查询词典 reaction rate

The reaction mechanism between nickel ion and butynediols in the electroless plating process was analyzed. The results show that the change of BOZ concentration is a quasi first-order reaction, the change of the nickel ion concentration is related to the BOZ density, and this change belongs to a higher order reaction. The reaction rate equation was determined as dC/dt=-8.585×10^(-4)+1.188×10^(-4)t-4.64×10^(-6)t^2+5.8×10^(-8)t^3-2.3×10^(-11)t^4. The activation energy of this process decreases as temperature increases, and it decreases with the BOZ concentration as 64-423 mg/L, it increases with the BOZ concentration as 123~240 mg/L. The S value is positively correlated to temperature, when the temperature is 80℃, the reaction rate and S value are the largest; while when the temperature is above 80℃ and BOZ concentration is over 160 mg/L, S value and the reaction rate decrease gradually.

结果表明，镀液中BOZ浓度的变化是准一级反应，镍离子的浓度变化与BOZ的浓度有关，属多级反应，其反应速率方程为dC/dt=-8.585×10^(-4)+1.188×10^(-4)t-4.64×10^(-6)t^2+5.8×10^(-8)t^3-2.3×10^(-11)t^4，反应体系的活化能E随温度的升高而减少，随BOZ浓度的变化而变化：当BOZ浓度在64~123mg/L时，E线性减少；在123~240mg/L时E线性增加。S随温度的升高而增加，当温度达到80℃时S值最大，反应速度最大；当温度超过80℃，BOZ浓度大于160mg/L时，蝎的值逐渐减少，反应速度降低。

Transmission Electron Microscope and other properties testing results show that the complex emulsifier system is the crucial influence factor of the polymerization process and the properties of products. It may influence the coagulum content and reaction rate of the polymerization process, the performance, particle diameter,viscosity, electrolyte stability and storage stability of the emulsion products and the contact angle of the film.The initiator mainly influences the coagulum content and reaction rate.The acrylic monomers mainly influence the solid content, Minimum Film Formation Temperature of the emulsion and the Glass Transition Temperature of the film.The organic silicone monomer mainly influences the water absorption of the film.The reaction temperature mainly influences the reaction rate and conversion.The stirring intensity mainly influences the coagulum content of the polymerization process.

透射电镜等性能测试结果显示：复合乳化剂体系是硅丙共聚乳液的聚合过程及产品性能的主要影响因素，它可以对聚合过程的凝胶率、反应速率以及乳液的外观、粒径、粘度、耐电解质稳定性及贮存稳定性，还有乳液涂膜的接触角等造成不同程度的影响；引发剂主要影响反应速率和凝胶率；丙烯酸酯单体主要影响到乳液的固含量、最低成膜温度以及涂膜的玻璃化转变温度，有机硅单体主要影响涂膜的吸水率等；聚合反应温度主要影响乳液的反应速率和转化率等；搅拌强度主要是影响到聚合过程的凝胶率。

With the reaction time is variable speed integration of the equation fitting response curve Determine the apparent Michaelis constant (apparent MichaelisMenten constant, Kmapp) and the most apparent reaction rate (apparent maximal reaction rate, Vmapp).

用反应时间为自变量的积分速度方程拟合反应曲线确定表观米氏常数(apparent MichaelisMenten constant， Kmapp)和表观最大反应速度(apparent maximal reaction rate， Vmapp)。

The formation of our 1D nickel wires can be ascribed to the cooperative effect of the reaction rate and magnetic field.The reaction rate in the system is controlled mainly by adjusting the reactant concentration when other reaction conditions are fixed.When the concentration of Ni~(2+) is low,the reaction rate is correspondingly slow,so the complex[Ni(N_2H_4)_x]~(2+) preferentially migrates to the magnetic line of force since paramagnetic metal ions are attracted toward the maximum field.

当反应物Ni~(2+)浓度较低时，反应速率相对较慢，[Ni(N_2H_4)_x]~(2+)优先选择迁移到磁力线附近并且沿着磁力线方向排列，导致电极电势增大，于是[Ni(N_2H_4)_x]~(2+)的化学还原反应也是沿着磁力线发生，结果导致了镍纳米线的形成。

By using a fracture simulation unit,the regularity that temperature,flow rate and fracture width influence on HCl/dolomite reaction rate is investigated.The sequence of temperature,flow rate,acid concentration and fracture width influence to the acidic rock reaction rate is also studied in a four factors and four levels orthonormal test,and the sequence that acid concentration＞flow rate＞temperature＞fracture width is found.At the last,the possible HCl/dolomite reaction mechanism model which can explain the influence factors is derived.

