查询词典 reaction rate

The AM1 method was used for a quantum chemistry study of the phenol hydroxylation reaction mechanism. The possible reaction path of the phenol and oxyhydrogen free radical was optimized, and the structures of stable intermediates in the reaction mechanism were also obtained.

本文还首次采用AM1方法对苯酚羟基化反应机理进行了量子化学研究，将苯酚与氢氧自由基的反应沿可能的反应路径进行几何优化，得到反应历程上相关驻点稳定构型的三维结构。

Whenpyridine was used as reductive decomposing agent, the expecting cholest-4-en-3,6-dione-22-al was obtained. However, when Zn/HOAc was used to decomposethe ozonide, C-4,5 double bond was further reduced to give cholest-3,6-dione-22-al as main product. 2 For the side-chain construction of compound (1), the solid-liquid phase-transfer Wittig reaction was used. When (3-methyl-2-oxobutyl)-triphenylarsonium bromide was used as reagent, the reaction can be carried out inmild reaction condition and the yield is higher than that when phosphorane wasused.

但使用Zn／HOAc作为分解剂时，却得到其氢化产物胆甾-3， 6-二酮-22-醛；2在甾体支链引入过程中，采用固-液相转移Wittig反应的方法，用(3-甲基)-2-氧丁基三苯基溴化胂作为试剂，反应在非常温和的条件下便可完成，而且产率比传统采用膦烷的方法更高；3在对某些甾酮化合物的选择性还原反应研究时，发现在〓还原体系中，当加入某些金属离子后，反应有更好的区域选择性和立体选择性。

The optimum conditions were reaction temperature 120°C, reaction time 20h, mole ratio of 5-chloromethyl-2-oxazolidinone and sodium phenolate 1:1. 3,5-Dimethylphenol and epichlorohydrin in sodium hydroxide were condensated to give l,2-epoxy-3-phenoxy propane, then the reation of l,2-epoxy-3-phenoxypropane and the carbamate afforded oxazolidinone in the yields of 69.0%~76.0%. The side reaction had been avoided effectively by the uses of the excessive epichlorohydrin and mixed catalysts.

用3，5-二甲基苯酚和环氧氯丙烷在氢氧化钠存在下缩合生成苯氧基环氧丙烷，然后和氨基甲酸酯反应生成噁唑烷酮，采用过量环氧氯丙烷和使用混合催化剂，有效的避免了副反应的发生，提高了噁唑烷酮的产率，产率69.0%～76.0%。

The polyesterification reaction of DFA and EG was regarded as research object.The polyesterification reaction process of polyacid and polyalcohol was studied andimproved, and condition of synthesis reaction was determined.

3以二聚脂肪酸与乙二醇酯化反应为研究对象，研究和改进了多元酸和多元醇缩聚反应的工艺，确定了二聚脂肪酸-乙二醇聚酯合成的工艺条件。

The experimental results show that the content of SiC in RBSC increases with carbon content while α-SiC is chosen as a filler. However, the residual carbon would appear in specimens when the carbon content exceeds 30% by weight. Using carbon felt, the reaction-formed SiC particles are small and uniform in size and distribution. However, when carbon felt is impregnated with phenol resin, the reaction-formed SiC is nonuniform in size and distribution. X-ray diffraction shows that the fabricated RBSC is composed of α-SiC,β-SiC, and free Si. The polytype of SiC is related to the reaction-heat during sintering.

结果表明：选用α-SiC+C粉的混合物作为生坯，SiC相的体积分数随生坯中wC的增加而增加，但过大的wC将使硅化后的试样出现残碳；选用碳毡作为生坯，反应烧结碳化硅的显微组织特点是C／Si反应生成的碳化硅颗粒均匀细小，并呈线状分布在游离硅中；浸渍过树脂的碳毡硅化处理后的显微组织特点是反应生成的碳化硅颗粒粗大且呈不均匀分布。X射线衍射结果也表明，反应烧结碳化硅陶瓷由游离Si、α-SiC、β-SiC组成，试样中不同晶型碳化硅的出现与C／Si反应的放热过程有关。

