查询词典 pyridyl

The synthesis, crystal structure and characterization of 4, 5-dimethyl-2-(2-pyridyl) imidazole were reported.

为了制备研究2-取代咪唑配合物，设计合成了4， 5-二甲基-2-（2-吡啶基）咪唑，用IR、MS、1H-NMR对其结构进行了确证，并对其晶体结构进行了分析。

In their MS breakdown mechanism, coordination of pyridyl moiety to iron atom is proposed.

在该类化合物的质谱裂解中，发现吡啶环对铁原子存在配位作用。

The tobacco-specific nitrosamine 4--1-(3-pyridyl)-1-butanol is present in the urine of tobacco users and, at lower concentrations, in the urine of nonsmokers exposed to secondhand smoke.

烟草特有的亚硝胺4--1-(3-吡啶)-1-丁醇存在于吸烟者和被动吸二手烟的非吸烟者人群的尿液中，只是被动吸二手烟的非吸烟者人群尿液中的浓度更小。

We report herein the syntheses and characterization of three ligands:2,3-di-2-pyridylquinoxaline, 2,3-bis(2-pyridyl)-5,6-dimethoxyl-quinoxaline,and 2,3,7,8-tetrakis(2-pyridyl)pyrazino[2,3-g]quinoxaline and their 〓 and 〓complexes.

多吡啶配合物的结构多种多样，具有不寻常的光、电、磁性质和生物活性等，所以它们在非线性光学材料、磁性和超导材料、催化及药物合成方面有良好的潜在应用前景。

In order to find biologically active urea compounds,seven new N-[5-(3-pyridyl)-1,3,4-thiadiazol-2-yl]-N'- urea derivatives were synthesized by the reaction of 2-amino-5-(3-pyridyl)-1,3,4-thiadiazole with aroylazides,which were prepared starting from carboxylic acids,ethyl chloroformate and sodium azide by one-pot procedure.

为了寻找高生物活性的脲类化合物，通过2-氨基-5-(3-吡啶基)-1，3，4-噻二唑与酰基叠氮化物反应，设计合成了7个新的N-[5-(3-吡啶基)-1，3，4-噻二唑-2-基]-N'-取代苯基脲，其中芳酰基叠氮化物是以芳酸、氯甲酸乙酯、叠氮化钠为起始原料采用&一锅法&所制得。

Three novel rigid compounds 3, 6-bis[2-(4-pyridylethenyl]-9-ethylcarbazole (L~1), 3,6-bis[2-(2-pyridyl)ethenyl]-9-ethylcarbazole (L~2), 3,6-bis[2-(4-pyridyl)ethenyl]-9 -ethylpyridylcarbazole (L~3) were successfully synthesized by Heck reaction, which were fully characterized by elemental analyses, NMR, MS, IR spectra and single X-ray diffraction analysis.

利用Heck偶联反应，成功地合成了三种新型刚性的吡啶基咔唑类化合物：3，6-二[2-(4-吡啶基)乙烯基]-9-乙基咔唑(L~1)，3，6-二[2-(2-吡啶基)乙烯基]-9-乙基咔唑(L~2)和3，6-二[2-(4-吡啶基)吡啶基]-9-乙基吡啶基咔唑(L~3)，通过元素分析、核磁共振谱、质谱、红外光谱和单晶X-射线衍射等分析手段确证了它们的结构。

The reactions of 〓with bptz generate a cyclic tetranuclear and a 1-D helical chain 〓 complexes with thehydrolysis reaction products: 2,5-di(4-pyridyl)-l,3,4-oxadiazole and N,N'-bis(α-hydroxyl-2-pyridyl)ketazine.

本文利用〓在不同的环境中与bptz反应得到两个水解产物形成的配合物并解析了其晶体结构，一个为一维链状配合物，另一个为一个四核环状结构。

Adjacent helical chains are racemic. The Ag atom is linked to two nitrogen atoms of the 2-pyridyl and 4'-pyridyl groups from two different 2,4'-bpy ligands as well as to the oxygen atom of the counterion. In 17 and 19, the adjacent helical chains are linked to wavy two-dimensional network structures by the nitrate counterions.

相邻的螺旋链间是外消旋的，Ag 原子与分别来自两个不同2，4'-联吡啶的2-吡啶基和4'-吡啶基的氮原子以及阴离子的氧原子配位，在配合物17和19中，相邻聚合螺旋链被硝酸根离子桥连接起来，变成了一个波浪形的二维网络结构；配合物18是首次通过无桥连配体支持的Ag ××× Ag键将相邻螺旋链连接成二维非穿插的网络结构。

Two sorts of polyacrylate derivates were designed and systhesized. One has benzoic acid groups linked to backbone via an alkyl chain of different length, the other has pyridyl groups at its side chain. On the basis of hydrogen-bonding between carboxyl and pyridyl groups, multilayer film was fabricated in mixed solvents. We studied the effect of either the composition of mixed solvents or length of alkyl chain on the structure of a multilayer film.

设计合成了两类聚丙烯酸酯类高分子，一种侧链含有通过不同个数的亚甲基和主链相连的苯甲酸基团，另一种侧链含有吡啶基团，基于羧基和吡啶基之间的氢键相互作用，在混合溶剂中制备了多层膜，并研究了溶剂组成与高分子侧链间隔基长度对多层膜结构的影响。

With two tripodal ligands, dtma and tmpa, dtma=diethylenetriamine-N'-acetate and tmpa=tris(2-pyridyl-methylamine and a polyamine ligand, trien (=triethylenetetramine), serving as terminal ligands, we synthesized 19 species of new imidazolate -bridged Cu-Zn, Zn-Zn and Cu-Cu, and other relating compounds, in which 〓 and 〓 complexes are model compounds of Cu, Zn-SOD.

用不等臂三脚架dtma(diethylenetriamine-N'-acetate)、直链trien和等臂三脚架tmpatris(2-pyridyl-methyl-amine为配体，合成了一系列咪唑桥联Cu-Zn、Zn-Zn和Cu-Cu等有关19个新化合物，其中两个异双核〓Cu〓和〓〓配合物为Cu，Zn-SOD活性中心的模型化合物。2。

In the negative and interrogative forms, of course, this is identical to the non-emphatic forms.

。但是，在否定句或疑问句里，这种带有"do"的方法表达的效果却没有什么强调的意思。

Go down on one's knees;kneel down

屈膝跪下。。。下跪祈祷