查询词典 reaction rate

The results show that the yield of compound 5 reached a maximum of 65% under the optimum reaction conditions, where the pH of the reaction medium was 3.8~4.0, the reaction temperature was 85~90 ℃, and the molar ratio of zinc powder to compound 1 was 2.6:1. The optimum oxidant for the selective oxidation of α-methyl on compound 5 was sulfuryl chloride, and the yield of the product was 52.5%.

结果表明，合成化合物5的最佳反应条件为：反应介质pH值为3.8~4.0，反应温度85~90℃，锌粉与反应物1之间的摩尔比2.6：1，产物收率达到65%；化合物5中α-甲基选择性氧化反应的最佳氧化剂为硫酰氯，产物收率达到52.5%。

To develop an eco-friendly epoxy impregnating resin system for groundwall insulation of large generators, the curing reaction mechanism has been fully studied, the formulation and the curing techniques have been optimized, and the influence of different constitution on the curing reaction, microstructure, and final performances have been studied and characterized.In this paper, influences of different reactive organo-siloxanes on the curing reaction and performances of epoxy V.P.I.

本文研究比较了含有环氧基、氨基或乙烯基的反应性硅氧烷，包括：γ-缩水甘油醚氧丙基甲基二乙氧基硅烷、β-(3，4环氧环已基)乙基三乙氧基硅烷、γ-缩水甘油醚氧丙基三甲氧基硅、β-(3，4环氧环已基)乙基三甲氧基硅烷、γ-甲基丙烯酰氧基丙基三甲氧基硅烷、乙烯基三乙氧基硅烷和苯胺甲基三乙氧基硅烷对环氧V.P.I。

When loading a nuclear fission reactions, release of fissile material can achieve the high-temperature thermo-nuclear center, high-density state and caused thermonuclear reaction thermonuclear reaction produces a large number of neutrons causing yet more fissile loading fission reaction took place, thereby improved efficiency.

当裂变装料发生核反应时，放出的裂变能使中心的热核材料达到高温、高密度状态并发生热核反应，热核反应产生的大量中子又使更多的裂变装料发生裂变反应，从而提高了利用效率。

Phenyl or m -tolyl selenoamides reacted with functionalized α-haloacetic acid in 1∶1 or 1∶2 molar ratio with no catalyst in various alcohols to undergo a selenium transfer reaction. This reaction in dif-ferent molar ratios furnished the same C—Se—Se—C coupling products with a special structure bis diselenide. A new and facile method for synthesis of such bis(alkoxycarbonyl-methyl) diselenides with the advantages of mild reaction conditions, high yields, easy availability of starting materials and good chemical selectivity was provided.

芳基硒代酰胺与氯乙酸在各种醇中无催化剂下以1∶1和1∶2的比例投入，发生硒转移反应，不同原料投入比下的反应生成了同一种C—Se—Se—C偶联产物——具有多功能团的二烷氧羰基甲基二硒醚，提供了一种新的合成二烷氧羰基甲基二硒醚的简便方法，且反应具有条件温和、产率高、原料易得和选择性好等优点。

The N + OH reaction system has no energy barrier in the entrance channel on the PES; instead, there are double wells along the reaction path, which leads to that the integral reaction cross sections are not strongly dependent on either translational energy or initial rotational and vibrational state.

计算还显示，由于N+OH反应入口谷没有能垒，而沿着最小能量反应路径有两个势阱，因此反应的积分截面并不强烈依赖平动能和反应物分子的初始振转态。

We studied trivalence chromium ion electrode reaction on three different surface state by cyclic voltammetry, discussed electrode activation influence on electrode reaction, and analysed the mechanism of electrode reaction. We discussed current efficiency during the first charge process and charge/discharge cycle performance by invariable current charge method.

应用循环伏安法考察了三价铬离子在三种不同表面状态石墨电极上的电极反应，探讨了电极表面活化处理对三价铬离子的电极反应的影响，并分析了电极反应的机理；采用恒电流充电的方法探讨铬液流电池初次充电过程的电流效率及恒电流充/放电循环的性能。

The experimental reaction kinetics data were represented by two models:(1) Pseudo-first order reaction mechanism incorporated with the zwitterion mechanism for CO2-AMP reaction mechanism.

而二氧化碳在混合醇胺水溶液之亨利常数、扩散系数将由氧化亚氮相似定律估算。

The result showed that the oxidation reaction of abietic acid is first-order reaction during the initial period but then isn't first-order reaction because of oxidant film.

实验结果表明，枞酸氧化反应动力学在初期阶段呈表观一级，后期受氧化膜影响不呈表观一级。

The optimum reaction conditions were as follows: rosin 5 g, m: in: m 1:2:2, palladium chloride 0.090 %, n: n1:10, hydrogen pressure 5 MPa, reaction temperature 160℃ reaction time 3 h, mass fraction of abietic acid could be under 1%, mass fraction of dehydroabietic acid was 5.6%, which conforms to the national standards. The regeneration of catalyst was investigated. After cycling five times, the product of hydrogenated rosin still conforms to the national standards without any treatment of catalyst.

在松香5g、m：m：m1：2：2、氯化钯0.090%、n：nl：10、氢气压力5MPa，反应温度160℃，反应时间3h的较佳工艺条件下，产物氢化松香中极酸的质量分数小于1%，去氢枞酸的质量分数5.6%，符合GB/T 14020-2006国家标准；并对催化剂的重复使用性能进行了考察，催化剂相不经过处理直接重复使用5次后，产品氢化松香仍然符合国家标准中关于枞酸和去氢枞酸的指标要求。

By using GC/MS, the process of oxidizing reaction of atractylone is studied, and five decomposition products are obtained, which is greatly different from the references-only two decomposition products, and the mechanism of oxidizing reaction of atractylone is investigated. The hypothesized mechanism of reaction is: atractylone is readily to additively react with water and to generate the semiacetalhydroxyl at 1, 4-site.

利用GC/Ms法跟踪分析了苍术酮纯品的分解过程，得到5种分解产物―与文献报道的苍术酮转变成2种产物存在较大的差异；研究了苍术酮的氧化反应机理：苍术酮与水易进行1，4加成反应，生成半羧醛羟基。

Based on the relationship and the phenomenon model, an improved model of MR damper has been presented in this paper.

摘 要：本文在实验数据的基础上建立了磁流变阻尼器输出力与不同常电流控制量的关系，对现有的 p模型进行了改进。

I don't think our founding fathers were very fuckable.

我认为我们的开国元老没什么吸引力