查询词典 reaction ring

The invention comprises the steps of dehydration reaction, purification treatment, bromization ring contraction integral reaction, separation, refining and by-product processing.

本发明包括脱水反应步骤、纯化处理步骤、溴代缩环一体化反应步骤、分离步骤、精制步骤和副产物加工步骤。

This paperindicated that it was good for condensation reaction when benzene-ring bearingelectron-attaching groups. It also showed that and the 6-hydroxyl group could bereacted with acyl halide, haloid ether and halo alkene, but not with halo alkane. It wasnot only the first time to find that the reaction product of D-mannitol and aromaticaldehyde is tri-condensation derivatives, but also the first time to obtain thep-phthaldehyde-sorbitol derivatives containing eight hydroxyl groups.

研究发现：苯环上有吸电子基团时对缩合反应有利；多元醇缩醛衍生物6-羟基除与酰氯反应外，也能和卤代酸酯、溴代烯反应，但不与卤代烷反应；首次发现D-甘露醇与醛反应主要得到三缩合物；首次合成了含有8个羟基的对苯二甲醛和山梨醇的缩合物。

In this article, weh ave utilized the ABEEM-σπ model to research this kind of reactions. Through regional softness values of both the atoms and π bonds, which are calculated by this model, we have interpreted properly the typical and particular stereoselectivity of Diels-Alder reaction. Furthermore, we also have initiatorily probed into the rationality and feasibility in terms of synthesizing heteroatomic -ring compounds using Diels-Alder reaction.

本文利用ABEEM-σπ模型对此类反应进行了研究，通过计算原子和π键区域的电荷分布和局域软度，结合局域硬软酸碱原理对Diels-Alder 反应的立体选择性给出了合理解释，而且还初步探讨了利用Diels-Alder 反应合成杂环化合物方法的合理性和可行性。

A novel biodegradable copolymer of poly and poly (γ-benzyl-L-glutamate) was successfully synthesized. Under appropriate conditions, the PBLG initiates the ring-opening polymerization of L-lactide to produce block copolymer, by using low toxicity stannous octoate as catalyst. The optimal reaction conditions were determined as follows; the catalytic agent: PBLG=1:1, the temperature is 120℃, the reaction time is 6h.

以L-丙交酯为原料，在催化剂辛酸锡酯Sn2的作用下，利用聚的活性端氨基引发LLA进行开环聚合，合成了聚L-丙交酯与聚的共聚物，对反应条件的各项因素进行了讨论，确定了最佳反应条件是：m：m=1：1；反应温度120℃；反应时间6h。

The reactions include, organometallic reactions (grignard reaction, organolithium -zinc, and -copper chemistry ), metal catalyzed reactions, mannich reaction, nitration, hydrogenation, azidation, amino-protection reactions, organoalluminum catalyzed beckmann rearrangement, schmidt rearrangement, epoxidation, epoxide ring opening reactions, swern oxidation etc.

这些反应包括：有机金属反应(格利亚反应，有机锂，有机锌和有机铜反应)，金属催化反应堆(suzuki 反应， negish 反应)， mannish 反应，硝化反应，氢化反应，叠氮反应，各种基团的保护和脱保护反应，有机铝催化的贝克曼重排反应，斯密特重排反应，环氧化反应，环氧烷开环反应， swern 氧化反应等。

The reaction of cyclic b-keto esters with CF3CO2ZnCH2I provides the corresponding ring-expanded products with the advantage of mild condition in moderate to good yields. A simple and efficient procedure has been developed for a variety of 1,3-diketones converted into the corresponding 1,4-diketones and trans-1,2-disubstituted cyclopropanols in high yields. In conclusion, this new type of organozinc reagents has been developed for many useful reaction in organic synthesis.

利用有机锌试剂所具有的双重特性，在新型的Baylis-Hillman反应中，可以直接与炔基酮和醛反应一锅制得多官能团的三取代的顺式烯；在b-酮酯化合物的扩环反应中，取得了重要进展，得到了增加一个碳的扩环产物，&一步法&合成，反应条件温和、环境友好；在1，3-二酮分子中成功地插入1个碳，合成出1，4-二酮和环丙醇，为现代有机合成提供了新的合成方法，具有良好的应用前景。

Chloro-5,12-naphthacenequinone was synthesized from 2-(1-hydroxy-2-naphthyl)carbonylbenzoic acid by chlorination reaction using a mixture of phosphorus pentachloride and phosphorus oxychloride as a chlorating agent and then by ring-closing reaction using sulfuric acid as a dehydrating agent.

以2-[(1-羟基-2-萘基)羰基]苯甲酸为原料、五氯化磷/三氯氧磷为氯化剂进行氯化反应，然后用浓硫酸脱水环化，合成了6-氯-5，12-萘并萘醌，优化了反应条件，总收率达68.2%。

New reactions found in this program include: photoinduced regioselective free radical addition to aromatic imines;photoinduced Dielse-Alder reactions of aromatic imines for synthesis of tetrahydroquinoline derivatives;Photoinduced radical cation mediated selective ring opening reaction of epoxides;Formation of novel macrocyclic crown ethers by photoinduced reaction of diazonaphthaquinones;photoinduced selective desilylation of silyl ethers.

用这种方法成功的发现了下列在有机合成中有意义的新反应：(1)光诱导产生的自由基正离子诱导的自由基对芳香亚胺的区域选择性加成反应；(2)用光诱导的芳香亚胺的Diels-Alder反应合成四氢喹啉衍生物；(3)经光诱导产生的自由基正离子基诱导的环氧化物选择性开环反应；（4）重氮萘酮在环醚中经光诱导反应形成新奇的大环冠醚；（5）硅醚的光诱导选择性脱硅基反应。

The results showed that the addition leading to -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 7 could proceed with good diastereoselectivity and excellent yield (95%).(3) The selective N-deprotection of -2-phenyl-2-(2-vinylpiperidin-1-yl) ethanol 2 without affecting the vinyl group in the substrate were untaken.(4) The Zip reaction for the transformation of -1-(3-aminopropyl)-3-methylazecan-2-one 8 to -7-Methyl-1, Sdiaza-cyclotetradecan-6-one 9 were undertaken. The results showed that, under controlled conditions, acceptable yields (43%) could be achieved and racemization can be minimized during the ring expansion reaction.

该合成路线与文献方法相比，反应条件较温和，也缩短了反应时间；(2)哌啶衍生物2与乙烯基格氏试剂进行加成反应的条件和立体选择性，取得了较好的结果（差向异构体比为80：20，产率95％左右）；(3)不饱和哌啶衍生物7在不影响碳碳双键的情况下去除苯基甘氨醇手性辅助基的条件；(4)具有羰基α位手性的氨基酰胺8在不同条件下经Zip重排反应转变为9的反应，控制反应条件，可使反应中消旋化减小到最小的程度。

The chemical ring expansion is complex and expensive, and causes a significant negative environmental impact. Therefore, an enzymatic reaction is greatly desirable to replace such chemical reaction.

由於这种化学扩环不仅制程复杂，而且会对环境造成相当程度的损害，因此一种利用酵素的生物扩环法取代目前的化学法是被高度期盼的。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失