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Some research and analysis on the reaction of 2,4-difluoronitrobenzene and nucleophilic reagent alcohol sodium (methyl alcohol ,ethyl alcohol, propyl alcohol, n-butyl alcohol, t-butyl alcohol, et hl) and the reaction choice of opposite -F in different solvent and conditions have done in this paper.

论文以2，4-二氟硝基苯为主要原料，研究了其与亲核试剂醇钠(甲醇、乙醇、丙醇、正丁醇、叔丁醇等)在不同溶剂中的反应情况，讨论了在几种代表性的溶剂——醇、四氢呋喃、苯、N，N-二甲基甲酰胺中亲核取代反应的情况，研究了温度、反应时间、亲核试剂、溶剂等条件对亲核取代反应的影响。

The effects of reaction time,reaction temperature,content of hydroxyl propyl acrylateand n-propanol on the hydrophilicity of the films were discussed respectively.

这类材料一般兼有有机和无机材料的优点，如在保持有机高分子成膜性、透明性的基础上，又具有耐磨性、耐溶剂性、高硬度等优点[1]。

Pain is not only a body reaction but also a psychologic reaction.

摘要］疼痛不仅是躯体事件，更是一种心理事件。

Catalysts in three synthesis routes,the hydroxylation of 4-tert-butyl-phenol,the alkylation of pyrocatechol by tert-butyl alcohol and the alkylation of pyrocatechol by isobutene,were discussed in detail in terms of reaction conditions,catalysts,temperature,reaction time etc.

论述了对叔丁基苯酚羟基化法、邻苯二酚与叔丁醇烷基化法和邻苯二酚与异丁烯烷基化法生产对叔丁基邻苯二酚的合成路线的催化剂。

The method of phenanthroline-Fe2+reaction system and autoxidation reaction system of pyrogallol and the system of lipid peroxide were used to measure the antioxidation of the water extraction from C.

本文采用邻二氮菲-Fe2+氧化法，邻苯三酚自氧化法以及卵黄脂蛋白不饱和脂肪酸过氧化体系，对甘青铁线莲花水提取物清除超氧阴离子自由基O2-。

Pyronine B adheres to on the surface of CdS and prevents CdS aggregating, which leads to the decrease of fluorescence quantum yield of CdS. Fluorescence resonance energy transfer happens from CdS to Rhodamine B, Butyl rhodamine B and Rhodamine 6G, respectively. There is a higher FRET efficiency between CdS and Neutral red with the value being 0.282. Moreover, coupling reaction between -NH_2 of Neutral red and -COOH of CdS -TGA leads to red shift of CdS fluorescence spectrum. The reaction also occurs between Safranine T and CdS. At the same time, the Fluorescence of ST is quenched by forming ST -CdS ground state complex. Chapter 6, CdS QDs modified by chitosan and polyethyleneimine can be quenched by Cu~(2+). According to the experimental result, we develop the novel sensor for Cu~(2+).

研究结果，吡啰红与CdS之间作用形式是染料聚集在CdS的表面使得CdS不易聚集，但同时也降低了CdS的发光的量子效率；罗丹明B、罗丹明6G、丁基罗丹明B均与CdS之间存在能量转移，位阻效应使得能量转移效率最高的BRhB的相对荧光强度增大最小；中性红与CdS的能量转移效率更高，同时推测可能使CdS-TGA上的-COOH与部分NR的-NH_2发生偶联导致粒子变大而发生荧光光谱的红移；番红花红与CdS是相互荧光猝灭，可能是ST的-NH_2与CdS-TGA上的-COOH发生偶联使得纳米粒子变大以及二者形成基态复合物的共同作用的影响。

The reaction activity of kaolinite, illite and pyrophyllite is obviously different and the reaction activity of pyrophyllite is the highest.

高岭石、伊利石和叶蜡石的反应活性存在较明显的不同，其中叶蜡石的反应活性最大。

Previously, we reported chiral 2, 5-disubstituted pyrrolidine derivatives as chiral catalyst ligands in the reaction of diethylzinc with arylaldehydes. Very high yields and enationselectivities have been achieved in this asymmetric addition reaction.

我们小组以前合成的具有C〓-对称性的五员氮杂环类手性配体在二乙基锌和醛的不对称加成反应中取得了优良的结果。

A program based on four kinds of methods in thermal analysis is designed for finding out the mechanism of decomposition reaction of explosives and calculating their kinetic parameters. Compared with the Kissinger's method, the program here adopted has the advantage of exploring the reaction mechanism besieds a calculation of the kinetic parameters. Mechanism of decomposition of the explosive PYX was determined applying this program. The kinetic parameters of PYX calculated by non-isothermal integral meth...

以热分析理论为依据，摒弃了以往仅用一种热分析法进行反应动力学研究和近似假设─—炸药的热分解反应机理f＝（1—α）n所带来的弊病，采取4种热分析方法（等温积分法、等温微分法、非等温微分法、非等温积分法）相结合的方法，编制了计算程序，首先判断反应机理，然后求取动力学参数，用所编程序对PYX炸药的反应动力学进行了研究，用非等温法判断了PYX炸药的反应机理，并求得动力学参数，所求参数与Kissinger法求得的结果十分接近。

The excited-state intramolecular proton transfer tautomerism reaction of 6-methyl-4-hydroxy pyri-midine monomers and dimmers was investigated by the ab initio method with the self-consistent reaction field with Tomas's polarized continuum mode and CIS theories at HF level on the basis of 6-311+G* and 6-31G basis set. By studying the potential energy surface, it was found that the monomer's ground-state proton transfer process together with the excited-state proton transfer process is a molecular system of four energy level, but dimmers were not, which can be used to explain the fact that UV-visible absorption and fluorescence spectra of monomer and dimers all corresponded to quinoid.

采用 ab initio HF理论的组态相关CIS方法和连续溶剂模型PCM，分别在6-311+G*和6-31G水平上研究了6-甲基-4-羟基嘧啶单体及二聚体激发态质子转移的异构化反应；对其反应势能面的研究发现，单体基态和激发态的异构化反应一起可以形成四能级的分子电子体系，而二聚体的却不能，由此解释了单体和二聚体的紫外吸收光谱和荧光发射光谱均对应于酮式构型的原因。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。