concentration of monomer on the performance of AS high range water reducer was analyzed.

以对氨基苯磺酸钠、苯酚和甲醛等为原料合成出了氨基磺酸单环芳烃型高效减水剂,研究了反应单体的摩尔比以及工艺参数对AS高效减水剂对水泥颗粒分散效果的影响。

Amino-sulfonic acid single aromatic ring typehigh range water reducer was synthesized form aminobenzene sulfonic acid,phenol and formaldehyde. The influence of monomers ratio,reaction temperature,reaction time,pH value,the concentration of monomer on the performance of AS high range water reducer was analyzed.

以对氨基苯磺酸钠、苯酚和甲醛等为原料合成出了氨基磺酸单环芳烃型高效减水剂,研究了反应单体的摩尔比以及工艺参数对AS高效减水剂对水泥颗粒分散效果的影响。

The presence of solvent disfavors the reaction, whereas the participation of water in the aminolysis reaction plays a positive role and reduces the activation energy greatly.

没有水分子参与的情况下,路径a的反应能垒最低,而在有水分子参与反应时,按协同机理反应生成P2的反应路径略占优势。

METHODSThe compounds were prepared by using 2ethylpyridine, through the Whol Ziegler reaction, the Williamson reaction and aminolysis. The effects for ability of memory in mice were measured by swimming maze test.

方法]以2乙基吡啶为原料,经WholZiegler反应、Williamson反应及氨解反应得到2[1(2吡啶)乙氧基]乙酰4取代哌嗪,采用水迷宫法观察所合成的化合物对小鼠记忆力的影响。

One synthetic strategy started fromγ-butyrolactone 38, from which a cyclohexadiene intermediate 30 was prepared in an overall yield of 44% in a 7-step procedure after y-butyrolactone underwent a-bromination, dehydrobromination, Diels-Alder reaction, aminolysis, benzylation, bromination and dehydrobromination, with the key step being the Diels-Alder reaction under harsh condition.

其中一个路线从γ-丁内酯38开始,连续经过α-溴化、脱溴化氢、Diels-Alder反应、胺解、苄基化、溴化和脱溴化氢共7步反应,制备了一个环己二烯衍生物30,总产率44%,关键步骤是高温高压下Diels-Alder反应。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力