查询词典 pyrazole

In this report, a series of nitrogen heterocycle porphyrin compounds were obtained by introducing a pyrazole heterocyclic ring with high fluorescent quantum yield to the parent porphyrin.

本文通过将具有较高荧光量子产率的吡唑杂环化合物连到卟啉环的中位而得到一类新型的含氮杂环卟啉。

Cinnabarinus at 150 mg/L.The influences on bioactivity of substituted pyrazole and pyrimidine were discussed respectively: pyrazoles substituted with phenyls at 3 position had higher activity than thiophen and compounds with R_1=methyl had higher activity than that with R_1= hydrogen, pyrimidines substituted with methyl at 2 (R_3) and 5 (R_3) position and phenyl at 6 position were most active.

本论文对吡唑及嘧啶取代基对活性的影响分别进行了讨论，可知：吡唑3位为取代苯基的化合物杀菌活性优于取代噻吩的，吡唑4位(R_1)为甲基的杀菌活性高于R_1为氢的活性；嘧啶的2位(R_3)为甲基，5位(R_1)为甲基，6位为无取代基的苯基时活性最好。

The-methyl-β-methoxyacrylate compounds containing substituted pyrazole ring I-14、I-16 had good acaricidal activity with 100% control of T.

含吡唑环的甲氧基丙烯酸酯类化合物I-14、I-16在150 mg/L浓度下具有很好的杀螨活性。

Preliminary bioassays indicated that many title compounds exhibited excellent fungicidal, or insecticidal and acaricidal activities. The strobilurin derivatives containing substituted pyrimide ring have lower biological activity than the strobilurin derivatives containing substituted pyrazole ring which exhibited good fungicidal activity against RB (0.92 mg/L), TLB (0.3 mg/L), CDM (12.5 mg/L) and WPM (1.56 mg/L).

初步生物活性测定结果表明，新型Strobilurin类化合物中多个化合物具有较好的杀菌或杀虫杀螨活性，其中吡唑类化合物要明显优于嘧啶类化合物，吡唑类化合物在低浓度下对水稻稻瘟病菌(0.92 mg/L)、番茄晚疫病菌(0.3 mg/L)、黄瓜霜霉病(12.5 mg/L)和小麦白粉病(1.56 mg/L)仍具有很好的杀菌活性。

Preliminary bioassays indicated that many title compounds exhibited excellent fungicidal, or insecticidal and acaricidal activities. The strobilurin derivatives containing substituted pyrimide ring have lower biological activity than the strobilurin derivatives containing substituted pyrazole ring which exhibited good fungicidal activity against RB (0.92 mg/L), TLB (0.3 mg/L), CDM (12.5 mg/L) and WPM (1.56 mg/L).

初步生物活性测定结果表明，新型Strobilurin类化合物中多个化合物具有较好的杀菌或杀虫杀加热管螨活性，其中吡唑类化合物要明显优于嘧啶类化合物，吡唑类化合物在低浓加热管度下对水稻稻瘟病菌(0.92 mg/L)、番茄晚疫病菌(0.3 mg/L)、黄瓜霜霉病(12.5 mg/L)和小加热管麦白粉病(1.56 mg/L)仍具有很好的杀菌活性。

Pyrazolyl alkenyl Fischer carbene complexes have both the virtues of multiple reactivity in carbene fragment and high bioactivity in pyrazole fragment, which attracts our interest in their synthesis and application from a theoretical and applied viewpoint.

吡唑基烯基卡宾化合物同时具有高反应活性的卡宾基团和高生物活性的吡唑基团，因而其反应研究具有一定的理论意义和应用价值。

The general formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

The genera formulas of these compounds are as follows:The strobilurin derivatives were synthesized from substitutedβ-keto esters (2) as starting material which were prepared from substituted ketones (1) and dimethyl carbonate. The ester (2) and methyl hydrazine or substituted amidine were dissolved in methanol and the mixture was heated to reflux to obtain the substituted 5-hydroxy-1H-pyrazole (3) or 4-hydroxy-pyrimidine (4). The title compounds were prepared by reacting the intermediates (3 and 4) with substituted halomethylphenyls which contain four active group under basic conditions.

本论文所合成的strobilurin化合物均是以β-酮酸酯类化合物(2)为起始原料合成的，该中间体(2)是由酮类化合物(1)与碳酸二甲酯在碱性条件下反应生成的，中间体(2)与甲基肼或取代脒类化合物在甲醇中回流制得取代的1H-5-羟基吡唑(3)或4-羟基嘧啶(4)，中间体(3和4)再与包含四种活性基的苄卤中间体在碱性条件下制得目标化合物。

In addition, the reactions of the carbodiimide with alkanol and substituted phenol were studied firstly.

研究了4-酯基吡唑-5-碳二亚胺(Pyrazole-5-N=C=N-Ar)与NH_3，RNH_2，R_2NH和RNHNH_2成环反应的选择性。

METHODS 5-amino-1-hydroxyethyl pyrazole-4-carboylic acid was synthesized through condensation of ethyl cyanoacetate and triethyl orthoformate followed by one-pot methodology of cyclization,hydolysis.

方法原甲酸三乙酯与氰乙酸乙酯缩合，然后和羟乙基肼经环合、水解等一锅法合成5-氨基吡唑-4-甲酸，然后在亚硫酸钠存在条件下加热脱羧得到5-氨基-1-羟乙基吡唑。

Do you know, i need you to come back

你知道吗，我需要你回来

Yang yinshu、Wang xiangsheng、Li decang,The first discovery of haemaphysalis conicinna.

1〕 杨银书，王祥生，李德昌。安徽省首次发现嗜群血蜱。