查询词典 racemates

Some economic and practical polysaccharide-based chiral stationary phases for HPLC were prepared and applied to the enantiomeric resolution of a variety of racemates.

本论文选择高效液相色谱手性分离为研究目标，制备了一些经济、实用的多糖类手性固定相，并对多种手性化合物的拆分进行了研究。

The chromatographic parameters of these racemates on AD, OD and OJ columns at various ratios of hexane/2-propanol were examined.

考察了它们于不同浓度配比的这类洗脱体系中在柱上的色谱行为。

Many studies dealing with chiral drugs which are administered as their racemates rely on non-stereoselective analytical techniques. It was shown that the use of such an analytical method can lead to the collection of data which may be both quantitatively and qualitatively inaccurate with respect to the individual enantiomers.

一般非对掌选择性的药物分析条件，得到的药物血中浓度是个别镜像异构物的总和，而非个别镜像异构物的血中浓度，因此并无法对於对掌性药品的立体选择性动态学做定性或定量的探讨。

In recent years, optically active polymers have attracted much attention because of their unique functions such as molecular recognition, optical resolution for racemates and catalytic activity in asymmetric transformations as well.

近年来，光学活性聚合物的合成与结构—性能研究深受国内外学者的高度关注，这是由于这些合成材料具有潜在的应用前景，如：光学活性聚合物可应用于外消旋混合物的对映异构体分离，即光学拆分过程；不对称吸附、手性诱导及许多有机化学反应过程中的不对称催化。

With high efficiency, high selectivity, security and environmental friendship, the biocatalysis possesses significant advantages over chemical catalysis in organic synthesis, especially in the asymmetric synthesis of the enantiomerically pure compounds and in the resolution of racemates.

生物催化的高效性、选择性、安全性以及环境友好等优点，使其在一些化学合成领域，特别是在对映体纯的手性化合物的合成和消旋体拆分等方面，具有化学催化不可比拟的优势。

In our study, the synthesis of spice and the resolution of racemates menthol,(R, 5-4-hydroxy-3-methyl-2-(2-propenyl)-2-cyclopenten-1-one (R, S-HMPC were achieved in ionic liquids by three lipase that are usually used in biocatalysis. Meanwhile, some problems associated with enzyme catalysis in ionic liquids were also addressed.

本论文以三种常用于生物催化的脂肪酶作催化用酶，在&绿色&反应介质—离子液体中实现了香料的合成和手性对映体的拆分，同时也对酶在离子液体中催化所存在的问题进行了一些探讨。

Resolution of-1,-2,-3 and-1,-2,-3 were performed via their corresponding camphorsulfonates of the racemates.

得到这些双山黄皮咔唑后，我们用D--樟脑磺酰酯为拆分手性源，成功将各消旋体的樟脑磺酰酯在硅胶柱上进行了手性分离，首次获得手性的双山黄皮咔唑-1，-1，-2，-2，-3，-3。

Some compounds possessing chiral center themselves may be racemates and appear racemic phenomenon in the extraction and separation from medicine herbs, structure modification and chemical synthesis.

但是，由于含有手性中心的中药有效成分本身可能是消旋体、或者在分离提取、结构改造及化学合成时会出现外消旋化现象，使新药研制与开发中面临对映体成分的分离制备、体内手性药物分析及对映体特异性药代动力学研究等重大难题。

Firstly, synthetic racemates of β- amino acids were resolved into their enantiomers by ehiral ligand - exchange flash chromatography with L - hydroxyproline chemically bonded to irregular silica as the stationary phase and aqueous solution containing cupric ions as the mo

首先合成L-羟脯氨酸硅胶键合手性固定相，用于快速色谱中3-羟基-4-甲氧基-β-苯丙氨酸对映体的制备分离，考察了流动相中Cu^2＋浓度、样品体积等因素对分离的影响。

Direct enantiomeric separation of racemic mixtures of 13 β-amino alcohols and β-hydroxy sulfides was achieved by HPLC using Chiralcel OD, Chiralcel OJ and Chiralpak AD as chiral stationary phases and hexane/2-propanol mixture as eluent. These racemates were completely separated into enantiomers at least on one of these stationary phases.

在以正己烷-异丙醇为移动相的体系中，用ChiralcelOD，ChiralcelOJ及ChiralpakAD作为手性固定相对13种β-氨基醇及β-羟基硫醚类化合物对映体进行HPLC手性拆分，这些化合物至少能在一支柱上得到基线级分离。

As she looked at Warrington's manly face, and dark, melancholy eyes, she had settled in her mind that he must have been the victim of an unhappy attachment.

每逢看到沃林顿那刚毅的脸，那乌黑、忧郁的眼睛，她便会相信，他一定作过不幸的爱情的受害者。

Maybe they'll disappear into a pothole.

也许他们将在壶穴里消失