查询词典 reaction

To further extend the scope of this type Cannizzaro disproportionation reaction and the reactivity of enolate ligand in complex with aldehyde,we designed to synthesis new rare earth complexes containing arylamido and.enolate mixed ligands,studied their reactivity with aromatic aldehydes for the disproportionation reaction.

为了进一步探索这种歧化反应的应用范围及配合物中作为配体的乙烯醇基与醛的反应性，我们设计合成了含胺基、乙烯醇基混合配体的新型稀土配合物，并研究了其与芳香醛的反应。

In Granards' reactionof fluorinated β-ketophosphonium salts we found differentGranard reagents give different reaction mechanisms andPhMgBr realized the enolate reaction of fluorinatedβ-keto-phosphonium salts.

在研究含氟β-酮基鏻盐的β位亲核加成反应中，我们利用含氟α-烷氧基-β-酮基鏻盐与有机锂试剂的亲核加成反应一锅法高度立体选择性地合成了E式或Z式三氟甲基的烯醚类化合物。

Under optimal reaction procedures and reaction system, genomic DNA of a series of 10 times reference culture diluents of salmonella enteritidis extracted through poaching cracking process is taken as a template to carry through fluorescence quantitative PCR , and then specification curve is drawn. Based on linear relation R and augmentation efficiency E, whether the repeated sample data are consistent and whether initial templates with different copy numbers have the same augmentation efficiency are judged.

在优化的反应程序和反应体系下，以水煮裂解法提取的肠炎沙门氏菌标准菌株10倍系列稀释液的基因组DNA为模板，进行荧光定量PCR，绘制标准曲线，根据线性关系R 2 和扩增效率E来衡量重复样品数据是否一致和不同拷贝数的初始模板是否具有相同的扩增效率。

ELISA method was used for comparison. Results The positive rate of DIGFA in testing the serum from 50 infected rats was 96.0%(48/50). The negative rate of DIGFA in healthy rats was 100%(50/50). Cross reaction with Enteroclysis (13 samples) and Tapeworm (11 sqamples) was not observed. The cross reaction rate in 18 Strongyloidiasis rats was 5.6%. The sensitivity and specificity of DIGFA is comparable with ELISA (96.7%).

结果 用DIGFA检测广州管圆线虫实验感染鼠血清50份，其阳性检出率为96.0%，50份正常鼠血清的阴性符合率达100%，DIGFA分别检测蛲虫阳性鼠血清13份，绦虫阳性鼠血清11份和粪类圆线虫阳性鼠血清18份，前二者均为阴性，后者交叉反应率为5.6%；DIGFA与ELISA平行检测30份广州管圆线虫阳性鼠血清，两法符合率达96.7%。

The mathematical model of deflagration to detonation transition for coke p owder and oxygen mixture in one-dimensional closed system was established on th e basis of chemical reaction and two-phase reaction fluid mechanics theory. Num erical simulation of the process was successfully made through coordinate transf ormation and two-step display differential schemes.

根据化学反应和两相反应流体动力学理论，建立了焦炭粉-氧气混合物燃烧波在一维封闭空间内的爆燃爆震转捩现象的数学模型，运用坐标变换和M acCormack两步显式差分格式，成功地完成了过程的数值模拟。

Considering the effect of m any factors when the reaction reaches balance, and in order to increase t he rate of the product, the rate of the changing of sulfate dimthyle, we det ermined the best condition at last. The temperature is between 80 ℃ and 90 ℃. The for mula of the materials is 3∶1～4∶1.The time of reaction is between 4 and 5 hour s.

考虑反应达平衡时诸多因素的影响以及有利于提高产品的产率、硫酸二甲酯的转化率等问题，最后确定了最佳条件：反应温度为80～90 ℃之间，原料配比为3∶1～4∶1，反应时间为4～5 h。

Compared with the traditional process of esterify reaction, Employing the method of distillation with reaction can simplify the esterifying process, and save much energy and money.

结果表明，与传统的酯化反应过程相比较，采用反应精馏法可以简化酯化流程，节省大量能量和开支，是一项切实可行的方案。

3A biomimetic catalytic system M_n/CH_3CHO has been used in the selective oxidation of p-chlorotoluene.The effects of the center metal ions,the amount of catalyst and ethanal,the oxygen pressure,the reaction time,and the reaction solvents on the selective oxidation were investigated.

3将M_n/CH_3CHO仿生催化体系用于对氯甲苯的选择性氧化，研究了不同中心金属离子、催化剂用量、乙醛用量、氧气压力、反应时间及反应介质对反应的影响。

The results show that among the acetoacetonate complexes,Co_3 has the best catalytic activity.The optimum reaction conditions were as follows:0.764 mmol of Co_3,mole fraction of ethanal 10%based on the substrate,room temperature,oxygen pressure 2 MPa,reaction time 11h and solvent acetonitrile.Under these conditions,13.3%p-chlorobenzaldehyde was obtained with 15.3%conversion and 87.2%selectivity.The oxidation can also be carried out without solvent with 8.1%conversion,89.1%selectivity and 7.2%yield respectively.

在金属配合物中Co_3的催化性能最好，在其用量为0.764 mmol、乙醛用量为反应物物质的量的10%、氧气压力为2MPa时，以乙腈为反应介质，室温下反应11h，反应的转化率和选择性可达15.3%，87.2%，对氯苯甲醛收率可达13.3%；反应也可在无溶剂时进行，此时反应的转化率、选择性及醛的收率分别为：8.1%，89.1%，7.2%。

The optimum reaction condition was as follows: catalyst dosage=4.3% of the amount of ethanediol,reaction time 50 min.1,4-dioxane yield of 84.82% was obtained under the optimum condition.

考察了催化剂用量、反应时间和反应温度等因素对收率的影响，得出最佳反应条件：催化剂用量为乙二醇质量的4.3%，反应时间50 min，收率可达84.82%。

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应，而且减少跟风的可能性。