查询词典 reaction rate

A compound 2-(3-hydroxyphenyl)[60] fullerene pyrrolidine was synthesized by the 1,3-dipolar cycloaddition reaction of the fullerene(C60) and azomethine ylide (prepared from glycine and 3-hydroxybenzaldehyde). The product was characterized by UV-Vis,1H-NMR ,FT-IR and MS. The reaction conditions affecting the yields of product were investigated and the optimum reaction conditions with product yield 75%(based on consumed C60) were:molar ratio of C60∶3-hydroxybenzaldehyde:glycine 1∶3∶6,reaction temperature 95℃,reaction time 18h.

利用甘氨酸和3-羟基苯甲醛与C60发生1， 3-偶极环加成反应，合成分离得到了2-(3-羟基苯基)[60]富勒烯吡咯烷，用UV-Vis、1H-NMR、FT-IR、MS等测试手段表征了产物的结构，并通过单因素方法，探讨了反应条件对产物产率的影响，得到最佳工艺条件：反应物摩尔比1∶3∶6，温度95 ℃，反应时间18 h，产物的产率可达75%（以消耗的C60计）。

The main work we did on synthesis: We studied bromination reaction influence factor in detail, such as reaction time、reaction temperature、solvent dosage、reagent mole ratio, and optimized the reaction condition, discussed reaction mechanism rudimentally.

本文在合成方面所做的工作：系统研究了对称二醇的单溴代反应反应时间、反应温度、溶剂用量、反应物摩尔比等因素对产率的影响。

The research result of the reaction between DMHAN and heptavalent technetium in nitric acid indicates that, in the studied range, DMHAN does not react with heptavalent technetium, which means that, heptavalent technetium does not directly consume DMHAN. 4, The research result of the reaction between MMH and Tc in nitric acid indicates that, this reaction is composed of three stages, induction period, fast reaction period and the termination of the reaction.

3，DMHAN和七价锝反应的研究结果表明：研究范围内，DMHAN不与七价锝发生反应，即七价锝的存在不会造成还原剂DMHAN的消耗； 4，MMH与七价锝反应的研究结果表明：MMH与七价锝的反应分为三个阶段，即诱导期、快速反应阶段和反应终止。

The Suzuki reaction, the coupling of organoborate compounds with organic electrophiles catalyzed by Palladium complexes, is a valuable Csp2-Csp bond forming reaction. The reaction has been drawing increased attention in that the reaction permit the use of organoboron compounds that are thermally stable and inert to water and oxygen.In this section microwave promoted Suzuki reaction of phenylboronic acid with benzyl halides catalyzed by Pd(PPh3)2Cl2 DMF/H2O(v/v=10 : 2) was first reported.

第四章：微波辐射下Pd配合物催化端烯与芳卤偶联反应研究本章中我们在微波辐射条件下，研究了PdclZ(P Ph3)：催化端烯与芳卤的偶联反应，合成出了七种乙烯基化合物；并分别考察了微波辐射功率、辐射时间、原料配比、和PTc等因素对反应的影响，优选出了较佳的反应条件，并根据文献及实验结果，讨论了可能的反应机理。

Four phenylalanine derivatives were synthesized with this approach. The condition of the condensation reaction was optimized. The side reaction of the Curtius reaction was studied and a urine by-product was isolated and characterized.b. Through the detailed study of the behavior of various N-acetyl phenylalanine methyl esters under the condition of the Bischler-Napieralski reaction, it was found for the first time that the formation of benzyl oxazole derivatives was a competitive approach with the normal B-N reaction.

一、基于Bischler-Napieralski反应设计了以苯丙氨酸衍生物为原料的路线，在这条路线的研究中，主要取得了以下结果：、建立了一条以芳香醛和丙二酸单甲酯为原料，通过缩合、氢化、Curtius等反应制备苯丙氨酸甲酯的通用合成路线，对其中的缩合反应条件及Curtius反应中的副反应进行了深入的研究，利用这条路线合成了四个芳环取代的苯丙氨酸单甲酯衍生物。

The side reaction of the Curtius reaction was studied and a urine by-product was isolated and characterized.b. Through the detailed study of the behavior of various N-acetyl phenylalanine methyl esters under the condition of the Bischler-Napieralski reaction, it was found for the first time that the formation of benzyl oxazole derivatives was a competitive approach with the normal B-N reaction. A convincing mechanism was suggested and a rule governing the reaction was summarized.c.

一、基于Bischler-Napieralski反应设计了以苯丙氨酸衍生物为原料的路线，在这条路线的研究中，主要取得了以下结果：、建立了一条以芳香醛和丙二酸单甲酯为原料，通过缩合、氢化、Curtius等反应制备苯丙氨酸甲酯的通用合成路线，对其中的缩合反应条件及Curtius反应中的副反应进行了深入的研究，利用这条路线合成了四个芳环取代的苯丙氨酸单甲酯衍生物。

The results show that:First, concentration of hydrogen peroxide have the most obvious influence to oil yield and carbon black yield,with the increase of concentration of hydrogen peroxide the oil yield first increase then decrease,when concentration of hydrogen peroxide is 8.19% or so,the oil yield reach to the biggest value, and with the increase of concentration of hydrogen peroxide carbon black yield decrese;Then,reaction time have more obvious influence to oil yield and carbon black yield,oil yield increase but carbon black yield decrease with the increase of reaction time;Thirdly,reaction tempreture have some influence to oil yield and carbon black yield,samely,oil yield increase but carbon black yield decrease with the increase of reaction tempreture;Finally,reaction pressure does almost no influence on oil yield and carbon black yield.