This article that focuses on the systematic and in-depth research in the current primal problem about abnormal burst pressure reservoir depress burst pressure has procured following main fruits:1 It forms the method which could obtain massive vertical static state mechanics parameters.2 In a foundation of acquisition of rock mechanics parameters,apply bent lamella that as mechanical model along with characteristic of actual geologic characteristics to analysis curvature for anticlinal strcture, get homologous tectonic stress value throug relation between the curvature and stress and different principal curvature in anticlinal structure,consequently set up laminational stress model for anticline reservoir. The block lamination for existed fracturing date has formed method of setting up mechanical model of lamination terrestrial stress by abtaining the block tectonic stress coefficients which are got by complex utilization test, laboratory test and fracturing date playback.3 Analysesing the main reason which lead to high burst pressure by considering the characteristic of reservoir geology,reservoir,and rock mechanics and reservoir damage,etc.Establishing burst pressure quantitative prediction model which provide gist for depressing construction risk and optimizing construction craft under the condition of open hole completion ,gun-perforated completion and damaged reservoir.4 Provding theoretical basis for interpreting acidification pretreatment which could depress busrt pressure by finding the relation between the influencing factors and rock machanics parameters and analysing the factors that have effect on rock mechanics parameters. Expounding the mechanism of reaction of mixed monomineral and acid from the angle of microcosmic element, evaluating quantitatively acid sensilility of different kinds of mineral effectively, and determing the first-order reaction dynamical equation of each mineral.5 Revealing rock mechanics property chage as a result of acid flooding in different condition by sandstone traumata experiment in different temperatures which combined with rock mechanics triaxial stress experiment.6 Associating damage mechanics with sandstone acidizing, established sandstone damage mechanics model in the foundation of the recognition on the rock mechanics parametric variation which is caused by acid-rock reaction in both macroscopic view and microscopic view ,also demonstrated those processes and quantitative estimated the acid busrt pressure to direct the site operation.

本文针对目前异常破裂压力储层降低破裂压力的主要问题展开较为系统和深入的研究，取得了以下主要成果：1形成了利用测井资料，结合室内岩芯测试结果，获取静动岩石力学参数的相关性特征，从而获得纵向上大量静态力学参数的方法。2在获取了岩石力学参数的此基础上，利用弯曲薄板作为力学模型，结合区块实际地质特征对背斜构造进行曲率分析，通过曲率与应力的关系，利用背斜构造不同部位的主曲率求得相应的构造应力值，从而建立起背斜储层的分层应力模型；对已有压裂资料的区块分层，形成了综合利用测试、室内实验、压裂资料反演获得该区块构造应力系数，建立起分层地应力的力学模型的方法。3综合考虑储层地质、油藏、岩石力学特性和储层伤害等因素，分析造成高破裂压力的主要原因，综合利用岩石力学、弹性力学等知识，建立了裸眼完井、射孔完井条件下以及储层受到伤害后的储层破裂压力定量预测模型，为降低施工风险和优化施工工艺提供了依据。4完成了物性、岩性影响岩石力学参数的因素分析，找出了各影响因素和岩石力学参数之间的关系，为从机理上解释酸化预处理降低破裂压力提供了理论基础；从微观元素的角度阐述了单矿物与酸反应的机理；并在此基础上，有效评价了各种矿物的酸敏感性，定量确定了岩石中各矿物的一级反应动力学方程。5完成了不同温度下的酸液类型、酸液浓度、注酸量等一系列砂岩损伤实验，结合岩石力学三轴应力实验，系统揭示了在不同条件下注酸而引起的岩石力学性质变化。6将损伤力学与砂岩酸化相结合，在宏观、微观两个方面认识酸岩反应引起岩石力学参数变化基础上，建立了砂岩损伤力学模型，并对其进行验证，在此基础上定量计算酸化后的破裂压力，有效指导现场施工

It is one mixed response through reacting progressional research proved solidify reacts, different solidify cross-linking reaction is coinstantaneous, but what basically undertake is uncle amino reach second amino with annulus the reaction between oxygen radical, this kinds of reaction makes system be able to solidify.

