查询词典 reaction rate

As well as activity was exhibited. Theaddition of cinchonidine led to a remarkable increase in the reaction rate, as confirmed bythe IR study that the modifier activates the carbonyl groups of the reactant through itsquinuclidine nitrogen. On the contrary,〓 exerted a strong inhibition effect on theenantioselective hydrogenation. Chapter 3 Finely dispersed polyvinylpyrrolidone-stabilized iridium andbimetallic clusters were prepared by the alcohol-water reduction method.

第三章 采用醇水还原的方法制备了聚乙烯基吡咯烷酮稳定的铱纳米簇及双金属纳米簇，对丙酮酸甲酯的催化氢化表明，在铱金属簇催化体系中，辛可尼定不仅诱导了一定的对映选择性，同时对反应活性有明显的促进作用，平均反应速率可提高2-6倍。

On the basis of a great deal of the experimental data processing and analysis, the combustion converted account reaction rate constant, the unstable heat-exchange coefficient variation law between the airflow and the roadway rock and the codomain determined under different fire conditions have been provided with the correctness of the theoretical calculation formula for description of the airflow energy loss of the fire area tested and verified, a large number of the basic data concerning mine fires obtained.

通过大量实验数据的整理分析，给出了矿井火灾时期燃烧折算反应速率常数、风流与巷道岩石间的不稳定换热系数的变化规律及不同火灾条件下的取值范围，验证了火区风流能量损失理论计算式的正确性，并获得了大量的矿井火灾基础数据。

To master the relation of reaction rate constant and temperature.

掌握反应速率常数与温度的关系。

The reaction rate constant and its term of validity at room temperature was calculated by Arrhenius equation.

结果依达拉奉和注射剂的含量下降符合一级动力学模型，有关物质增加符合零极动力学模型。

The study and determination of reaction rate constants has always been one of the main research fields in chemistry.

化学反应速率常数的研究和测定工作一直是化学领域主要研究课题之一。

In addition, some modifications on several computational methods are also presented. Using LMTO method the electronic structure of several systems are studied, and some results are obtained. They are: The ideal Nb (100) surface has three surface states, the multi-layer relaxed surface has two surface states. The surface energy of the ideal surface is higher than that of the relaxed surface, that means that the multi-layer relaxed surface is more stable than the former one, which supports the LEED results. The mono-layer relaxed Ag (111) surface is the most stable one among several" stable surface models"presented by several researchers. The surface energy of Ag (111) surface is higher than that of surface Ag (001), which supports some experimental results such as different reaction rate at different surface orientations for the same material. The surafce states of Si (111) surface not only locate near the Fermi level, but also in the valence band, which agrees well with Cohen's conclusion. Si (111)-H is an effective model for analysing the surface states and H adsorbed on the back surface is a good method for improving the convincingness of the results obtained on thinner slab models. The surface stability depends on three different kinds of MoSi〓(001) surfaces, the surface with mono-layer Si is the most stable one, and the surface with Mo at the first layer is the most unstable one among them. These are consistant with the Kemoda's experimental results. The valence bands of clean or K adsorbed CdTe (111) surface agrees well with the synchrotron radiation studies. The surface of CdTe (111) consists of four kinds of surface models which show different surface electronic structures and different surface structure stabilities. The conclusion agrees well with Wu's experimental work. The different absorbed alkali metals on the CdTe (111) surface give different adsorption characteristics which have relations not only with the valence electrons, but also with the core ones of the alkali metals. The electonic structures of Si-C alloys are different from that of Si-Ge alloys, and the energy band gaps of Si-C alloys do not increase linearly with Carbon concentration, our conclusion supports Alexander's results, but conflicts with Soref's one.

现分述如下： LMTO方法及其应用方面：1）通过对Nb（100）表面电子态分析发现清洁理想表面有三个表面态，多层弛豫表面有两个表面态；表面能大小说明多层弛豫表面更稳定，支持了LEED结果。2）通过对采用不同方法获得的几种不同Ag（111）表面稳定结构的表面能计算分析，给出了单层弛豫表面为Ag（111）表面的最稳定结构；从Ag（111）单层弛豫表面和Ag（001）表面的表面能比较，发现了Ag（001）表面表面能要比Ag（111）小的，表明了同种物质不同表面取向将表现出不同物理、化学性质，这是与实验中得出的结论是吻合的，3）通过对Si（111）表面态分析，不仅发现了Si（111）表面不仅具有居于费米能级附近的悬挂键所对应的表面态，而且还有很多表面态位于价带能量范围内，与Cohen等结果一致，H饱和slab模型背表面相当于增加了slab层的厚度，是一有效的变相增加slab层厚的方法，弛豫表面较清洁理想表面价带谱们低能端的少许移动，预示着总能降低，说明弛豫表面较清洁理想表面稳定。4）MoSi〓具有三种表面，从费米能级上态密度值大小得到单层Si表面最稳定，Mo原子为表层原子的表面最不稳定，双层Si原子表面居中的结论，这与Kemoda等人实验结果是一致的。5）通过对CdTe（111）表面表面电子态、表面结构稳定性及表面H、碱金属吸附的电子结构系列研究，不仅得出了CdTe（111）清洁及碱金属K吸附价带谱与同步辐射光电子谱相吻合的结果，而且发现了CdTe（111）表面具有四类不同原子近邻特征，表现出四类不同的表面结构及电子结构特征：不同表面态分布、不同的表面结构稳定性（表层原子与次层原子成三键有一悬挂键的表面要比表层原子与次层原子成一键有三悬挂键稳定（与Wu等人实验结果一致））、不同的H吸附特性。

Solution of the electrostatic Coulomb interaction between ions of the liquid phase reaction rate.

溶液中的静电库仑作用对液相中离子间反应速率的影响。

The results indicate that the time of rearrangement decreases greatly near critical region, which account for the increase of reaction rate in supercritical water.

结果发现，在临界点附近，水分子的动力学重排时间急剧缩短，这就使得以超临界水为介质的化学反应速率大大增加。

The cross-reaction rate with CEA was 6%,with AFP,CA125 and CA153 was negligible.

本方法与CEA有6％交叉反应，与CA125、CA153和AFP均无交叉反应。

Results indicate that the serum titers of the two kinds of antibodies all reached 3.2×10^5, however, the antibody produced by the immunogen prepared via glutaraldehyde showed higher affinity. The CTC half inhibition concentration (IC50) was 96.2μgmL^(-1) the detection limit was 6.67ngmL^(-1), and the cross-reaction rate between tetracycline and CTC was 77%. The research layed a good foundation for the detection of the antibiotics in livestock products.

结果表明，2种血清的抗体效价最高均达3.2×10^5%，而戊二醛法制备的抗原产生的抗体具有更高的亲和力，抑制率为50%时的金霉素的质量浓度(IC50)为96.2μmL^(-1)，金霉素的最低检测限为6.67ngmL^(-1)，金霉素和四环素的交叉反应率为77%研究结果为畜产品中四环素类抗生素残留的检测奠定了较好的基础。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。