查询词典 reaction rate

In the temperature rang from 120 to 150℃, the relations between the apparent reaction rate constant and temperature of the photochlorination in the side chain of m-chloromethyl benzene were: min-1 min-1 min-1 The apparent reaction activation energies are: Ea1=33.54、Ea2=32.45、Ea3=24.26kJ/mol.

在120～150℃温度范围内，间氯甲苯侧链光氯化表观反应速度常数与温度的关系为： min-1 min-1 min-1 表观反应活化能分别为：Ea1=33.54、Ea2=32.45、Ea3=24.26kJ/mol。

The yield of conversion and reaction rate were investigated under different reaction temperature, reactant ratio and catalyst amount through conditional experiment, and best conditions were confirmed, which was 75℃, the ratio of 1:4 for binary acid to ethanol and the amount of silicotungstic acid was 2% of mixing binary acid quality.

通过条件试验，分别考察了在不同的温度、投料比、催化剂用量情况下酯化反应的转化率和反应速率，最终确定了该反应的最佳反应条件：温度75℃，酸醇比为1：4，催化剂用量为混合二元酸质量的2%。

Taking into account the chemical reaction rate, internal diffusion and reaction heat, the theoretical model of regeneration process was established to investigate the regeneration within large coked catalyst particle.

综合考虑化学反应速率、内扩散和反应热的影响，建立单个催化剂颗粒表面烧焦过程的数学模型，模拟研究了粒径1000μm的球形催化剂的表面烧焦过程。

The apparent activation energies and reaction rate constants of clinker formation reaction were also got in this study by Gentling and Arrhenius equation.

此外，利用金斯特林格和阿仑尼乌斯方程得出了熟料形成反应的表观活化能和反应速率常数。

Using the theory of radiative capture reaction and combining our department experiment, we investigate two nuclear reactions, 11C12N and 12C13C, and calculate the cross sections and astrophysical reaction rate of them.

利用研究的辐射俘获反应的理论，我们结合了我所的实验工作，研究了两个天体物理感兴趣的核反应~(11)C~(12)N和~(12)C~(13)C，计算了它们的反应截面以及天体核反应率。

Can with water, alcohol and ammonia reaction, difference generate acids, esters and amides, the reaction rate than the corresponding ester and anhydride fast.

可与水，醇和氨反应，分别生成酸、酯和酰胺，反应速度比相应的酯和酸酐快。

According to the experimental results the reaction mechanism of gasification is proposed: firstly, the catalyst releases an oxygen atom from its rich-oxygen site to combine with a carbon atom and create a CO, then the CO molecule desorbs from the catalyst surface; next, the catalyst absorbs a CO2 molecule; and finally on the catalyst surface another CO molecule is created and the original rich-oxygen site gets an oxygen atom. On the basis of gasification process the material balance equations were built, which were solved by using numerrical integral methods and the reaction rate constants for four steps were obtained: they are 0.0703mol·g-1·min-1·kPa-1, 0.0959mol·g-1·min-1·kPa-1, 0.00539 mol·g-1·min-1 and 0.0321 mol·g-1·min-1·kPa-1 respectively.

根据实验结果推导得出了该反应过程是催化剂表面富氧活性部位先与煤焦反应生成一个CO分子，然后此CO分子从催化剂表面脱附，接着催化剂吸附气态的CO2生成一个CO并且夺得一个氧原子实现自身还原的过程，在此基础上建立了煤的催化气化的物料平衡方程组，对各步骤的反应速率常数进行了求解，在本文采用的实验条件下，各反应步骤的反应速率常数分别为0.0703 mol·g-1·min-1·kPa-1；0.0959 mol·g-1·min-1·kPa-1；0.00539 mol·g-1·min-1·kPa-1； 0.0321mol·g-1·min-1·kPa-1。

In order to surmount the problem of slow reaction rate of the Baylis-Hillman reaction, we employed N-tosylated imines as the electronphile.

因为醛和环状烯酮的反应很难进行，我们便用活性更高的亲电试剂磺酰亚胺代替醛进行Baylis-Hillman反应，取得了很好的结果，反应速度得到了很大的提高。

The interfacial chemistry, synergistic effects and interfacial kinetics of thesynergistic extraction system D_2EHPA-MPA-Fe~(3+) have been studied, where MPA is amono-alkyl phosphate extraction with long carbon chain. D_2EHPA in the mixed extractionsystem strongly exhibits the effect on the thermodynamics of micella formation and interfaceproperties of MPA. Some thermodynamic parameters of micella formation were obtained.The interfacial adsorption behaviour of D_2EHPA is opposite to that of MPA. Theemulsification for single MPA and the mixed system was discussed. The synergistic effectswere found in this mixed extraction system. It is proved that the process of Fe~(3+) extractionfor non-mixed extraction system is controlled by chemical reaction, the controlling reactionoccurs at the interface, and the reaction rate equation is obtained.

本文研究了协同萃取体系D_2EHPA—MPA—Fe~(3+的胶团形成热力学、界面特性、协萃效应和界面动力学(动力学控制机制和反应速率方程)研究发现，混合萃取体系中的D_2EHPA强烈地影响MPA的胶团形成热力学和界面吸附行为，得到了胶团生成常数、胶团形成自由能和临界胶团浓度的热力学参数D_2EHPA和MPA具有相反的界面吸附行为研究发现D_2EHPA—MPA混合萃取剂体系对Fe~(3+)产生了协萃效应动力学和界面化学的研究结果还证实了非胶束混合萃取体系的Fe~(3+)的萃取过程是受化学反应控制的，控制反应发生在界面上

The results of FT-IR 1H-NMR indicate the structure of polyester, and the 13C-NMR analysis of three quaternary carbon showed the existing of hyperbranched struscture, MALDI-TOF MS showed the hyperbranched polyester structure, the degree of branching of the polyesters determined by 13C-NMR being 0.408. The esterification reaction kinetics followed a second-order equation and the reaction rate was controled by the concemtration of carboxyl group and hydroxyl group,-d/dt=K.

以IR、1H-NMR证实了聚酯结构的存在，13C-NMR谱图上3种季碳的特征峰有力证实了超支化分子结构的存在，MALDI-TOF MS证明了超支化聚酯的成功合成，并计算超支化聚酯的支化度为0.408；探讨并建立了超支化聚酯的缩聚反应动力学方程－d/dt=K，该缩聚反应属于二级反应，反应速率由羟基浓度和羟基浓度共同决定。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。