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A method of production of a reduction resistant dielectric ceramic composition having a superior low frequency dielectric characteristic and further improved in accelerated lifetime of insulation resistance, specifically a method of production of a dielectric ceramic composition containing a main component including a dielectric oxide of a specific composition, a first subcomponent including a V oxide, a second subcomponent containing an Al oxide, a third subcomponent containing an Mn oxide, and a fourth subcomponent containing a specific sintering aid in a specific ratio, including a step of mixing at least part of the materials of the subcomponents excluding one or both of at least the material of the third subcomponent and material of the fourth subcomponent with the starting materials prepared for obtaining the material of the main component to prepare the pre-reaction material, a step of causing the prepared pre-reaction material to react to obtain a reacted material, and a step of mixing the materials of the subcomponents excluded when preparing the pre-reaction material with the obtained reacted material to obtain a dielectric ceramic composition.

本发明提供一种介电陶瓷组合物的制造方法,其中介电陶瓷组合物以特定的比例含有如下成分:含有特定组成的介电体氧化物的主成分,该主成分可以提供具有优异的低频率介电特性的、绝缘电阻的加速寿命进一步提高的耐还原性介电陶瓷组合物的制造方法,含有V氧化物的第1副成分,含有Al氧化物的第2副成分,含有Mn氧化物的第3副成分,以及含有特定的烧结助剂的第4副成分;该方法包含如下工序:将至少除去第3副成分的原料和第4副成分的原料的一种或两种的其它副成分原料的至少一部分,与为了得到主成分原料而准备的起始原料混合,准备反应前原料的工序;使准备的反应前原料反应而得到反应后原料的工序;以及在所得的反应后原料中,混合在准备反应前原料时除去的副成分原料,得到介电陶瓷组合物原料的工序。

The results show that the yield of compound 5 reached a maximum of 65% under the optimum reaction conditions, where the pH of the reaction medium was 3.8~4.0, the reaction temperature was 85~90 ℃, and the molar ratio of zinc powder to compound 1 was 2.6:1. The optimum oxidant for the selective oxidation of α-methyl on compound 5 was sulfuryl chloride, and the yield of the product was 52.5%.

结果表明,合成化合物5的最佳反应条件为:反应介质pH值为3.8~4.0,反应温度85~90℃,锌粉与反应物1之间的摩尔比2.6:1,产物收率达到65%;化合物5中α-甲基选择性氧化反应的最佳氧化剂为硫酰氯,产物收率达到52.5%。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷,包括:γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3,4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3,4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

When loading a nuclear fission reactions, release of fissile material can achieve the high-temperature thermo-nuclear center, high-density state and caused thermonuclear reaction thermonuclear reaction produces a large number of neutrons causing yet more fissile loading fission reaction took place, thereby improved efficiency.

当裂变装料发生核反应时,放出的裂变能使中心的热核材料达到高温、高密度状态并发生热核反应,热核反应产生的大量中子又使更多的裂变装料发生裂变反应,从而提高了利用效率。

Phenyl or m -tolyl selenoamides reacted with functionalized α-haloacetic acid in 1∶1 or 1∶2 molar ratio with no catalyst in various alcohols to undergo a selenium transfer reaction. This reaction in dif-ferent molar ratios furnished the same C—Se—Se—C coupling products with a special structure bis diselenide. A new and facile method for synthesis of such bis(alkoxycarbonyl-methyl) diselenides with the advantages of mild reaction conditions, high yields, easy availability of starting materials and good chemical selectivity was provided.

芳基硒代酰胺与氯乙酸在各种醇中无催化剂下以1∶1和1∶2的比例投入,发生硒转移反应,不同原料投入比下的反应生成了同一种C—Se—Se—C偶联产物——具有多功能团的二烷氧羰基甲基二硒醚,提供了一种新的合成二烷氧羰基甲基二硒醚的简便方法,且反应具有条件温和、产率高、原料易得和选择性好等优点。

The N + OH reaction system has no energy barrier in the entrance channel on the PES; instead, there are double wells along the reaction path, which leads to that the integral reaction cross sections are not strongly dependent on either translational energy or initial rotational and vibrational state.

计算还显示,由于N+OH反应入口谷没有能垒,而沿着最小能量反应路径有两个势阱,因此反应的积分截面并不强烈依赖平动能和反应物分子的初始振转态。

We studied trivalence chromium ion electrode reaction on three different surface state by cyclic voltammetry, discussed electrode activation influence on electrode reaction, and analysed the mechanism of electrode reaction. We discussed current efficiency during the first charge process and charge/discharge cycle performance by invariable current charge method.

应用循环伏安法考察了三价铬离子在三种不同表面状态石墨电极上的电极反应,探讨了电极表面活化处理对三价铬离子的电极反应的影响,并分析了电极反应的机理;采用恒电流充电的方法探讨铬液流电池初次充电过程的电流效率及恒电流充/放电循环的性能。

The experimental reaction kinetics data were represented by two models:(1) Pseudo-first order reaction mechanism incorporated with the zwitterion mechanism for CO2-AMP reaction mechanism.

而二氧化碳在混合醇胺水溶液之亨利常数、扩散系数将由氧化亚氮相似定律估算。

The result showed that the oxidation reaction of abietic acid is first-order reaction during the initial period but then isn't first-order reaction because of oxidant film.

实验结果表明,枞酸氧化反应动力学在初期阶段呈表观一级,后期受氧化膜影响不呈表观一级。

When the reaction temperatures were 303.15, 308.15, 313.15, 318.15, 323.15 and 328.15 K, respectively, the apparent reaction rate constants of abietic acid were 0.0036, 0.0041, 0.0062, 0.0087, 0.011 and 0.0157 min^(-1), respectively. Its reaction activation energy was 50.29 kJ/mol.

枞酸的氧化反应温度为30,35,40,45,50和55℃时,表观速率常数分别为0.0036,0.0041,0.0062,0.0087,0.011和0.0157min^(-1),表观反应活化能E为50.29kJ/mol。

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The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力