通过反应级数的探究证实了固化反应为一复杂反应，不同的固化交联反应同时发生，但主要进行的是伯氨基及仲氨基和环氧基之间的反应，该类反应使得体系得以固化。

Thus, the optimum synthesizing condition was found here, namely input material ratio 3 to 1, reaction temperature 67℃, and reaction time 3 hours. The hydrolysis process of the pyrophosphate byproduct, which is brought by phosphating reaction, is also discussed well in this paper and the full hydrolysis condition of pyrophosphate is obtained finally.

论文对副产物焦磷酸酯的水解反应进行了研究，得到了焦磷酸酯完全水解的条件：水解温度为80℃、水的用量为4%、水解时间为12小时，解决了因焦磷酸酯存在而造成的对磷酸化反应产物分析困难的问题。

A common heating oxidation device(fig.1)is to place a silicon plate in a quartz crystal glass reaction chamber. In the reaction chamber, a electric resistant wire heating device heat up the chamber to a certain temperature(usually, the temperature is 900～1200℃. In a special condition, it can be descended to under 600℃). When oxygen or water vapour pass through the chamber(typical gas flow speed is 1cm/s). A chemical reaction is generated on surface of the silicon plate.

常用的热氧化装置（图1）将硅片置于用石英玻璃制成的反应管中，反应管用电阻丝加热炉加热一定温度(常用的温度为900～1200℃，在特殊条件下可降到600℃以下)，氧气或水汽通过反应管（典型的气流速度为1厘米/秒）时，在硅片表面发生化学反应

Synthesis of target compounds namely: to vanillic acid as the starting material with methanol under reflux conditions for 4 - hydroxy -3 - p-methyl, then ether, and nitration, reduction, cyclization reaction 6 - methoxy -7 - benzyloxy-quinazoline -4 - one, and then by the chloride in place of aniline, benzyloxy-off, such as etherification reaction of the target compounds; target compounds with the second and third occurrence of substitution reactions of amines by the TM1, that is, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(N, N-diethyl amino) oxy c] quinazoline; with ether occurred Ornidazole reaction of TM2, namely, 4 - amino-benzene -6 - methoxy -7 - [2 - hydroxy -3 -(2 - methyl -5 - nitroimidazole) C oxy] quinazoline.

本论文以嘌呤类似物喹唑啉为母核，分别在其4位和7位引入结构多样的取代苯氨基和柔性侧链，设计了一系列4-取代苯胺基-6-甲氧基-7-(2-羟基取代丙氧基)喹唑啉类化合物。目标化合物的合成即：以香草酸为起始原料，与甲醇回流条件下得到4-羟基-3-甲氧基苯甲酸甲酯，然后经过醚化、硝化、还原、环合反应得到6-甲氧基-7-苄氧基喹唑啉-4-酮，然后再经氯化、取代苯胺、脱苄氧基、醚化等反应得到目标化合物；目标化合物与二乙胺发生胺取代反应得到了TM1，即4-苯氨基-6-甲氧基-7-[2-羟基-3-丙氧基]喹唑啉；通过与奥硝唑发生醚化反应得到TM2，即4-苯氨基-6-甲氧基-7-[2-羟基-3-(2-甲基-5-硝基咪唑)丙氧基]喹唑啉。

The work of this paper is as follows: 1. Looking back the progressing history of the linear motor, introducing the features of the elevator driven by linear induction motor, radicating the topic of this paper "the digital frequency variable control of the elevator bi-side direct driven by linear induction motor". The research of this paper covers the conventional VVVF control, space vector based VVVF control, vector control and DTC.

本文主要开展了以下几个方面的工作： 1 回顾了直线电机发展历史，电机的驱动技术演变，特别是针对直线电机的驱动，简要介绍了直线感应电机驱动电梯的优点和不同结构类型，对传统的v／f控制，基于空间矢量法的v／f控制，矢量控制，和基于电压空间矢量的直接转矩控制进行了比较，确立了本课题的研究主题：直线感应电机双边直推式驱动电梯的全数字变频控制。

The article combines with the treatment of a superficial civil air defense work to introduce how the grouting method to improve the performance of the backfill soil.

文章从治理漂浮人防工事的角度提出了注浆技术在改善回填土性质方面的应用，并详细阐述了注浆技术的施工流程。