文中利用人工模拟裂缝装置，研究了温度、注酸排量、裂缝宽度等因素对盐酸/白云岩反应速率的影响规律；并采用四因素四水平的正交试验，综合考察了温度、排量、酸浓度、缝宽四种因素对酸岩反应速率的影响的主次顺序，发现对酸岩反应速率影响力的大小次序为：酸浓度＞排量＞温度＞缝宽；最后，提出了盐酸/白云岩反应可能的机理模式，并根据这一模式对诸因素的影响进行了合理的解释。

For intramolecular electron transfer reactions in solution,the fluctuations of the intramolecular vibrational modes are much faster than that of solvent mode.Thus,the reaction-diffusion equation is commonly used to describe the motion of solvent,with a sink function to treat the vibrational high-frequency mode.Based on this theory-so -called the Sumi-Marcus theory,we proposed an imaginary-time split operator approach to solve the reaction-diffusion equation.The approach is applied to evaluate the intermolecular ET rate between oxazine 1 and N,N-dimethlaniline.By measuring the two average survival times of the donor state probability and the rate constant in long time limit,the full kinetics of the ET is revealed with a variety of sink functions.

对于扩散控制的溶液中的电子转移反应，分子内振动模的运动比溶剂运动快很多，Sumi-Marcus理论提出用反应扩散方程(reaction-diffusion equation)处理溶剂的扩散运动，而分子内的振动用sink函数来表示，我们基于此理论发展了用虚时间分裂算符的方法(imaginary-time Split operator approach)解反应扩散方程，并将其应用于嗪1(oxazine 1，OX1)和N，N-二甲基苯胺分子之间的电子转移反应，Sink函数采用几种不同的微扰表达式，通过计算得到给体几率衰减的两种平均速率和长时间极限下的速率常数，揭示了该体系电子转移过程中的一些动力学性质。

The results showed that the population administered with free adjuvant cholera vaccines,both low dose group and common dose group,occurred the weak adverse reaction with 10￣25% rate.The reaction rates between two dose groups of the same vaccine have not significant difference;The reaction rate of the first inoculation(19￣25%) is higher than those of the second inoculation(10￣15%)(P 05);The inoculating local reaction is very light ,only the very few subject occurred the scleroma with 15 mm of diameter.The reaction of aluminum absorbed cholera vaccine is slightly stronger than those of other groups.

结果表明，不加铝佐剂的O139型霍乱菌苗及O1群霍乱菌苗，不论是低剂量组（两剂全程接种45亿菌体）抑或常剂量组（全程接种90亿）接种人群均可产生10～25％的体温呈轻度升高的弱反应，并且同种菌苗的两剂量组的反应率无显著差异；第一剂接种的反应率（19～25％）较第二剂接种的（10～15％）高，P＜0.05；接种局部反应轻微，只有个别受试者出现直径小于15mm的硬结；加佐剂的O1群吸附霍乱菌苗的反应较其它组强。

The results demonstrated that the fractional conversion and reaction rate were rapidly increased in the initial curing reaction. The higher the curing temperature, the higher the fractional conversion and reaction rate was. With increasing of the curing temperature and time, the fractional conversion and reaction rate decreased and became constantly. The initial curing reaction was a first order reaction. The apparent activation energy and frequency factor of curing reaction used G- capryl ester was bigger than that of used G-oligomer.

结果表明：固化体系在研究的固化温度下，转化率和反应速率在固化反应初期增加快速，温度越高增加越快，随着固化时间的延长，这种变化逐渐变慢，并最终趋于恒定；初期固化反应为一级反应，反应初期的表观活化能和指前因子大小顺序为G-预聚体＞G-辛酯。

The effect of reaction, mixing and temperature on reaction rate in the space of instantaneous reaction rate -unreacted main reactant was studied using retention time as an objective, and a new strategy for the synthesis of reactor networks was presented under steady state, isochoric and non-isothermal anditions.

本研究以反应器系统为对象，以停留时间为目标，针对稳态、恒容、非等温条件下的化学反应过程，在瞬时反应速率 r和关键反应物的未转化率x空间探讨了反应、混合、温度对反应速率的影响，提出了在r x空间非等温反应器网络综合的新策略。

The research show that from anthracite, lean coal to bituminous, reaction rate become more and more large and ignition activation energy become more and more small; ignition activation energy falls and reaction rate increases as the volatile content increases;With the carbon content of dry ash-free basis increasing, ignition activation energy increases and reaction rate falls.

结果表明：从无烟煤，贫煤到烟煤，其反应速率越来越大，频率因子越来越小，着火活化能越来越低；挥发分增加，活化能减小，反应速率变大；干燥无灰基固定碳含量增加，着火活化能增加，反应速率减小。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。