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1H NMR spectroscopic analysis of aromatic protons combined with theoretical analysis of molecular structures proved the existence of two rotational isomers at 300 K, as well as a rapid interconversion equilibrium at 330 K for both compounds Ⅰ and Ⅱ. However, only one conformer exists for compound Ⅲ and puerarin containing 7-phenolic hydroxyl instead of propyl in A-ring as the case of compounds Ⅰ and Ⅱ. Based on UV-Visible absorption data of neutral and basic solutions, and on the density function calculations, the 7-phenolic hydroxyl group in A-ring was found to be more acidic than the 4'-phenolic hydroxyl group in B-ring. The mechanism of derivation reaction and the structure-reactivity relationship of puerarin as an antioxidant were further discussed.

其中7-丙基葛根素Ⅱ属于新型取代衍生物;变温1H NMR和理论计算结果表明,在300 K时,葛根素和4'-丙基葛根素以单一构型存在;而7,4'-二丙基葛根素和7-丙基葛根素则存在两种核磁可分辨的旋转异构体,当温度升至330 K时,两种异构体可以相互转化;通过对比分析葛根素及其衍生物脱质子产物的紫外可见吸收光谱并结合理论计算,确定了A环上7位酚羟基比B环上4'位酚羟基先脱去质子,并由此进一步阐明了葛根素衍生化反应机理以及在抗氧化作用中可能的活性位点和结构活性关系。

The author explores the following questions:"rigid understanding the relationship between the teaching of knowledge and the cultivation of students' capabilities","the passive influences to the historical teaching at middle school brought by the controversy between the falling behind of the teaching stuff and the rapid knowledge update","the lack of originality of researching topics, the weakness of the consciousness of research, the confusion of pedagogical ideas and the inappropriate inclination in teaching practices", and so on.

笔者从"僵化理解知识传授与能力培养的关系"、"教科书内容的滞后和知识更新的矛盾对中学历史教学的消极影响"、"科研选题创造性不足,问题意识不强,教育学概念混淆以及教学实践中的错误倾向"等中学历史教学诸如此类问题进行了分析,并探讨了解决对策。

With the rapid rise in economy in China, traffic demand increases in high-speed. Traffic congest has been a severe problem which battles the people's life and economy development.

随着现代中国经济的快速发展,交通需求量急剧膨胀,交通拥挤已经成为一个严重影响人们生活和社会经济发展的问题。

With rapid development of urban economy,the problem of traffic congestion becomes more and more serious.

随着城市经济的发展,交通拥挤的问题变得越来越突出,交通拥挤收费逐渐成为解决这一问题的新管理措施。

Network congestion has become an important issue with the rapid development of the Internet.

随着互联网规模的增长,拥塞已经成为一个十分重要的问题。

The rapid development of socialist construction in our country needs a great quantity of timber,particularly coniferous,which are often used in architectural structures.

随着社会主义建设的发展,需要大量木材,用于建筑结构的针叶树木材就显得更加珍贵了。

Now, the rapid development of computer and occurrence of a great deal of large-scale optimization problems make the researches in conjugate gradient method revive.

近年来,随着计算机的飞速发展和实际问题中大规模优化问题的涌现,寻找快速有效的共轭梯度法成为了学者们研究的热门方向之一。

A Foundation Model - the Graded Component Object Model of Product Family is offered on the analysis of knowledge characteristics of PFM. Then, the component object, the Conjunctional Hiberarchy Model of Product and the relationships among component objects are defined respectively. Whereafter, the rapid generating mechanism of the instances of component objects and product is introduced. Based on the theory of GCOM, an Enhanced Model - the Skeleton Model of Product Family is offered.

通过分析产品族模型蕴含知识特性,提出了一种具体的产品族基础模型表达——产品族元件分级对象模型,分别定义了各级元件对象、层次联接结构模型和元件对象关系,并探讨了产品族元件分级对象实例的生成与产品实例快速获取的机制。

Justice and efficiency have become the two values and targets of modern criminal judicatory, in order to find out the best conjuncture of them, countries of the two systems of law have set up all kinds of criminal procedure of rapid decision besides the general criminal procedure.

公正与效益已经成为现代刑事司法的两大价值目标,为了寻求两者的最佳结合点,两大法系国家在刑事普通程序之外,均创设了形式各样的刑事速决程序。

High-tech company supported by science and technology innovation as the driving force of Connotative stick to the path of development to achieve the rapid development of production and operation.

公司以高科技为支撑,以科技创新为动力,坚持走内涵式发展道路,实现了生产经营的高速发展。

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推荐网络例句

The split between the two groups can hardly be papered over.

这两个团体间的分歧难以掩饰。

This approach not only encourages a greater number of responses, but minimizes the likelihood of stale groupthink.

这种做法不仅鼓励了更多的反应,而且减少跟风的可能性。

The new PS20 solar power tower collected sunlight through mirrors known as "heliostats" to produce steam that is converted into electricity by a turbine in Sanlucar la Mayor, Spain, Wednesday.

聚光:照片上是建在西班牙桑路卡拉马尤城的一座新型PS20塔式太阳能电站。被称为&日光反射装置&的镜子将太阳光反射到主塔,然后用聚集的热量产生蒸汽进而通过涡轮机转化为电力