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Heterogonous catalysis means the reactants and the catalyst are in different phases.

P41 异相催化指反应物和催化剂在不同的相中，相反，均相催化指反应物和催化剂在同一相中。

These concrete worksare the following:1, a new heterogonous SHS model had been proposed, which first included all the relativematerials characters, such as reactants particle sizes, changeable heat-conductivity and massdiffusion during SHS and so on, and its chemical reaction characters, initial combustion status.This new model made a more precise prediction about the SHS combustion way and itsTechnological characters possible.2, with the heterogonous SHS model, lots of combustion way had been imitated by changesystems relative factors and the rule of the combustion way change had also been studied,chemical reaction in these systems was controlled by a single mechanism.

在该模型中，首次将体系的微观不均匀特性、体系的基本物性及燃烧过程中的化学反应机理与整体燃烧动力学行为联系在一起，从而为更加准确地预测和控制SHS体系的燃烧行为，优化SHS的工艺过程奠定了理论基础。2、采用非均质燃烧模型，通过对相关参数的改变，模拟SHS燃烧过程中的各种燃烧行为，并研究了燃烧行为变化的规律。

The synthesis of green oxane from isobutyl aldehyde and 2,2,4-trimethy-1,3- pentanediol catalysed by HY zeolite was studied. The effects of ratio of reactants,temperature,solvent,dosage and the recycling of catalyst were investigated.

研究了以异丁醛和2，2，4-三甲基-1，3-戊二醇为原料，HY沸石分子筛为催化剂合成了青叶口恶烷的反应，考察了醛醇比、反应时间、带水剂、催化剂用量与其循环使用性对该反应的影响。

The synthesis of butyl isobutyrate with n-butanol and isobutyric acid as reactants and rare-earth solid superacid SO_4~(2-)/TiO_2/La~(3+) as catalyst has been studied.

研究了以稀土固体超强酸 SO_4~（2－）／TiO_2／La~（3＋）为催化剂，异丁酸和正丁醇为原料合成异丁酸丁酯，并考察了影响反应的因素。

The optimal conditions were found to be: n:n=1:1.5; mass fraction of catalyst to reactants, 1.0%; reaction time, 0.75 h and dried cyclohexane, 8 mL. Under these conditions, the yield of cyclohexanone ethylene ketal was 87.7%.

实验结果表明，在n∶n=1.0∶1.5、催化剂用量占反应物料总质量的1.0%、反应时间0.75 h的条件下，环己酮乙二醇缩酮的收率为87.7%。

The effects of reaction time, mole ratio of reactants and amount of catalyst on yield of ketal were investigated by using the [SO3H-bPy] [H2PO4] ionic liquid as catalyst. Results show that the ionic liquid was an efficient catalyst for the ketalization with high conversion and selectivity in mild conditions.

以磺酸基功能化的吡啶磷酸类离子液体[SO3H-bPy][H2PO4]为催化剂，系统考察了反应时间、酮与醇的配比、催化剂的用量及催化剂重复使用、不同阴离子、阳离子等因素对反应的影响，优化了反应条件。

The ketalization of cyclohexanone and 1,4-butanediol catalyzed by the Hβ zeolite was studied.Effects of reaction time,mole ratio of reactants and amount of catalyst on the yield of ketal were studied.Results showed that the Hβ zeolite was an efficient catalyst for the synthesis of ketal.

研究了Hβ分子筛催化1，4-丁二醇与环己酮的缩合生成新型七元环缩酮的反应，考察了反应时间、酮与醇的配比、催化剂用量、催化剂重复使用等因素对醛与醇缩合反应的影响。

The reaction rate of the reactants milled at high temperature was higher than that of milled at room temperature.

但由于反应在高温进行，球磨活化作用有失去的趋势，球磨对反应的促进作用就会减弱乃至消失。

To assess the thermal contribution from oxidation reaction, the standard formation enthalpes of all reactants and products were used to calculate the oxidation enthalpies. It could be found that all oxidation reactions were exothermic. And oxidation played a more important role during the toluene trinitration at high temperature, because the reaction temperature of toluene trinitration is the higher than mononitration and dinitration, and the temperature coefficient of oxidation is higher than that of trinitration too.

为了考察不同阶段氧化副反应对反应放热的贡献，用反应物和产物的标准生成焓推得氧化反应的理论反应热，计算结果表明，各段硝化的氧化副反应均为放热反应，其中三段硝化反应由于反应温度最高，氧化反应的温度系数比硝化反应高，故氧化副反应对三段硝化影响最大。

Firstly, a series of organic molecules which use phthalimido group as electron acceptor, N as electron donor, COO~- as eletrofugal group were synthesized based on SET-promoted photocyclization processes. These compounds were irradiated by 500 W ultraviolet under nitrogen atmosphere in room temperature. After filtration of the photochemical character of these molecules, substrate S1 and S2 were selected as appropriate model reactants. Secondly, the monosubstituted derivatives at the 6-position ofβ-cyclodextrin were synthesized as chiral template of photocyclization.

首先，以单电子转移机理为指导，设计了一系列以邻苯二甲酰亚胺基为电子受体、N为电子给体、羧基为离去基团的光环合反应底物，这些化合物在氮气保护下以500瓦紫外光室温下进行光照反应，对这一系列的分子的反应情况进行了研究与筛选，最终选择底物S1和S2作为研究光环合反应中立体控制方法的模型底物；其次，又合成了一系列6-位单取代β-环糊精，以此作为光环合反应的手性模板。

On the other hand, the more important thing is because the urban housing is a kind of heterogeneity products.

另一方面，更重要的是由于城市住房是一种异质性产品。

Climate histogram is the fall that collects place measure calm value, cent serves as cross axle for a few equal interval, the area that the frequency that the value appears according to place is accumulated and becomes will be determined inside each interval, discharge the graph that rise with post, also be called histogram.

气候直方图是将所收集的降水量测定值，分为几个相等的区间作为横轴，并将各区间内所测定值依所出现的次数累积而成的面积，用柱子排起来的图形，也叫做柱状图。