查询词典 reaction

The technological scheme is that under the conditions one reaction temperature 40-200 deg.c, reaction pressure from normal pressure to 6.0 MPa and reaction velocity of 0.5-3/hr, C4 mixture as the main material is made to contact with catalyst to produce isooctene. The production process may be used in industrial production of selective C4 mixture dimerizing process to prepare isooctene.

本发明通过采用以混合碳四为原料，在反应温度为40～200℃，反应压力为常压～6.0MPa，反应液体体积空速为0.5～3小时-1条件下，反应原料与催化剂接触生成异辛烯的该技术方案较好地解决了上述问题，可用于混合碳四选择性二聚制异辛烯的工业生产中。

This Sm-catalyzed reaction firstly efficiently realized the catalytic cycle in the tandem rearrangement/reduction reaction of α-hydroxy epoxides, and moreover the diastereoselective amplification could be distinctly observed when two C1 epimers in substrate were subjected to this catalytic tandem reaction.

该催化的多功能串联反应，高度非对映选择性地一步控制了含有季碳的三个相邻立体中心，有效地构建了&2-季碳1，3-二醇&结构单元，首次实现了此类重排—还原过程的催化循环，其中对于两个C1位的差向异构体底物，此反应具有明显的非对映选择性放大特点。

In order to identify the ring-opening reaction between hydroxyl group and epoxide group, an analogous reaction was performed and the effect of reaction environment on conversion ratio was discussed in detail.

文中对羟侧基和环氧基的开环反应进行了模拟，并对大分子的反应程度及其影响因素进行了较详细的研究。

In chapter 3, general reaction of a-hydroxy epoxides were introduced. We have developed a newly gold-catalyzed ring opening reaction ofα-hydroxy epoxides containing carbon cycle. We have disclosed the rule of ring opening reaction. And the plausible mechanism was proposed.

第三章：首先介绍了α-羟基环氧化合物的反应，其次介绍了一个新的金催化的含碳环骨架的α-羟基环氧化合物开环反应，总结了反应规律，提出了可能的反应机理。

The rational reaction mechanism of alkylation with PTC was proposed and the experiments show that the alkylation reaction is a pseudo first-order reaction.

由实验得到的反应动力学方程符合拟一级反应，提出了合理的反应机理。

The reaction of disproportionation of gum rosin catalyzed by AH non-noble metal catalyst was studied, and the effects of reaction temperature, reaction time, particle size of catalyst, and stir speed were investigated.

用AH型非贵金属催化剂催化松香歧化反应，考察了搅拌速率、催化剂粒度、反应温度、反应时间对反应的影响，建立了动力学方程。

Thus if we control the reaction temperature at somesolvent we can obtain the products either by the reaction of phosphoryl-stabilizedcarbonanion with N-tosyl imines or by the reaction of methoxycarbonyl-stabilizedcarbanion with N-tosyl imines.

在一定溶剂中，如果控制反应的温度可以控制得到由膦酰基稳定的碳负离子和亚胺反应或由甲氧羰基稳定的碳负离子和亚胺反应。

From the potential energy profile, it can be predicted that, the dominant channel of this reaction consists of three steps: the two reactants first form a three-membered ring intermediate (INT1) through a barrier-free exothermic reaction of 19.2 kJ/mol; three-membered ring intermediate (INT1) isomerizes to a four-membered ring silylene(P2) via the transition state (TS2) with an energy barrier of 22.8 kJ/mol; four-membered ring silylene(P2) further reacts with ethene(R2) to form a silicic bis-heterocyclic compound (P3), which is also a barrier-free exothermic reaction of 132.2 kJ/mol.

用CCSD//MP2/6-31G*方法研究了单重态二甲基亚烷基硅烯与乙烯生成硅杂双环化合物环加成反应的机理，根据该反应的势能面可以预言，该反应的主反应通道有三步组成：第一步是两反应物（R1， R2）首先生成了一三元环中间体（INT1），它是一无势垒的放热反应，放出的能量为19.2 kJ/mol；第二步是三元环中间体(INT1)经过渡态TS2异构化为了四元环硅烯（P2），其势垒为22.8 kJ/mol；第三步是四元环硅烯（P2）进一步与乙烯(R2)反应生成了硅杂双环化合物（P3），该反应也是一无势垒的放热反应，放出的能量为132.2 kJ/mol。

Research on thermodynamics and kinetics of pyrolysis reaction mechanism Kinetic and thermodynaimic research of the pyrolysis reaction mechanism of toluene was conducted at different temperature range 298-1223K. The result shows that the pyrolysis reaction firstly occurs at the methyl on the benzene ring, and produces benzyl.

裂解机理的热力学与动力学研究在298K-1223K的温度范围内对甲苯热解机理的热力学和动力学研究结果表明，热解首先发生在苯环甲基C-H键上并生成卞基自由基，主要产物为联二甲苯，反应的活化能ΔE〓=402.27kJ/mol。

A type of modified methyl benzene sulfonic acid sodium salt was synthesized by Friedel-Crafts reaction,knoevenagel reaction and sulfonation reaction with methyl benzol as row material.

以甲基苯为初始反应物，通过付-克反应，knoevenagel反应，磺化反应，最后合成一种改性甲基苯磺酸钠。

But we don't care about Battlegrounds.

但我们并不在乎沙场中的显露。

Ah! don't mention it, the butcher's shop is a horror.

啊！不用提了。提到肉，真是糟透了。