查询词典 pyridine

One was HF/pyridine diazotization reaction at the 4-position of fluorene ring, and the other was Grignard reaction on the 9-position with Grignard reagent of pentafluorochlorobenzene.

使用HF/吡啶法在芴环的4位引入了氟原子，使用五氟氯苯格氏试剂在芴环的9位引入了全氟苯，合成了五个氟取代三联(9，9-二苯基)芴化合物。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene PolymerizationFacile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that:1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明：1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体；2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

New contributions of this work are as follows:(1). Preparation of Spherical MgCl_2-Supported Late-Transition Metal Catalysts for Ethylene Polymerization Facile and effective immobilization of late-transition metal catalysts. 2,3-bis-(2,6-diisopropylphenyl) butane diimine nickel dibromide (1) and 2,6-bis-[1-(2,4,6-trimethylphenylimino)ethyl]pyridine iron dichloride (2), for ethylene polymerization has been achieved, using spherical MgCl_2 supports obtained by thermal dealcoholization of MgCl_2·2.56C_2H_5OH, and the effects of dealcoholization temperature on supported late-transition metal catalysts and the properties of resultant polymers were studied, the results indicated that: 1.Supports with appropriate mechanical strength, high surface area and high porosity could be prepared by thermal dealcoholization of spherical MgCl_2·2.56C_2H_5OH supports; 2.BET, XRD, IR, SEM, GPC and DSC analyses indicate that the activities of the supported late-transition metal catalysts and the properties of resultant polymers are strongly dependent on the dealcoholization temperature.

本工作的新贡献如下：(1)、球形氯化镁负载后过渡金属催化荆催化乙烯聚合本文将配合物2，3-双(2，6-二异丙基苯亚胺)丁烷二溴化镍(1)和配合物2，6-二[1-(2，4，6-三甲基苯亚胺)乙基]吡啶二氯化铁(2)分别直接负载于经不同热脱醇温度处理的球形氯化镁载体上，研究了氯化镁载体的脱醇温度对负载化后过渡金属催化剂及其聚合物的影响，研究表明： 1、通过对球形MgCl_2·2.56C_2H_5OH载体进行热脱醇处理，可以获得合适机械强度、较高比表面积和较高孔隙度的球形氯化镁载体； 2、BET，XRD，IR，SEM，GPC和DSC研究表明，脱醇温度极大地影响负载后过渡金属催化剂的活性和聚合物的性能。

Recent progress for β-diketone derivatives were reviewed based on reading a great deal of related literature including Photoluminescence and Electroluminescence of rear earth metal complexes and the photoelectric properties of multi-pyridine Ru complexes.

本论文在大量文献调研的基础上，对β-二酮的结构特点和研究状况、稀土配合物发光材料和多吡啶钌配合物光电性质研究进展进行了较详细的综述。

In this dissertation, the more denoting β-diketone ligand is used to weaken the electrophilic property of Ti center to obtain a complex for use as a catalyst precursor to polymerize ethylene, vinyl pyridine and acrylonitrile.

如何通过化学或物理化学方法来调节活性中心与非极性烯烃、活性中心与极性单体这两者之间的性能差异，使之同时能适应两类单体聚合无疑是很重要的。

Stable pharmaceutical compositions containing 8-chloro-6,11-dihydro-11-(4-piperidylidene)-5H-benzo[5,6] cycloheptic [1,2-b] pyridine and a DCL protective amount of a pharmaceutically acceptable basic salt such as calcium dibasic phosphate and an amount of at least one disintegrant, preferably two disintegrates such as microcrystalline cellulose and starch sufficient to provide dissolution of at least about 80% by weight of the pharmaceutical composition in about 45 minutes and suitable for oral administration to treat allergic reactions in mammals such as man are disclosed.

