查询词典 pyridine

The speed of the coordinating reaction between pyridine and Co is higher than that between pyridine and Fe.

吡啶与Co结合的速率比Fe结合的速率快。

Pyridine and pyridine production base is also a feed additive main raw material for nicotinic acid.

吡啶和吡啶生产基地，也是主要的饲料添加剂烟酸原料。

At high pyridine concentration, the swelling ratio increased with the pyridine concentration.

在高吡啶浓度时，溶胀率随吸附量的增大而增加。

These ligands can be roughly divided into two groups: those in which the camphor is annulated in the 2,3-positions to the -face of the pyridine ring and those in which the pyridine is contained as a pendent on the C2 or C3 of the camphor framework.

这些配大体可以分为两类：这其中是空心的樟脑2，3-阵地到对面的吡啶环与那些其中吡啶载于作为悬吊的樟脑的C2或C3的架构。

10-arylmethylene anthrone pyridine compounds and the raw materials for the reaction conditions, join in alkaline, phase transfer catalysts and acceleration response, KI synthesis of containing pyridine 10,10 - dialkyl anthraquinone.

以蒽酮和含吡啶基的化合物为反应原料，在碱性条件，加入相转移催化剂和KI加速反应的进行，来合成含吡啶基的10，10-二烷基蒽酮。

It isconfirmed by ~1H NMR,~(13)C NMR and X-ray crystallographic analysis that complexes 60-63are monopyridine complexes and show distorted square pyramid geometries; complexes 64and 65 are bispyridine complexes and show pseudo-octahedral geometries, where twopyridine ligands are in cis arrangement and trans to the NHC and the benzylidene ligandrespectively, the bond length between ruthenium and pyridine ligand trans to the benzylideneligand is 16 pm longer than the bond length between ruthenium and pyridine ligand trans tothe NHC ligand.

1H NMR、~(13)C NMR及X射线单晶衍射分析证明，配合物60-63是单吡啶衍生物配位的钌卡宾配合物，具有变形的四方锥构型；配合物64、65为双吡啶衍生物配位的钌卡宾配合物，具有变形的八面体构型，其中两个顺式配位的吡啶衍生物分别处于氮杂环卡宾和苯亚甲基的反位，处于苯亚甲基反位的吡啶衍生物对应的钌-氮键长要比处于氮杂环卡宾反位的长出16 pm。

Benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene]dichloro(2-methylpyridine)ruthenium (62), benzylidene[1,3-bis(2,6-dimethylphenyl)-4,5-dihydroimidazol-2-ylidene] dichloro(2,4-dimethylpyridine)ruthen ium (63) introduce ortho substituted pyridine as dissociating ligand to weaken Ru-N bondand accelerate dissociation of pyridine derivative ligand through steric hindrance.

在钌卡宾配合物[1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基]-苯亚甲基-(2-甲基吡啶)-二氯合钌(62)，1，3-二-(2，6-二甲苯基)-4，5-二氢咪唑基1-苯亚甲基-(2，4-二甲基吡啶)-二氯合钌(63)中，邻位取代的吡啶作为解离配体，通过邻位基团的空间效应削弱钌-氮配位键，使配体更易解离，提高了催化剂的初活性。

Several types of ligand reactions observed under hydrothermal condition were summed up:(1) hydrolysis of pyridine nitrile, aldehyde and ester in mixed water and alcohol into pyridine-carboxylate;(2) replacement of carboxylate group with sulfonic group;(3) coupling of phenanthroline by dehydrogen;(4) oxidative coupling of methanol into oxalic acid;(5) hydroxylation of isophthalate.

总结了以往在水热条件下观察到的几类配体反应：（1）吡啶腈、醛和酯在醇和水混合溶液中水解成吡啶羧酸；（2）磺基取代羧基反应；（3）邻菲啰啉的脱氢的聚合：（4）甲醇被氧化偶合生成草酸：（5）间苯二甲酸的羟基化反应。

WO3, an interlayer compound prepared by J. W. Johnson (1981) using yellow tungstic oxide hydrate. Suspension of white powdery tungstic acid in anhydrous pyridine yields on standing for 2 wk whiteHW4O13.3H2O. IR and DTA studies revealed the connection between that pyridine polytungstate and white powdery tungstic acid (microcryst.), whose composition may thereby be assigned as H2W4O13.nH2O.

WO3。粉状白钨酸在无水吡啶中放置两周后可得到另一种化学式为(C5H5NH)HW4O13.3H2O的吡啶化合物，经IR和DTA研究可初步说明该化合物与粉状白钨酸之间的联系，并因此推测白钨酸的组成可能为H2W4O13.nH2O。

The reactions of pyridine-2-carbaldehyde semicarbazone with transition metal Ni(II,Cosalts afford two pyridine-2-carbaldehyde semicarbazone transition metal compounds.

配合物[CoL2]·(ClO4)2·H2O(3)，分子式C14H18Cl2CoN8O11，Mr=604.19，属三斜晶系，空间群P-1，晶胞参数：a=9.984(3) A， b=11.082(4) A， c=12.196(5) A ，Dc=1.769Mg/m3，α=112.954(4)°，β=110.050(4)°，γ=94.017(3)°，V=1134.4(7) A3， Z=2，μ=1.067mm-1， F(000)=614，结构偏离因子R=0.0501 和ωR=0.1028，配合物(3)的中心金属离子采取六配位的变形八面体。

Fancy gold-plated dangling earrings with facetted White Opal crystals.

花式镀金悬垂耳环与facetted白欧泊水晶。

This essay chooses the study aim from biology teachers in middle school in Shi Jiazhuang which tells us that most of the middle school biology teachers in Shi Jiazhuang have the"burnout", lower successfulness, individualize.

本文选取石家庄市初中生物教师作为研究对象，运用问卷调查的方法对石家庄市初中生物教师职业倦怠的现状进行调查，调查结果发现，石家庄市初中生物教师这一群体普遍存在职业倦怠，情感枯竭程度偏高，成就感偏低，去个性化程度最为严重。