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The influence of acrylic acid and cetane alcohol,amount of catalyst and inhibitor,reaction temperature,reaction time were investigated.

实验结果表明,合成的最佳反应条件为:丙烯酸与十六酯的物质的量之比为1.2∶1,对甲苯磺酸的用量为0.6%,对苯二酚的用量为0.4%,反应温度为110℃,反应时间为5 h。

The later is controlling step in BEGL The leaching of MnO2 in this system is dependent on the leaching of chalcopyrite. If the reaction of chalcopyrite can be performed, the reaction of MnO2 will continue.

MnO2的浸出在本研究的系统中是被动的,如果黄铜矿的浸出还能进行,MnO2的浸出就能持续。

Considering all the possible reaction products, a chemical reaction equation was established and a mathematical model of formulation design was obtained.

论述了混合炸药配方设计的基本思想,对含金属混合炸药,在考虑所有可能生成产物的情况下,给出爆炸反应方程式,得到了其配方设计的数学模型。

The research on N_4 to N60 have been also stated in this study. Gas reaction method, liquid electrolyzing method and Chemosynthesis method have been used to synthesize polynitrogen clusters and find the optimal reaction conditions in this paper.

本文综述了高能密度材料的发展历史、性能特征以及应用前景,并总结了人们在实验和理论两方面关于N_4到N_(60)的各种可能稳定存在的氮原子簇的研究成果。

And the optimum pH was 4-6 for the dechlorination reaction of 2,4-D, and pH between 2 and 8 were all suited for the reaction in Pd/Fe systems. Intermediate and final products of 2,4-D, HCH and chlordane with Pd/Fe were determined by GC/MS, and the possible dechlorination pathways were concluded: 2,4-D can be converted to phenoxyacetic acid through gradual hydrogenolysis, and HCH can be transformed to cyclohexatriene through dichloroelimination or dehydrochlorination.

通过GC/MS定性定量分析了三种目标污染物在Pd/Fe体系中发生还原脱氯反应过程中的反应物及最终产物,并根据反应产物推测分析了这三种有机污染物在催化还原反应体系中可能的反应途径:2,4-D主要通过逐级氢解最终生成彻底脱氯产物苯氧乙酸;而六六六则可能通过逐步双氯消除反应或脱氯化氢反应,最后生成环己三烯。

First, the preparation of l,2-dichloro-4-nitrobenzene, which l-chloro-4-nitrobenzene reacted with chlorine in a self-designed chlorinator, in presence of Lewis acid catalyst,.was investigated. By means of the Orthogonal Experiments design and single factor experiments, the influence of several reaction variables on the yield were examined and the optimum reaction conditions under the intervallic operation were obtained, the yield of l,2-diehloro-4-nitrobenzene was 83.26%.

为此,本文首先在自行设计的塔式氯化器中,以对硝基氯苯为原料,路易氏酸作催化剂,分子氯氯化合成3,4-二氯硝基苯(合成3-氯-4-氟-硝基苯的原料),根据该氯化过程特征,利用正交试验设计方法结合单因素实验考察了有关因素对氯化过程的影响,优化得到了最佳的氯化工艺条件,3,4—二氯硝基苯的收率可达83.26%。

The optimum conditions are 0.2 mol chlorobenzene, and 0.7 g catalyst, and 0.07 mol glycine, and 0.08 mol nitric acid, and reaction time of 3 hours, and reaction temperature of 45℃.

最宜工艺条件:氯苯为0.2 mol,催化剂为0.7 g,氨基乙酸为0.07 mol,硝酸为0.08 mol,反应温度为45℃,反应时间为3 h。

In my opinion, Cu complexes with unsaturated alcohol to form a complex compound; the nitrogenous compound introduced serves as the complex compound's stabilizing agent and reduces activation energy of reaction; TMPO serves as oxygen carrier and displays it's selective oxidation function. This new method and mechanism also demonstrates significance to other similar organic reactions.3 In the chlorohydrin reaction, NaCIO is replaced by Ca2see Chapter4.4.3.4(2 .A, this method hasn't been reported in previous literature,which exerts more buffer action to the react system, the yield increased from 52% to 88.6%; at the same time it solve the problem of poor stability and low percentage composition of NaCIO.

认为:CuD与烯醇形成络合物:含氮有机物的引入起到稳定络合物,降低活化能的作用:而TMPO则充当携氧子起传递氧的作用,并具有选择氧化功能:这种新的方法和理论对类似的反应(不饱和醇类在络合体系下选择性催化氧化为对应的醛也具有重要的指导作用。3在异戊二烯的氯醇化反应中,用次氯酸钙代替次氯酸钠见第4章4.3.4(2.A,本方法未见文献报道,使反应系统更加温和,收率由52%提高到88.6%:并解决了次氯酸钠稳定性差、有效氯含量低的实际问题,具有重要的实用意义。

Photo catalyst has the similar function of chlorophyl to supply the reaction space while without chemical reaction so that can be used for long time.

光触媒质类似于植物光合作用中的叶绿素,只提供了反应场所,本身不参与化学反应,所以能够长期使用。

If the laser is in ultraviolet-visible wave, photons activate choicely electron energy level or destroy weak bond of compound molecule, and result in chemistry reaction, which is photo leading decomposition mechanism, if the laser is in infrared wave, the chemistry reaction mainly is heat decomposition mechanism.

如果激光是可见紫外波段,光量子能量有利于选择性地激发分子的电子能级,或破坏化合物中弱键而诱导化学反应发生,化合物属于光致分解机理、引发弱键断裂机理;如果激光是红外波段,化合物表现的则是热分解机理。

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Lao Qiu is the Chairman of China Qiuyang Translation Group and the head master of the Confucius School. He has committed himself to the research and promotion of the classics of China.

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