本发明公开了含有8－氯－6，11－二氢－11－（4－亚哌啶基）－5H－苯并［5，6］环庚三烯并［1，2－b］吡啶和DCL保护量的可药用碱性盐如磷酸氢钙以及其含量足以使至少约80％的药物组合物在约45分钟内溶解的至少一种崩解剂、优选两种崩解剂如微晶纤维素和淀粉并且适于口服给药以治疗哺乳动物、例如人的过敏反应的稳定的药物组合物。

Results show that the best value of w is 7~10% and 5~7%, i is 0.08~0.2 A/cm^2 and 0.03~0.05 A/cm^2 respectively, during the electrolysis fluorination of pyridine and tributylamine; the addition of N-butyl mercaptan into the organic mixture can stabilize electrolysis process with its mass fraction 15~20% at best; impulse current polarization work status of low load is helpful to the electrolysis process and reduces corrosion rate of anode; electrolysis temperature is suitable at 0~20℃; electrobath can use electrolyte inner circulation structure, exterior circulation structure or blending structure.

结果表明：吡啶和N-三丁胺电解氟化的最佳值w分别为7%~10%和5%~7%，i分别为0.08~0.2A/平方公分和0.03~0.05A/平方公分；有机混合物中添加N-丁基硫醇可稳定电解过程，其质量分数最佳为15%~20%；采用低负荷的脉冲电流极化工况有利电解过程，降低阳极的腐蚀速度；电解温度0~20℃为宜；电解槽可采用电解液内循环、外循环结构，或其混合结构。

The functional groups which are placed at 4-position of pyridine-2,6-dicarboxylic acid can effect the electron cloud of the lanthanide complexes.

吡啶-2，6-二甲酸的4位取代官能团能影响配合物的电子云形状，配合物的荧光性能和电子能量传递密切相关。

Methods Starting from 2-chloro-4-nitrophenol and 2- pyridine hydrochlorid, 3-chloro-4-(pyridin-2-ylmethoxy) aniline was obtained via etherization and reduction. The obtained aniline coupled with N-(4-chloro-3-cyano-7-ethoxyquinolin-6-yl) acetamide to give 4-[3-chloro-4-(2-pyridylmethoxy) phenylamino]-3-cyano-7-ethoxy-6-N-acetylaminoquinoline. And then it was deacetylated, followed by reacting with4- but-2-enoyl chloride to yield the target compound neratinib.

以2-氯－4-硝基苯酚和2-氯甲基吡啶为起始原料，经醚化、硝基还原得到3-氯－4-（吡啶－2-甲氧基）苯胺，3-氯－4-（吡啶－2-甲氧基）苯胺与3-氰基－6-乙酰氨基－7-乙氧基－4-氯喹啉反应得到3-氰基－6-乙酰氨基－4-［3-氯－4-（吡啶－2-甲氧基）苯氨基］－7-乙氧基喹啉，3-氰基－6-乙酰氨基－4-［3-氯－4-（吡啶－2-甲氧基）苯氨基］－7-乙氧基喹啉去乙酰保护基后，与-4-二甲氨基－2-丁烯酰氯经酰化反应得到ner-atinib。

It is easily soluble in water, acetone and alcohol, slightly soluble in ether, ethyl acetate, chloroform, and pyridine, unsoluble in benzene.

熔点151℃～154℃。易溶于水、丙酮与醇，微溶于醚、乙酸乙酯、氯仿和吡啶，不溶于苯。

Fancy gold-plated dangling earrings with facetted White Opal crystals.

花式镀金悬垂耳环与facetted白欧泊水晶。

This essay chooses the study aim from biology teachers in middle school in Shi Jiazhuang which tells us that most of the middle school biology teachers in Shi Jiazhuang have the"burnout", lower successfulness, individualize.

本文选取石家庄市初中生物教师作为研究对象，运用问卷调查的方法对石家庄市初中生物教师职业倦怠的现状进行调查，调查结果发现，石家庄市初中生物教师这一群体普遍存在职业倦怠，情感枯竭程度偏高，成就感偏低，去个性化程度最为严重。