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The apparent degradation reaction activity energy of PET and PC are evaluated to be 27. 19kJ. mol〓 and 35. 75kJ. mol〓 in system noncritical region respectively. The mass transfer and scatter, which are the controlling factors of degradation in system noncritical region, change into chemical reaction in system critical region, where the activity energy of PET and PC are evaluated to be 89. 79kJ. mol〓 and 80.61kJ. mol〓 respectively.

在系统的非临界区域,PET、PC的降解为液固相反应,反应速率很低,其降解反应表观活化能分别为为27.19KJ.mol〓和35.75KJ.mol〓,为传质、扩散控制;在系统的临界区域,PET、PC的降解为液态均相反应,降解反应速率显著提高,其降解反应表观活化能分别为89.79KJ.mol〓和80.61KJ.mol〓,为化学反应控制。

In order to determine the optimal conditions of water glass from oil shale ash, through orthogonal experiment, the influences of correlative parameters including NaOH concentration, material ratio (NaOH to oil shale ash in weight), reaction time and reaction temperature on the modulus of water glass or deliquescent rate of SiO2 were all studied.

为研究页岩灰制取水玻璃的最佳条件,分别以水玻璃模数和页岩灰中SiO2溶出率为指标,NaOH溶液质量分数、物料比(NaOH溶液与页岩灰的质量比)、碱浸时间和碱浸温度为影响因素。进行了正交试验。

Effects of some major factors on deoxidize rate of silver, such as Mix ratio connection of tartaric acid and glucose, over all concentration of mixed liquid, the pH level, the reaction temperature, the reaction time etc.

考察了酒石酸与葡萄糖的配比关系、还原混合液的总浓度、pH值、反应温度、反应时间对银还原率的影响,得出了酒石酸与葡萄糖、无水乙醇的质量比为1:2.6:1,pH值为12,在室温下放置时间为3-5d,银的还原率大于92.7%的最佳条件,总回收的金属银纯度为98.2%。

For water gas, the inspection of the amount of H〓 and CO is the basis. In the gasification reaction zone, deoxidize zone is the main reaction zone for generating flammable gas and it is also the core zone to control the gasification stability.

在空气煤气中主要检测CO〓含量,做为是否调控的依据,在水煤气中,而是检测H〓及CO的含量,做为是否调控的依据。

The results showed that nitrogen oxide was strongly deoxidized to nitrogen by iron; Petroleum coke char and CO could promote the heterogeneous reaction of Fe and NO, deoxidize iron oxides, and prolong the active time of iron; while limestone had little effect on the heterogeneous reaction.

结果表明:Fe对NO有很强的还原作用;石油焦焦炭和CO对Fe与NO之间的多相反应具有很强的促进作用,可还原Fe的氧化物,延长Fe的作用时间;而石灰石对Fe与NO之间的多相反应几乎没有作用。

At the same time,studying the depolarization reaction of D.desulf.has both anode and cathode depolarization reaction.

同时通过电化学试验,研究了D.des ulf的去极化作用,发现D.desulf的存在既有阳极去极化作用,又有阴极去极化作用。

Results of our experiments showed that the depolymerization rate of chitosan depended on the reaction temperature, the reaction time and the concentration of hydrogen peroxide.

实验结果显示,几丁聚醣之去聚合反应受到反应温度、反应时间及过氧化氢浓度的影响,当反应温度为60℃,反应时间为两小时且过氧化氢浓度为2 M时,可得到分子量约四万的几丁聚醣。

They had suppressed the cathodic process of carbon steel electrode. Their inhibition performance was also related with their molecule stereo conformation and electron configuration. Four of bis-(1, 1'-benzotriazoly)-α,β-diamide compounds linked via-CO 〓CO-chain were synthesized and certified by IR and 〓H-NMR. The minimum energy conformations of these compounds were obtained by MM2 forcefield program. The two benzotriazole moiety in BBT1 was more planar than in other compounds. This was beneficial in increasing the inhibition effects of BBT1. In 0.5M H〓SO〓 solution, BBT1 suppressed anodic corrosion reaction. In 3%NaCl solution, BBT1 suppressed both cathodic and anodic corrosion reactions. 1- [ (1'-imidazolly)-methyl] benzotriazole was synthesized by Mannich reaction.

合成了四个通过-CO〓CO-连接的双(1,1'-苯并三唑)-α,ω-二酰胺化合物,采用MM2分子力学程序优化了它们的分子结构,双(1,1'-苯并三唑)-α,ω-二酰胺化合物的缓蚀作用与其分子内两个苯并三唑单元的空间取向有关系,良好的平面性有利于苯并三唑二聚体的吸附和缓蚀作用,苯并三唑二聚体BBT1分子内两个苯并三唑单元近似平行,所以显示出较好的缓蚀效果。0.5M硫酸中BBT1主要抑制铜的阳极溶解的电化学反应;3%NaCl溶液中,BBT1对铜的阳极溶解和氧的阴极还原过程均有抑制作用,相比较而言对阴极过程的抑制作用更大一些。

2Nd, thorough analysis: The Earth may say is an extremely marvelous thermonuclear reactor, when the earth interior pressure achieved certain critical, in the Earth material may decay the nuclear matter is called as the thermonuclear material, can have the thermonuclear reaction, thus has the huge energy, then the melted partial materials, form the rock magma are the liquid state materials, this response stratification plane is possibly many stratification planes, first possibly is located between the earth's crust and the mantle, upward next two transfers, displays for the light density material diastrophism as well as density upper mantle material phenomena and so on solidification; Under second possibly is located between the mantle and the core, the pressure is more formidable, causes not not easily to have the thermonuclear reaction thermonuclear material to have the response, forms the relative quite stable liquefied material level, simultaneously is upward next two transfers, forms the counter-flow phenomenon which the high density under mantle as well as the high density core material contact liquefies and is far away cools; These material periodicity regular movements and so on convection as well as Earth polar axis rotation are possibly the basic source powers which the terrestrial magnetic field produces.

深入剖析:地球可以说是一个非常奇妙的热核反应堆,当地球内部的压力达到一定的临界,地球物质中可衰变的核物质统称为热核物质,就会发生热核反应,从而产生巨大的能量,进而融化部分物质,形成岩浆即液态物质,这个反应层面可能是多个层面,第一层可能位于地壳与地幔之间,向上下两边对流,表现为轻密度物质的地壳运动以及中密度上地幔物质的固化等现象;第二层可能位于下地幔与地核之间,压力更为强大,引起不易发生热核反应的热核物质发生反应,形成相对比较稳定的液化物质层,同时向上下两边对流,形成中高密度的下地幔以及高密度地核物质的接触液化和远离冷却的对流现象;这些对流以及地球极轴自转等物质周期性规律性运动可能是地球磁场产生的根本源动力。

First, the precursor polymer with azobenzene groups on main-chain was obtained by condensation polymerization between 4,4'-dihydroxyazobenzene and N,N-(2-bromoethyl)aniline through Williamson reaction. Then the azo polymer containing azobenzene groups both on main-chain and side-chain was prepared through an azo-coupling reaction between the precursor polymer and the diazonium salt of 4-nitroaniline.

设计并合成了一种新型的主侧链均含偶氮生色团的聚合物,首先通过4,4'-二羟基偶氮苯与N,N-二溴乙基苯胺之间的Williamson反应缩聚得到主链含偶氮苯基团的先驱聚合物,再通过重氮偶合反应得到目标产物,并利用核磁共振、红外光谱、紫外可见光谱、热分析等手段确认了所制备聚合物的结构。

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