研究结果表明：过氧化氢质量浓度对产油率和炭黑产率的影响最为显著，产油率随过氧化氢质量浓度的提高先提高后降低，在过氧化氢质量浓度为8.19%左右时达到最大值，炭黑产率随过氧化氢质量浓度的提高而降低；反应时间对产油率和炭黑产率的影响也比较显著，产油率随反应时间的增加而提高，炭黑产率随反应时间的增加而降低；反应温度对产油率和炭黑产率也有一定的影响，产油率随反应温度的提高而相应地提高，炭黑产率随反应温度的提高而降低；在本文实验范围内，反应压力对产油率和炭黑产率基本上没有影响。

In this paper, firstly using natural fatty acids including lauric acid, myristic acid, palmitic acid etc. and disproportionated rosin as starting materials, the acyl reaction of starting materials with SOCl_2 respectively, and then using Schotten-Baumann condensation: on the reaction conditions of alkalescence, condensation of acylchloride with amino acid (sarcosine, glycine, alanine etc.), and then acidification, saltation. A series of anionic surfactants of N-acyl amino: sodium N-fatty acyl sarcosinate (SFS-12, SFS-14, SFS-16); sodiun N-fatty acyl glycinate(SFG-12, SFG-14, SFG-16); sodium N-fatty acyl alaninate(SFA-12, SFA-14, SFA-16)and sodium N-disproportionated rosinoyl aminatewere prepared. During the preparation of N-acylamino acid, the reaction conditions of acylchloride with amino acid condensation were identified by optimizing the synthetic conditions of N-lauroyl sarcosine: mol ratio of amino acid to acylchloride 2:1, reaction taken place in a solvent composed by acetone/water 2:1, acylchloride and 20% NaOH were slowly added to the reaction mixture at the same time while maintaining the pH at 9~10, after completion of adding maintaining reacting for 2.5h at 25℃.

首先以月桂酸、肉豆蔻酸、棕榈酸等天然脂肪酸和歧化松香为原料，与氯化亚砜反应制得酰氯，然后采用Schotten-Baumann 缩合法路线，即在碱性条件下，酰氯和氨基酸(肌氨酸、甘氨酸、丙氨酸等)缩合，经过酸化、成盐，合成一系列氨基酸型阴离子表面活性剂：脂肪酰肌氨酸钠，即月桂酰肌氨酸钠(SFS-12)、肉豆蔻酰肌氨酸钠(SFS-14)、棕榈酰肌氨酸钠(SFS-16)；脂肪酰甘氨酸钠，即月桂酰甘氨酸钠(SFG-12)、肉豆蔻酰甘氨酸钠(SFG-14)、棕榈酰甘氨酸钠(SFG-16)；脂肪酰丙氨酸钠，即月桂酰丙氨酸钠(SFA-12)、肉豆蔻酰丙氨酸钠(SFA-14)、棕榈酰丙氨酸钠(SFA-16)；N-歧化松香酰基氨基酸钠(sodium N-disproportionated rosinoyl aminate)，即N-歧化松香酰基肌氨酸钠(sodium N-disproportionated rosinoyl sarcosinate ，简称SDRS)、N-歧化松香酰基甘氨酸钠(sodium N-disproportionated rosinoyl glycinate，简称SDRG)、N-歧化松香酰基丙氨酸钠(sodium N-disproportionated rosinoyl alaninate，简称SDRA)。

The researching content was as follows: 1. When AlClx/HY zeolite be used as catalyst, the effects of the ratio of 2-methylnaphthalene to tetramethyl benzene, catalyst concentration, reaction temperature and reaction time on the conversion (based on 2-methylnaphthalene), yield and selectivity (both based on 2,6-DMN) were discussed. In addition, by orthogonal experiment, the optimum reaction conditions were determined at the same time. The optimum reaction conditions : the molar ratio of 2-methylnaphthalene and tetramethyl benzene =1:1, reaction temperature was 400℃.

具体研究如下： 1、以AlClx/HY型分子筛为催化剂，研究原料配比(2-甲基萘与均四甲苯的摩尔比)、反应温度和反应时间对2-甲基萘的转化率、目的产物2，6-DMN的收率和选择性的影响，并通过正交实验确定了该催化剂体系下的最佳反应条件为：原料的摩尔比为(2-甲基萘：均四甲苯)=1：1，反应质量空速为6h-1，反应温度为400℃。

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我们的产品是钛、镍、钼、钽、锆等稀贵金属材料加工；管、棒、丝、带、板、箔、网、饼环及合金制品；反应设备（500L反应釜、钛钢复合反应釜、钛外盘管加热反应釜、镍钢复合反应锅）；换热器（钛列管式换热器、钛板式换热器、镍换热器、钛螺旋板式换热器）；复合板（钛钢复合板、钛铜复合板、钛铝复合板成品）；配件及加热器（钛网蓝、钛法兰、钛螺母钛过滤器、钛泵、钛盘管、阳极、钛离心机、钛加热器、各种非标设备及配件。

Based on the relationship and the phenomenon model, an improved model of MR damper has been presented in this paper.

摘 要：本文在实验数据的基础上建立了磁流变阻尼器输出力与不同常电流控制量的关系，对现有的 p模型进行了改进。

I don't think our founding fathers were very fuckable.

我认为我们的开国元老没什么吸引力